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b(the)i(calculations,)h(the)f (vibrational)g(e\013ects)g(are)g(underestimated.)307 1872 y Fs(P)-6 b(A)n(CS)23 b(n)n(um)n(b)r(ers:)30 b(68.43.Mn,)24 b(68.43.Vx,)f(82.20.Kh)436 2130 y Fi(I.)88 b(INTR)n(ODUCTION)-67 2357 y Fr(The)30 b(catalytic)e(activit)n(y)h(of)h(surfaces)e(is)i (often)f(signi\014can)n(tly)-150 2452 y(mo)r(di\014ed)f(b)n(y)g(the)g (presence)g(of)g(co-adsorbates.)35 b(Sulfur)28 b(atoms)-150 2548 y(act)i(as)f(inhibitors)h(for)f(surface)g(reactions)g(and)h (therefore)f(p)r(oi-)-150 2643 y(son)49 b(catalysts.)103 b(An)51 b(understanding)e(of)h(the)g(microscopic)-150 2739 y(mec)n(hanisms)21 b(of)h(surface)f(reactions)f(is)i(dev)n(elop)r (ed)f(through)g(the)-150 2834 y(in)n(v)n(estigation)30 b(of)i(mo)r(del)g(systems,)g(lik)n(e)g(the)g(asso)r(ciativ)n(e)e(des-) -150 2930 y(orption)40 b(of)g(h)n(ydrogen)f(from)i(metal)f(surfaces.)75 b(Exp)r(erimen-)-150 3025 y(tally)44 b(the)g(study)g(of)g(all)g (molecular)f(degrees)f(of)i(freedom)g({)-150 3121 y(rotational)30 b(and)i(vibrational)f(energy)-7 b(,)32 b(in)n(ternal)f(state-sp)r (eci\014c)-150 3216 y(v)n(elo)r(cit)n(y)i(and)i(angular)d (distributions,)k(and)e(the)h(in\015uence)f(of)-150 3312 y(the)f(spatial)f(alignmen)n(t)g(of)h(the)g(rotational)e(angular)g (momen-)-150 3407 y(tum)g({)g(yields)f(dynamical)g(information)g(ab)r (out)g(the)h(reaction.)-150 3503 y(In)e(a)f(addition)g(to)g(these)h (quan)n(tities)f(a)g(theoretical)g(treatmen)n(t)-150 3598 y(allo)n(ws)39 b(further)h(to)g(in)n(v)n(estigate)f(the)i (in\015uence)f(of)h(the)f(lo)r(ca-)-150 3694 y(tion)30 b(within)g(the)g(surface)f(unit)h(cell)f(on)h(the)g(reaction.)41 b(A)n(t)30 b(the)-150 3789 y(clean)j(palladium)h(surface)f(h)n(ydrogen) f(reactions)g(ha)n(v)n(e)h(exten-)-150 3885 y(siv)n(ely)20 b(b)r(een)g(studied)523 3854 y Fh(1)q(,2)633 3885 y Fr(in)h(the)g(past) f(b)r(oth)h(exp)r(erimen)n(tally)1757 3854 y Fh(3)o({10)-150 3980 y Fr(and)32 b(theoretically)467 3950 y Fh(11)o({19)635 3980 y Fr(.)51 b(The)32 b(p)r(oten)n(tial)g(energy)f(surface)g(for)-150 4075 y(the)c(reaction)e(on)h(a)g(clean)g(palladium)h(surface)e(sho)n (ws)h(a)g(signif-)-150 4171 y(ican)n(t)f(energetic)g(and)g(geometric)f (corrugation.)34 b(In)26 b(particular,)-150 4266 y(reaction)f(paths)h (without)g(barrier)e(as)i(w)n(ell)f(as)h(activ)-5 b(ated)26 b(paths)-150 4362 y(with)36 b(barriers)d(up)i(to)g Fg(E)657 4374 y Ff(b)727 4362 y Fr(=)g(200)13 b(meV)35 b(are)f(a)n(v)-5 b(ailable)1630 4332 y Fh(12)o(,17,18)1869 4362 y Fr(.)-150 4457 y(This)34 b(leads)f(to)h(a)f(v)-5 b(ariet)n(y)33 b(of)h(in)n(teresting)f(dynamical)g(e\013ects,)-150 4553 y(lik)n(e)e(steering)g(of)h(molecules)f(with)i(lo)n(w)e(kinetic)h (energy)1658 4523 y Fh(11)1759 4553 y Fr(and)-150 4648 y(small)22 b(angular)f(momen)n(tum)765 4618 y Fh(17)858 4648 y Fr(to)i(fa)n(v)n(orable)d(adsorption)i(sites.)-150 4744 y(These)f(calculations)g(predict)h(a)f(signi\014can)n(t)g (rotational)f(co)r(oling)-150 4839 y(of)38 b(asso)r(ciativ)n(ely)e 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y(di\013eren)n(t)33 b(ro)n(vibrational)e(\()p Fg(v)758 4115 y Fq(0)782 4145 y Fg(;)14 b(J)873 4115 y Fq(0)896 4145 y Fr(\))34 b(lev)n(els)e(of)h(the)h(in)n(termediate)-150 4240 y Fg(B)h Fr(state)124 4210 y Fh(25,26)279 4240 y Fr(.)47 b(W)-7 b(e)31 b(therefore)f(determine)h(relativ)n(e)f (ionization)-150 4336 y(probabilities)f(b)n(y)g(observing,)g(at)g(the)h (giv)n(en)f(laser)f(in)n(tensities,)-150 4431 y(the)34 b(ion)f(yield)g(of)h(D)513 4443 y Fh(2)584 4431 y Fr(lea)n(ving)e(a)h (Kn)n(udsen)g(cell)g(with)h(a)f(\014xed)-150 4527 y(temp)r(erature)23 b(and)g(th)n(us)g(a)f(w)n(ell-kno)n(wn)g(Boltzmann)h(state)g(dis-)-150 4622 y(tribution.)50 b(A)32 b(detailed)g(description)f(of)h(this)g (calibration)f(has)-150 4718 y(b)r(een)41 b(giv)n(en)f(previously)660 4688 y Fh(10)729 4718 y Fr(.)77 b(Rotational)39 b(state)i(p)r (opulations)-150 4813 y(could)28 b(b)r(e)g(determined)g(for)f(D)809 4825 y Fh(2)874 4813 y Fr(\()p Fg(J)960 4783 y Fq(00)1026 4813 y Fr(=)c(0)18 b Fe(\000)h Fr(12\))27 b(in)h(vibrational)-150 4909 y(ground)i(and)h(D)363 4921 y Fh(2)432 4909 y Fr(\()p Fg(J)518 4879 y Fq(00)590 4909 y Fr(=)d(0)21 b Fe(\000)f Fr(8\))31 b(in)h(the)f(\014rst)g(vibrational)f(ex-)-150 5004 y(cited)e(state.)-67 5127 y(Molecules)20 b(desorbing)f(from)g(the) i(palladium)f(surface)f(are)h(de-)-150 5222 y(tected)k(at)f(a)f (distance)h(of)g(20)13 b(mm)24 b(from)f(the)g(surface.)35 b(Since)23 b(the)-150 5318 y(exp)r(erimen)n(ts)38 b(are)g(carried)f (out)i(with)g(a)f(con)n(tin)n(uous)g(desorp-)-150 5413 y(tion)e(\015ux,)i(some)d(molecules)g(ma)n(y)g(reac)n(h)g(the)h (detection)g(v)n(ol-)2042 -83 y(ume)29 b(after)g(ha)n(ving)g(thermally) f(equilibrated)h(at)g(the)h(c)n(ham)n(b)r(er)2042 12 y(w)n(alls.)76 b(This)41 b(bac)n(kground)d(is)j(partly)g(suppressed)f (b)n(y)g(sepa-)2042 108 y(rating)25 b(the)h(desorption)e(c)n(ham)n(b)r (er)h(con)n(taining)g(the)h(Pd)g(sample)2042 203 y(from)e(the)h (detection)f(v)n(olume,)h(and)f(allo)n(wing)f(only)h(the)h(cen)n(tral) 2042 299 y(part)k(of)h(the)g(desorption)f(\015ux)h(to)g(en)n(ter)g(the) g(detection)g(c)n(ham-)2042 394 y(b)r(er)37 b(through)f(a)h(10)13 b(mm)37 b(diameter)g(ap)r(erture.)64 b(The)37 b(residual)2042 490 y(bac)n(kground)23 b(gas)i(is)g(accoun)n(ted)g(for)g(b)n(y)g (taking)g(sp)r(ectra)f(of)i(the)2042 585 y(bac)n(kground)31 b(gas)g(only)-7 b(.)52 b(Due)34 b(to)e(its)h(thermal)g(p)r(opulation)f (at)2042 681 y Fg(T)52 b Fe(\030)42 b Fr(300)12 b(K)38 b(this)h(bac)n(kground)e(has)h(a)h(noticeable)f(in\015uence)2042 776 y(only)d(on)g(the)h(ion)f(signal)g(for)g(molecules)g(in)h Fg(J)3572 746 y Fq(00)3650 776 y Fr(=)g(0)f(to)h(5)f(in)2042 872 y(the)c(vibrational)e(ground)h(state.)45 b(The)31 b(ion)f(signal)g Fg(I)38 b Fr(observ)n(ed)2042 967 y(is)d(then)g (connected)g(to)f(the)h(ro)n(vibrational)e(state)h(p)r(opulation)2042 1063 y Fg(N)9 b Fr(\()p Fg(v)2193 1033 y Fq(00)2235 1063 y Fg(;)14 b(J)2326 1033 y Fq(00)2369 1063 y Fr(\))28 b(via)2042 1368 y Fg(I)i Fe(/)2195 1273 y Fd(\014)2195 1323 y(\014)2195 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Fc(00)2350 1657 y Ff(e)2500 1541 y Fd(\014)2500 1591 y(\014)2500 1641 y(\014)2528 1562 y Fh(2)2591 1637 y Fr(and)2750 1541 y Fd(\014)2750 1591 y(\014)2750 1641 y(\014)2778 1637 y Fg(R)2842 1607 y Ff(v)2877 1581 y Fc(0)2899 1607 y Ff(v)2934 1581 y Fc(00)2841 1660 y Fh(vib)2979 1541 y Fd(\014)2979 1591 y(\014)2979 1641 y(\014)3007 1562 y Fh(2)3070 1637 y Fr(denote)25 b(the)h(electronic)f(transi-)2042 1757 y(tion)c(momen)n(t)g(and)g(the)g(F)-7 b(ranc)n(k-Condon)19 b(factor,)j(resp)r(ectiv)n(ely)-7 b(,)2042 1852 y(and)35 b Fg(S)2262 1864 y Ff(J)2304 1848 y Fc(0)2326 1864 y Ff(J)2368 1848 y Fc(00)2449 1852 y Fr(describ)r(es)f(the)i(H\177)-42 b(onl-London)34 b(factor.)58 b Fg(K)6 b Fr(\()p Fg(v)3914 1822 y Fq(0)3938 1852 y Fg(;)14 b(J)4029 1822 y Fq(0)4052 1852 y Fr(\))2042 1948 y(tak)n(es)48 b(the)h(relativ)n(e)f(detection)h (sensitivit)n(y)g(as)f(determined)2042 2043 y(ab)r(o)n(v)n(e)21 b(in)n(to)g(accoun)n(t.)35 b(The)22 b(in\015uence)g(of)g(the)h (rotational)d(align-)2042 2138 y(men)n(t)36 b(of)g(desorbing)e (molecules)h(is)h(describ)r(ed)g(b)n(y)f(the)h(p)r(olar-)2042 2234 y(ization)24 b(factor)h Fg(\037)p Fr(\()p Fg(v)2674 2204 y Fq(00)2717 2234 y Fg(;)14 b(J)2808 2204 y Fq(00)2850 2234 y Fr(\).)36 b(This)25 b(factor)g(comp)r(ensates)f(for)h(the)2042 2329 y(dep)r(endence)e(of)g(the)g(excitation)g(probabilit)n(y)e(on)i (the)g(angle)f(b)r(e-)2042 2425 y(t)n(w)n(een)k(the)h(transition)f (momen)n(t)g(and)g(the)h(p)r(olarization)e(of)i(the)2042 2520 y(exciting)39 b(laser.)72 b(The)39 b(alignmen)n(t)g(of)h(D)3377 2532 y Fh(2)3414 2520 y Fr(\()p Fg(v)3489 2490 y Fq(00)3532 2520 y Fg(;)14 b(J)3623 2490 y Fq(00)3666 2520 y Fr(\))40 b(desorbing)2042 2616 y(from)26 b(c\(2)15 b Fe(\002)g Fr(2\))26 b(/)g(Pd\(100\))f(has)h(recen)n(tly)f(b)r(een)i(determined)f (in)2042 2711 y(this)i(lab)r(oratory)2585 2681 y Fh(21)2653 2711 y Fr(.)2836 2999 y Fi(B.)88 b(Theory)2125 3215 y Fr(The)47 b(theoretical)g(bac)n(kground)f(of)h(the)h(calculations)f (has)2042 3310 y(b)r(een)39 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Fh(28)3257 4170 y Fr(,)j(in)e(whic)n(h)g(all)g(six)g(h)n(ydro-) 2042 4265 y(gen)g(degrees)e(of)i(freedom)g(w)n(ere)f(explicitly)i(tak)n (en)e(in)n(to)h(accoun)n(t;)2042 4361 y(the)27 b(substrate,)g(ho)n(w)n (ev)n(er,)e(w)n(as)h(k)n(ept)h(\014xed.)37 b(This)27 b(is)g(a)f(reason-)2042 4456 y(able)e(appro)n(ximation)e(considering)h (the)i(large)e(mass)g(mismatc)n(h)2042 4552 y(b)r(et)n(w)n(een)k(h)n (ydrogen)f(and)i(palladium.)2125 4649 y(In)34 b(the)h(quan)n(tum)g(mec) n(hanical)e(sim)n(ulations)h(state-sp)r(eci\014c)2042 4745 y(stic)n(king)18 b(probabilities)h Fg(S)2857 4757 y Ff(n)2902 4745 y Fr(\()p Fg(E)2995 4757 y Fq(?)3052 4745 y Fr(\))g(as)g(a)g(function)h(of)f(the)h(inciden)n(t)2042 4840 y(normal)i(kinetic)i(energy)f Fg(E)2908 4852 y Fq(?)2988 4840 y Fr(are)f(determined.)36 b(Here)23 b Fg(n)h Fr(stands)2042 4936 y(for)37 b(a)g(m)n(ulti-index)g(that)h(describ)r(es)f(the)h (initial)f(vibrational,)2042 5031 y(rotational)24 b(and)i(parallel)f 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b(should)h(note,)i(ho) n(w)n(ev)n(er,)d(that)h(in)h(the)f(presen)n(t)f(study)2042 3867 y(theory)k(and)i(exp)r(erimen)n(t)f(ha)n(v)n(e)f(in)n(v)n (estigated)h(di\013eren)n(t)g(sur-)2042 3963 y(face)h(systems.)76 b(The)41 b(exp)r(erimen)n(tal)g(in)n(v)n(estigations)e(started)2042 4058 y(with)31 b(a)f(w)n(ell-ordered,)g(half)g(a)h(monola)n(y)n(er)d (co)n(v)n(erage)g(of)i(sulfur)2042 4154 y(in)36 b(a)h(c\(2)24 b Fe(\002)g Fr(2\))36 b(structure,)i(whic)n(h)e(decreased)g(during)g (an)g(ex-)2042 4249 y(p)r(erimen)n(tal)29 b(run)f(to)h(ab)r(out)g(a)g (quarter)f(of)h(a)f(monola)n(y)n(er.)39 b(This)2042 4345 y(sulfur)f(adla)n(y)n(er)d(do)r(es)j(,)i(ho)n(w)n(ev)n(er,)f(not)e (form)h(a)f(w)n(ell-ordered)2042 4440 y(p\(2)24 b Fe(\002)h Fr(2\))37 b(structure,)h(whic)n(h)f(is)g(examined)g(b)n(y)g(the)g (theoreti-)2042 4536 y(cal)32 b(in)n(v)n(estigations.)50 b(F)-7 b(urthermore,)33 b(the)g(calculations)f(sho)n(wn)2042 4631 y(are)j(p)r(erformed)h(for)f(H)2792 4643 y Fh(2)2866 4631 y 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F d reinitialize}?}b/terminate{!{& self eq{exit}{E}?}loop E}b/suspend/terminate , d /resume{` Pscript_Win_Data `}b U `/lucas 21690 d/featurebegin{countdictstack lucas[}b/featurecleanup{stopped{cleartomark @ lucas eq{! exit}if}loop countdictstack ~ sub @ 0 gt{{E}repeat}{!}?}b E/snap{transform 0.25 sub round 0.25 add ~ 0.25 sub round 0.25 add ~ itransform}b/dsnap{dtransform round ~ round ~ idtransform}b/nonzero_round{@ 0.5 ge{round}{@ -0.5 lt{round}{0 ge{1} {-1}?}?}?}b/nonzero_dsnap{dtransform nonzero_round ~ nonzero_round ~ idtransform}b U<04>cvn{}put/rr{1 ^ 0 - 0 ~ - neg 0 - C}b/irp{4 -2 $ + +S fx 4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/rp{4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/solid{[]0 sd}b/g {@ not{U/DefIf_save save put}if U/DefIf_bool 2 ^ put}b/DefIf_El{if U/DefIf_bool get not @{U/DefIf_save get restore}if}b/e{DefIf_El !}b/UDF{L2?{undefinefont}{!} ?}b/UDR{L2?{undefineresource}{! !}?}b/freeVM{/Courier findfont[40 0 0 -40 0 0] makefont Ji 2 vmreclaim}b %%EndResource %%BeginResource: file Pscript_Win_Utils_L2 5.0 0 /rf/rectfill , d/fx{1 1 dtransform @ 0 ge{1 sub 0.5}{1 add -0.5}? 3 -1 $ @ 0 ge {1 sub 0.5}{1 add -0.5}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{4 -2 $ snap + +S fx rf}b/rs/rectstroke , d/rc/rectclip , d/UtilsInit{currentglobal{F setglobal}if}b/scol{! setcolor}b/colspA/DeviceGray d/colspABC/DeviceRGB d /colspRefresh{colspABC setcolorspace}b/SetColSpace{colspABC setcolorspace}b /resourcestatus where{!/ColorRendering/ProcSet resourcestatus{! ! T}{F}?}{F}? not{/ColorRendering<>/defineresource where{!/ProcSet defineresource !}{! !}?}if/buildcrdname{/ColorRendering/ProcSet findresource ` mark GetHalftoneName @ type @/nametype ne ~/stringtype ne and{!/none}if(.) GetPageDeviceName @ type @/nametype ne ~/stringtype ne and{!/none}if(.)5 ^ 0 5 -1 1{^ length add}for string 6 1 $ 5 ^ 5{~ 1 ^ cvs length 1 ^ length 1 ^ sub getinterval}repeat ! cvn 3 1 $ ! ! E}b/definecolorrendering{~ buildcrdname ~ /ColorRendering defineresource !}b/findcolorrendering where{!}{ /findcolorrendering{buildcrdname @/ColorRendering resourcestatus{! ! T}{ /ColorRendering/ProcSet findresource ` GetSubstituteCRD E F}?}b}? /selectcolorrendering{findcolorrendering !/ColorRendering findresource setcolorrendering}b %%EndResource end %%EndProlog %%BeginSetup [ 0 1 -1 0 0 0 ] false Pscript_WinNT_Incr dup /initialize get exec 1 setlinecap 1 setlinejoin /mysetup [ 0.11999 0 0 -0.11999 9 821.99908 ] def %%EndSetup %%Page: 1 1 %%PageBoundingBox: 20 9 830 586 %%EndPageComments %%BeginPageSetup /DeviceRGB dup setcolorspace /colspABC exch def mysetup concat colspRefresh %%EndPageSetup 0 0 0 1 scol Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Text 5.0 0 /TextInit{TextInitialised? not{/Pscript_Windows_Font & d/TextInitialised? T d /fM[1 0 0 1 0 0]d/mFM matrix d/iMat[1 0 0.212557 1 0 0]d}if}b/copyfont{1 ^ length add dict `{1 ^/FID ne{d}{! !}?}forall & E}b/EncodeDict 11 dict d/bullets {{/bullet}repeat}b/rF{3 copyfont @ ` ~ EncodeDict ~ get/Encoding ~ 3 ^/0 eq{& /CharStrings known{CharStrings/Eth known not{! EncodeDict/ANSIEncodingOld get} if}if}if d E}b/mF{@ 7 1 $ findfont ~{@/Encoding get @ StandardEncoding eq{! T}{ {ISOLatin1Encoding}stopped{! F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{1 ^ ~ rF}{0 copyfont}? 6 -2 $ ! ! ~ !/pd_charset @ where{~ get 128 eq{@ FDV 2 copy get @ length array copy put pd_CoverFCRange}if}{!}? 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/xUP null d/yUP null d/uW null d/xSP null d/ySP null d/sW null d/sSU{N /uW ~ d/yUP ~ d/xUP ~ d}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ d/ySP ~ d/xSP ~ d}b/sT {xSP ySP sW sLT}b/sR{: + R 0 0 M}b/sRxy{: matrix astore concat 0 0 M}b/eR/; , d /AddOrigFP{{&/FontInfo known{&/FontInfo get length 6 add}{6}? dict ` /WinPitchAndFamily ~ d/WinCharSet ~ d/OrigFontType ~ d/OrigFontStyle ~ d /OrigFontName ~ d & E/FontInfo ~ d}{! ! ! ! !}?}b/mFS{makefont Pscript_Windows_Font 3 1 $ put}b/mF42D{0 copyfont `/FontName ~ d 2 copy ~ sub 1 add dict `/.notdef 0 d 2 copy 1 ~{@ 3 ^ sub Encoding ~ get ~ d}for & E /CharStrings ~ d ! ! & @ E/FontName get ~ definefont}b/mF42{15 dict ` @ 4 1 $ FontName ~ d/FontType 0 d/FMapType 2 d/FontMatrix[1 0 0 1 0 0]d 1 ^ 254 add 255 idiv @ array/Encoding ~ d 0 1 3 -1 $ 1 sub{@ Encoding 3 1 $ put}for/FDepVector Encoding length array d/CharStrings 2 dict `/.notdef 0 d & E d 0 1 Encoding length 1 sub{@ @ 10 lt{! FontName length 1 add string}{100 lt{FontName length 2 add string}{FontName length 3 add string}?}? @ 0 FontName @ length string cvs putinterval @ 3 -1 $ @ 4 1 $ 3 string cvs FontName length ~ putinterval cvn 1 ^ 256 mul @ 255 add 3 -1 $ 4 ^ findfont mF42D FDepVector 3 1 $ put}for & @ E /FontName get ~ definefont ! ! ! mF}b/mF_OTF_V{3{~ !}repeat 3 -1 $ ! findfont 1 ^ ~ definefont fM @ @ 5 0 put 4 0 put 90 matrix R matrix concatmatrix makefont Pscript_Windows_Font 3 1 $ put}b/UmF{L2?{Pscript_Windows_Font ~ undef}{!}?}b /UmF42{@ findfont/FDepVector get{/FontName get undefinefont}forall undefinefont}b %%EndResource end reinitialize Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Encoding256 5.0 0 /CharCol256Encoding[/.notdef/breve/caron/dotaccent/dotlessi/fi/fl/fraction /hungarumlaut/Lslash/lslash/minus/ogonek/ring/Zcaron/zcaron/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/exclam/quotedbl/numbersign /dollar/percent/ampersand/quotesingle/parenleft/parenright/asterisk/plus/comma /hyphen/period/slash/zero/one/two/three/four/five/six/seven/eight/nine/colon /semicolon/less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N/O/P/Q/R/S /T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright/asciicircum/underscore/grave /a/b/c/d/e/f/g/h/i/j/k/l/m/n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright /asciitilde/.notdef/Euro/.notdef/quotesinglbase/florin/quotedblbase/ellipsis /dagger/daggerdbl/circumflex/perthousand/Scaron/guilsinglleft/OE/.notdef /.notdef/.notdef/.notdef/quoteleft/quoteright/quotedblleft/quotedblright/bullet /endash/emdash/tilde/trademark/scaron/guilsinglright/oe/.notdef/.notdef /Ydieresis/.notdef/exclamdown/cent/sterling/currency/yen/brokenbar/section /dieresis/copyright/ordfeminine/guillemotleft/logicalnot/.notdef/registered /macron/degree/plusminus/twosuperior/threesuperior/acute/mu/paragraph /periodcentered/cedilla/onesuperior/ordmasculine/guillemotright/onequarter /onehalf/threequarters/questiondown/Agrave/Aacute/Acircumflex/Atilde/Adieresis /Aring/AE/Ccedilla/Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute /Icircumflex/Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute/Thorn/germandbls /agrave/aacute/acircumflex/atilde/adieresis/aring/ae/ccedilla/egrave/eacute /ecircumflex/edieresis/igrave/iacute/icircumflex/idieresis/eth/ntilde/ograve /oacute/ocircumflex/otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex /udieresis/yacute/thorn/ydieresis]def EncodeDict/256 CharCol256Encoding put %%EndResource end reinitialize %%IncludeResource: font Helvetica F /F0 0 /256 T /Helvetica mF /F0SB8 F0 [184.391 0 0 -184.391 0 0 ] mFS F0SB8 Ji 942 4354 M (0)S 1761 4354 M (1000)[103 103 103 0]xS 2734 4354 M (2000)[103 103 103 0]xS 3707 4354 M (3000)[103 103 103 0]xS 4680 4354 M (4000)[103 103 103 0]xS 5653 4354 M (5000)[103 103 103 0]xS 602 4185 M (-14)[62 103 0]xS 602 3593 M (-12)[62 103 0]xS 602 3002 M (-10)[62 103 0]xS 705 2410 M (-8)[62 0]xS 705 1818 M (-6)[62 0]xS 705 1227 M (-4)[62 0]xS 705 635 M (-2)[62 0]xS Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Win_GdiObject 5.0 0 /SavedCTM null d/CTMsave{/SavedCTM SavedCTM currentmatrix d}b/CTMrestore {SavedCTM setmatrix}b/mp null d/ADO_mxRot null d/GDIHMatrix null d /GDIHPatternDict 22 dict d GDIHPatternDict `/PatternType 1 d/PaintType 2 d/Reps L2?{1}{5}? d/XStep 8 Reps mul d/YStep XStep d/BBox[0 0 XStep YStep]d/TilingType 1 d/PaintProc{` 1 Lw[]0 sd PaintData , exec E}b/FGnd null d/BGnd null d /HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b/HS_BDiagonal {biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? d/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b /vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag{Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E/makehatch{4 -2 $/yOrg ~ d /xOrg ~ d GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix xOrg yOrg + mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0 /HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{/h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5 /HS_DiagCross makehatch}b/GDIBWPatternMx null d/pfprep{save 8 1 $ /PatternOfTheDay 8 1 $ GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/yExt ~ d/Width ~ d/BGnd ~ d/FGnd ~ d/Height yExt RepsV mul d/mx[Width 0 0 Height 0 0]d E build_pattern ~ !}b/pfbf{/fEOFill ~ d pfprep hbf fEOFill{O}{L}? restore}b /GraphInit{GDIHMatrix null eq{/SavedCTM matrix d : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ nonzero_dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly d ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E nonzero_dsnap +S/GDIBWPatternMx matrix currentmatrix readonly d ; ;}if}b %%EndResource %%BeginResource: file Pscript_Win_GdiObject_L2 5.0 0 /GDIBWPatternDict 25 dict @ `/PatternType 1 d/PaintType 1 d/RepsV 1 d/RepsH 1 d /BBox[0 0 RepsH 1]d/TilingType 1 d/XStep 1 d/YStep 1 d/Height 8 RepsV mul d /Width 8 d/mx[Width 0 0 Height neg 0 Height]d/FGnd null d/BGnd null d /SetBGndFGnd{BGnd null ne{BGnd aload ! scol BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! scol}if}b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E d/mp/makepattern , d /build_pattern{CTMsave GDIBWPatternMx setmatrix/nupangle where{! nupangle -90 eq{nupangle R}if}if GDIBWPatternDict @ ` Width Height ne{Width Height gt{Width Height V 1}{1 Height Width V}? +S}if xOrg yOrg E matrix + mp CTMrestore}b/hbf {setpattern}b/hf{:/fEOFill ~ d ~ ! setpattern fEOFill{O}{L}? ;}b/pbf{: ! /fEOFill ~ d GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/OutputBPP ~ d /Height ~ d/Width ~ d/PaintType 1 d/PatternType 1 d/TilingType 1 d/BBox[0 0 Width Height]d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d 20 dict @ ` /ImageType 1 d/Width Width d/Height Height d/ImageMatrix[1 0 0 1 0 0]d /BitsPerComponent 8 d OutputBPP 24 eq{/Decode[0 1 0 1 0 1]d}{OutputBPP 8 eq{ /Decode[0 1]d}{/Decode[0 1 0 1 0 1 0 1]d}?}?/DataSource{PaintData}d E/ImageDict ~ d/PaintProc{` ImageDict image E}b & mx makepattern setpattern E fEOFill{O}{L} ? ;}b/mask_pbf{:/fEOFill ~ d 20 dict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/Height ~ d/Width ~ d/PatternType 1 d/PaintType 2 d/TilingType 1 d/BBox[0 0 Width Height] d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d/PaintProc{` Width Height T[1 0 0 1 0 0]{PaintData}imagemask E}b & mx makepattern setpattern E fEOFill{O} {L}? ;}b %%EndResource end reinitialize 1 Lj 1 Lc 13 Lw solid N 994 4134 M 994 4065 I K N 1480 4134 M 1480 4099 I K N 1967 4134 M 1967 4065 I K N 2453 4134 M 2453 4099 I K N 2940 4134 M 2940 4065 I K N 3426 4134 M 3426 4099 I K N 3913 4134 M 3913 4065 I K N 4399 4134 M 4399 4099 I K N 4886 4134 M 4886 4065 I K N 5372 4134 M 5372 4099 I K N 5859 4134 M 5859 4065 I K N 6345 4134 M 6345 4099 I K N 945 4134 M 6345 4134 I K N 945 4134 M 1014 4134 I K N 945 3838 M 980 3838 I K N 945 3542 M 1014 3542 I K N 945 3246 M 980 3246 I K N 945 2951 M 1014 2951 I K N 945 2655 M 980 2655 I K N 945 2359 M 1014 2359 I K N 945 2063 M 980 2063 I K N 945 1767 M 1014 1767 I K N 945 1471 M 980 1471 I K N 945 1176 M 1014 1176 I K N 945 880 M 980 880 I K N 945 584 M 1014 584 I K N 945 288 M 980 288 I K N 945 4134 M 945 288 I K N 994 288 M 994 288 I K N 1480 288 M 1480 288 I K N 1967 288 M 1967 288 I K N 2453 288 M 2453 288 I K N 2940 288 M 2940 288 I K N 3426 288 M 3426 288 I K N 3913 288 M 3913 288 I K N 4399 288 M 4399 288 I K N 4886 288 M 4886 288 I K N 5372 288 M 5372 288 I K N 5859 288 M 5859 288 I K N 6345 288 M 6345 288 I K N 945 288 M 6345 288 I K N 6345 4134 M 6345 4134 I K N 6345 3838 M 6345 3838 I K N 6345 3542 M 6345 3542 I K N 6345 3246 M 6345 3246 I K N 6345 2951 M 6345 2951 I K N 6345 2655 M 6345 2655 I K N 6345 2359 M 6345 2359 I K N 6345 2063 M 6345 2063 I K N 6345 1767 M 6345 1767 I K N 6345 1471 M 6345 1471 I K N 6345 1176 M 6345 1176 I K N 6345 880 M 6345 880 I K N 6345 584 M 6345 584 I K N 6345 288 M 6345 288 I K N 6345 4134 M 6345 288 I K 0 Lj 7 Lw : 945 810 142 186 rc N 1041 855 M 946 855 I 946 950 I 1041 950 I C : O ; K ; N 1099 852 M 1004 852 I 1004 947 I 1099 947 I C : O ; K N 1215 944 M 1120 944 I 1120 1039 I 1215 1039 I C : O ; K N 1388 1202 M 1293 1202 I 1293 1297 I 1388 1297 I C : O ; K N 1618 1335 M 1523 1335 I 1523 1430 I 1618 1430 I C : O ; K N 1904 1601 M 1809 1601 I 1809 1696 I 1904 1696 I C : O ; K N 2244 1740 M 2149 1740 I 2149 1835 I 2244 1835 I C : O ; K N 2636 1900 M 2541 1900 I 2541 1995 I 2636 1995 I C : O ; K N 3080 2107 M 2985 2107 I 2985 2202 I 3080 2202 I C : O ; K N 3573 2417 M 3478 2417 I 3478 2512 I 3573 2512 I C : O ; K N 4114 2666 M 4019 2666 I 4019 2761 I 4114 2761 I C : O ; K N 4701 2669 M 4606 2669 I 4606 2764 I 4701 2764 I C : O ; K 1 Lj 8 Lw N 3959 2429 M 3959 2400 3935 2376 3905 2376 -c 3875 2376 3852 2400 3852 2429 -c 3852 2459 3875 2483 3905 2483 -c 3935 2483 3959 2459 3959 2429 -c C : 1 1 1 1 scol O ; K N 4015 2426 M 4015 2397 3991 2373 3961 2373 -c 3931 2373 3908 2397 3908 2426 -c 3908 2456 3931 2480 3961 2480 -c 3991 2480 4015 2456 4015 2426 -c C : 1 1 1 1 scol O ; K N 4127 2506 M 4127 2477 4103 2453 4073 2453 -c 4043 2453 4020 2477 4020 2506 -c 4020 2536 4043 2560 4073 2560 -c 4103 2560 4127 2536 4127 2506 -c C : 1 1 1 1 scol O ; K N 4295 2556 M 4295 2527 4271 2503 4241 2503 -c 4211 2503 4188 2527 4188 2556 -c 4188 2586 4211 2610 4241 2610 -c 4271 2610 4295 2586 4295 2556 -c C : 1 1 1 1 scol O ; K N 4516 2743 M 4516 2714 4492 2690 4462 2690 -c 4432 2690 4409 2714 4409 2743 -c 4409 2773 4432 2797 4462 2797 -c 4492 2797 4516 2773 4516 2743 -c C : 1 1 1 1 scol O ; K N 4792 2911 M 4792 2882 4768 2858 4738 2858 -c 4708 2858 4685 2882 4685 2911 -c 4685 2941 4708 2965 4738 2965 -c 4768 2965 4792 2941 4792 2911 -c C : 1 1 1 1 scol O ; K N 5120 3095 M 5120 3066 5096 3042 5066 3042 -c 5036 3042 5013 3066 5013 3095 -c 5013 3125 5036 3149 5066 3149 -c 5096 3149 5120 3125 5120 3095 -c C : 1 1 1 1 scol O ; K N 5498 3172 M 5498 3143 5474 3119 5444 3119 -c 5414 3119 5391 3143 5391 3172 -c 5391 3202 5414 3226 5444 3226 -c 5474 3226 5498 3202 5498 3172 -c C : 1 1 1 1 scol O ; K N 5926 3343 M 5926 3314 5902 3290 5872 3290 -c 5842 3290 5819 3314 5819 3343 -c 5819 3373 5842 3397 5872 3397 -c 5902 3397 5926 3373 5926 3343 -c C : 1 1 1 1 scol O ; K 5 Lw : 990 1038 5356 3097 rc N 994 1042 M 10098 6311 I K ; N 3251 492 M 3681 492 I K /F0SA9 F0 [169.172 0 0 -169.172 0 0 ] mFS F0SA9 Ji 3681 550 M ( Boltzmann distribution T)[47 113 95 38 47 85 142 95 95 95 47 95 38 85 47 57 38 95 95 47 38 95 95 47 0]xS /F0S65 F0 [101.145 0 0 -101.145 0 0 ] mFS F0S65 Ji 5556 616 M (S)S F0SA9 Ji 5623 550 M (=745 K)[99 95 95 95 47 0]xS 0 Lj 6 Lw N 3508 675 M 3423 675 I 3423 760 I 3508 760 I C : O ; K 3681 776 M ( v''=0)[47 85 32 32 99 0]xS 1 Lj 7 Lw N 3514 924 M 3514 897 3492 876 3465 876 -c 3438 876 3417 897 3417 924 -c 3417 951 3438 973 3465 973 -c 3492 973 3514 951 3514 924 -c C : 1 1 1 1 scol O ; K 3681 983 M ( v''=1)[47 85 32 32 99 0]xS /F0S00IFFFFFF76 F0 [0 -137.844 -137.844 0 0 0 ] mFS F0S00IFFFFFF76 Ji 6581 2322 M ( )S : 3626 0 38 148 rc /F0S89 F0 [137.844 0 0 -137.844 0 0 ] mFS F0S89 Ji 3626 117 M ( )S ; /F0S00IFFFFFF29 F0 [0 -214.824 -214.824 0 0 0 ] mFS F0S00IFFFFFF29 Ji 437 3505 M (ln[N\(v'',J''\) / \(2J''+1\) / g)[-48 -120 -60 -155 -72 -108 -41 -41 -60 -108 -41 -41 -72 -60 -60 -60 -72 -120 -108 -41 -41 -126 -120 -72 -60 -60 -60 0]yS /F0S00IFFFFFF7F F0 [0 -128.895 -128.895 0 0 0 ] mFS F0S00IFFFFFF7F Ji 520 1359 M (n)S F0S00IFFFFFF29 Ji 437 1289 M (])S /F0SD6 F0 [214.824 0 0 -214.824 0 0 ] mFS F0SD6 Ji 2640 4668 M (internal energy [cm)[48 120 60 120 72 120 120 48 60 120 120 120 72 120 108 60 60 108 0]xS /F0S80 F0 [128.895 0 0 -128.895 0 0 ] mFS F0S80 Ji 4475 4550 M (-1)[43 0]xS F0SD6 Ji 4590 4668 M (])S LH %%PageTrailer %%Trailer %%DocumentNeededResources: %%+ font Helvetica %%DocumentSuppliedResources: %%+ procset Pscript_WinNT_ErrorHandler 5.0 0 %%+ procset Pscript_FatalError 5.0 0 %%+ procset Pscript_Win_Basic 5.0 0 %%+ procset Pscript_Win_Utils_L2 5.0 0 %%+ procset Pscript_Text 5.0 0 %%+ procset Pscript_Encoding256 5.0 0 %%+ procset Pscript_Win_GdiObject 5.0 0 %%+ procset Pscript_Win_GdiObject_L2 5.0 0 Pscript_WinNT_Incr dup /terminate get exec %%EOF %%EndDocument @endspecial 170 x Fo(FIG.)26 b(1:)36 b(Measured)26 b(ro)n(vibrational) h(p)r(opulation)g Fk(N)8 b Fo(\()p Fk(v)1461 1433 y Fj(00)1502 1465 y Fk(;)13 b(J)1585 1433 y Fj(00)1626 1465 y Fo(\))25 b(for)i(D)1858 1473 y Fn(2)-150 1552 y Fo(desorbing)41 b(from)e(S/Pd\(100\))i(at)f Fk(T)950 1560 y Fl(S)1040 1552 y Fo(=)45 b(745)14 b(K.)40 b(Filled)h(squares:)-150 1639 y(D)-91 1647 y Fn(2)-57 1639 y Fo(\()p Fk(v)13 1607 y Fj(00)86 1639 y Fo(=)31 b(0\);)36 b(op)r(en)c(circles:)49 b(D)827 1647 y Fn(2)861 1639 y Fo(\()p Fk(v)931 1607 y Fj(00)1004 1639 y Fo(=)31 b(1\);)36 b(line:)48 b(p)r(opulation)32 b(for)-150 1726 y Fk(T)-105 1734 y Fl(S)-39 1726 y Fo(=)21 b(745)14 b(K.)-150 2071 y Fg(N)-83 2083 y Fh(B)-33 2071 y Fr(\()p Fg(v)42 2041 y Fq(00)85 2071 y Fg(;)g(J)176 2041 y Fq(00)219 2071 y Fg(;)g(T)305 2083 y Ff(S)352 2071 y Fr(\),)25 b(is)e(prop)r(ortional)f(to)i(the)g(relativ)n(e)e (desorption)-150 2167 y(probabilit)n(y)-7 b(.)59 b(F)-7 b(or)34 b(molecules)h(desorbing)f(in)h(the)h(vibrational)-150 2262 y(ground)26 b(state)g(the)i(results)e(are)g(sho)n(wn)g(in)h(a)f (semi-logarithmic)-150 2358 y(plot)d(in)h(\014gure)e(3.)35 b(These)23 b(results)f(sho)n(w)h(\014rst)g(a)f(decrease)g(of)h(the)-150 2453 y(desorption)g(probabilit)n(y)g(up)h(to)g Fg(J)942 2423 y Fq(00)1007 2453 y Fr(=)f(5)g(and)h(then)g(an)g(increas-)-150 2549 y(ing)40 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(900)[103 103 0]xS 561 4185 M (300)[103 103 0]xS 561 3636 M (400)[103 103 0]xS 561 3086 M (500)[103 103 0]xS 561 2537 M (600)[103 103 0]xS 561 1987 M (700)[103 103 0]xS 561 1438 M (800)[103 103 0]xS 561 888 M (900)[103 103 0]xS 458 339 M (1000)[103 103 103 0]xS Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Win_GdiObject 5.0 0 /SavedCTM null d/CTMsave{/SavedCTM SavedCTM currentmatrix d}b/CTMrestore {SavedCTM setmatrix}b/mp null d/ADO_mxRot null d/GDIHMatrix null d /GDIHPatternDict 22 dict d GDIHPatternDict `/PatternType 1 d/PaintType 2 d/Reps L2?{1}{5}? d/XStep 8 Reps mul d/YStep XStep d/BBox[0 0 XStep YStep]d/TilingType 1 d/PaintProc{` 1 Lw[]0 sd PaintData , exec E}b/FGnd null d/BGnd null d /HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b/HS_BDiagonal {biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? d/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b /vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag{Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E/makehatch{4 -2 $/yOrg ~ d /xOrg ~ d GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix xOrg yOrg + mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0 /HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{/h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5 /HS_DiagCross makehatch}b/GDIBWPatternMx null d/pfprep{save 8 1 $ /PatternOfTheDay 8 1 $ GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/yExt ~ d/Width ~ d/BGnd ~ d/FGnd ~ d/Height yExt RepsV mul d/mx[Width 0 0 Height 0 0]d E build_pattern ~ !}b/pfbf{/fEOFill ~ d pfprep hbf fEOFill{O}{L}? restore}b /GraphInit{GDIHMatrix null eq{/SavedCTM matrix d : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ nonzero_dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly d ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E nonzero_dsnap +S/GDIBWPatternMx matrix currentmatrix readonly d ; ;}if}b %%EndResource %%BeginResource: file Pscript_Win_GdiObject_L2 5.0 0 /GDIBWPatternDict 25 dict @ `/PatternType 1 d/PaintType 1 d/RepsV 1 d/RepsH 1 d /BBox[0 0 RepsH 1]d/TilingType 1 d/XStep 1 d/YStep 1 d/Height 8 RepsV mul d /Width 8 d/mx[Width 0 0 Height neg 0 Height]d/FGnd null d/BGnd null d /SetBGndFGnd{BGnd null ne{BGnd aload ! scol BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! scol}if}b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E d/mp/makepattern , d /build_pattern{CTMsave GDIBWPatternMx setmatrix/nupangle where{! nupangle -90 eq{nupangle R}if}if GDIBWPatternDict @ ` Width Height ne{Width Height gt{Width Height V 1}{1 Height Width V}? +S}if xOrg yOrg E matrix + mp CTMrestore}b/hbf {setpattern}b/hf{:/fEOFill ~ d ~ ! setpattern fEOFill{O}{L}? ;}b/pbf{: ! /fEOFill ~ d GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/OutputBPP ~ d /Height ~ d/Width ~ d/PaintType 1 d/PatternType 1 d/TilingType 1 d/BBox[0 0 Width Height]d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d 20 dict @ ` /ImageType 1 d/Width Width d/Height Height d/ImageMatrix[1 0 0 1 0 0]d /BitsPerComponent 8 d OutputBPP 24 eq{/Decode[0 1 0 1 0 1]d}{OutputBPP 8 eq{ /Decode[0 1]d}{/Decode[0 1 0 1 0 1 0 1]d}?}?/DataSource{PaintData}d E/ImageDict ~ d/PaintProc{` ImageDict image E}b & mx makepattern setpattern E fEOFill{O}{L} ? ;}b/mask_pbf{:/fEOFill ~ d 20 dict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/Height ~ d/Width ~ d/PatternType 1 d/PaintType 2 d/TilingType 1 d/BBox[0 0 Width Height] d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d/PaintProc{` Width Height T[1 0 0 1 0 0]{PaintData}imagemask E}b & mx makepattern setpattern E fEOFill{O} {L}? ;}b %%EndResource end reinitialize 1 Lj 1 Lc 13 Lw solid N 945 4134 M 945 4065 I K N 1485 4134 M 1485 4099 I K N 2025 4134 M 2025 4065 I K N 2565 4134 M 2565 4099 I K N 3105 4134 M 3105 4065 I K N 3645 4134 M 3645 4099 I K N 4185 4134 M 4185 4065 I K N 4725 4134 M 4725 4099 I K N 5265 4134 M 5265 4065 I K N 5805 4134 M 5805 4099 I K N 6345 4134 M 6345 4065 I K N 945 4134 M 6345 4134 I K N 945 4134 M 1014 4134 I K N 945 3859 M 980 3859 I K N 945 3585 M 1014 3585 I K N 945 3310 M 980 3310 I K N 945 3035 M 1014 3035 I K N 945 2760 M 980 2760 I K N 945 2486 M 1014 2486 I K N 945 2211 M 980 2211 I K N 945 1936 M 1014 1936 I K N 945 1662 M 980 1662 I K N 945 1387 M 1014 1387 I K N 945 1112 M 980 1112 I K N 945 837 M 1014 837 I K N 945 563 M 980 563 I K N 945 288 M 1014 288 I K N 945 4134 M 945 288 I K N 945 288 M 945 288 I K N 1485 288 M 1485 288 I K N 2025 288 M 2025 288 I K N 2565 288 M 2565 288 I K N 3105 288 M 3105 288 I K N 3645 288 M 3645 288 I K N 4185 288 M 4185 288 I K N 4725 288 M 4725 288 I K N 5265 288 M 5265 288 I K N 5805 288 M 5805 288 I K N 6345 288 M 6345 288 I K N 945 288 M 6345 288 I K N 6345 4134 M 6345 4134 I K N 6345 3859 M 6345 3859 I K N 6345 3585 M 6345 3585 I K N 6345 3310 M 6345 3310 I K N 6345 3035 M 6345 3035 I K N 6345 2760 M 6345 2760 I K N 6345 2486 M 6345 2486 I K N 6345 2211 M 6345 2211 I K N 6345 1936 M 6345 1936 I K N 6345 1662 M 6345 1662 I K N 6345 1387 M 6345 1387 I K N 6345 1112 M 6345 1112 I K N 6345 837 M 6345 837 I K N 6345 563 M 6345 563 I K N 6345 288 M 6345 288 I K N 6345 4134 M 6345 288 I K 0 Lj 7 Lw N 2029 3648 M 1934 3648 I 1934 3743 I 2029 3743 I C : O ; K N 2580 3413 M 2485 3413 I 2485 3508 I 2580 3508 I C : O ; K N 3163 3331 M 3068 3331 I 3068 3426 I 3163 3426 I C : O ; K N 3627 2759 M 3532 2759 I 3532 2854 I 3627 2854 I C : O ; K N 4102 2360 M 4007 2360 I 4007 2455 I 4102 2455 I C : O ; K N 4718 2253 M 4623 2253 I 4623 2348 I 4718 2348 I C : O ; K N 5323 1968 M 5228 1968 I 5228 2063 I 5323 2063 I C : O ; K 1 Lj 8 Lw N 2035 3779 M 2035 3750 2011 3726 1981 3726 -c 1951 3726 1928 3750 1928 3779 -c 1928 3809 1951 3833 1981 3833 -c 2011 3833 2035 3809 2035 3779 -c C : 1 1 1 1 scol O ; K N 2586 2914 M 2586 2885 2562 2861 2532 2861 -c 2502 2861 2479 2885 2479 2914 -c 2479 2944 2502 2968 2532 2968 -c 2562 2968 2586 2944 2586 2914 -c C : 1 1 1 1 scol O ; K N 3169 2070 M 3169 2041 3145 2017 3115 2017 -c 3085 2017 3062 2041 3062 2070 -c 3062 2100 3085 2124 3115 2124 -c 3145 2124 3169 2100 3169 2070 -c C : 1 1 1 1 scol O ; K N 3633 2525 M 3633 2496 3609 2472 3579 2472 -c 3549 2472 3526 2496 3526 2525 -c 3526 2555 3549 2579 3579 2579 -c 3609 2579 3633 2555 3633 2525 -c C : 1 1 1 1 scol O ; K N 4108 1207 M 4108 1178 4084 1154 4054 1154 -c 4024 1154 4001 1178 4001 1207 -c 4001 1237 4024 1261 4054 1261 -c 4084 1261 4108 1237 4108 1207 -c C : 1 1 1 1 scol O ; K N 4724 973 M 4724 944 4700 920 4670 920 -c 4640 920 4617 944 4617 973 -c 4617 1003 4640 1027 4670 1027 -c 4700 1027 4724 1003 4724 973 -c C : 1 1 1 1 scol O ; K N 5329 1355 M 5329 1326 5305 1302 5275 1302 -c 5245 1302 5222 1326 5222 1355 -c 5222 1385 5245 1409 5275 1409 -c 5305 1409 5329 1385 5329 1355 -c C : 1 1 1 1 scol O ; K 18 Lw : 945 288 5401 3847 rc N -3375 5782 M 9585 -811 I K ; 13 Lw N 1436 3386 M 1378 3414 I K N 1313 3445 M 1255 3473 I K N 1190 3504 M 1132 3532 I K N 1067 3563 M 1009 3591 I K N 1976 3129 M 1918 3157 I K N 1853 3188 M 1795 3215 I K N 1730 3246 M 1672 3274 I K N 1607 3305 M 1549 3333 I K N 2516 2874 M 2458 2901 I K N 2393 2932 M 2335 2960 I K N 2270 2990 M 2212 3018 I K N 2147 3048 M 2089 3076 I K N 3056 2621 M 2998 2648 I K N 2933 2679 M 2875 2706 I K N 2810 2736 M 2752 2763 I K N 2687 2794 M 2629 2821 I K N 3596 2370 M 3538 2397 I K N 3473 2427 M 3415 2454 I K N 3350 2484 M 3292 2511 I K N 3227 2541 M 3169 2568 I K N 4136 2120 M 4078 2147 I K N 4013 2177 M 3955 2204 I K N 3890 2234 M 3832 2260 I K N 3767 2290 M 3709 2317 I K N 4676 1872 M 4618 1899 I K N 4553 1928 M 4495 1955 I K N 4430 1984 M 4372 2011 I K N 4307 2041 M 4249 2067 I K N 5216 1625 M 5158 1652 I K N 5093 1681 M 5035 1708 I K N 4970 1737 M 4912 1764 I K N 4847 1794 M 4789 1820 I K N 5756 1381 M 5698 1407 I K N 5633 1437 M 5575 1463 I K N 5510 1492 M 5452 1519 I K N 5387 1548 M 5329 1574 I K N 6296 1138 M 6238 1164 I K N 6173 1193 M 6115 1219 I K N 6050 1249 M 5992 1275 I K N 5927 1304 M 5869 1330 I K 0 Lj 5 Lw : 945 3554 67 134 rc N 976 3589 M 913 3589 I 913 3652 I 976 3652 I C : O ; K ; N 1516 3331 M 1453 3331 I 1453 3394 I 1516 3394 I C : O ; K N 2056 3074 M 1993 3074 I 1993 3137 I 2056 3137 I C : O ; K N 2596 2819 M 2533 2819 I 2533 2882 I 2596 2882 I C : O ; K N 3136 2566 M 3073 2566 I 3073 2629 I 3136 2629 I C : O ; K N 3676 2315 M 3613 2315 I 3613 2378 I 3676 2378 I C : O ; K N 4216 2065 M 4153 2065 I 4153 2128 I 4216 2128 I C : O ; K N 4756 1817 M 4693 1817 I 4693 1880 I 4756 1880 I C : O ; K N 5296 1571 M 5233 1571 I 5233 1634 I 5296 1634 I C : O ; K N 5836 1327 M 5773 1327 I 5773 1390 I 5836 1390 I C : O ; K : 6278 1049 68 134 rc N 6376 1084 M 6313 1084 I 6313 1147 I 6376 1147 I C : O ; K ; 1 Lj 13 Lw N 1436 3525 M 1410 3536 I K N 1380 3549 M 1354 3561 I K N 1324 3574 M 1298 3585 I K N 1268 3598 M 1242 3609 I K N 1212 3622 M 1186 3634 I K N 1156 3647 M 1130 3658 I K N 1100 3671 M 1074 3682 I K N 1044 3695 M 1018 3707 I K N 1976 3287 M 1950 3298 I K N 1920 3312 M 1894 3323 I K N 1864 3336 M 1838 3348 I K N 1808 3361 M 1782 3372 I K N 1752 3385 M 1726 3397 I K N 1696 3410 M 1670 3421 I K N 1640 3434 M 1614 3446 I K N 1584 3459 M 1558 3470 I K N 2516 3046 M 2490 3058 I K N 2460 3071 M 2434 3083 I K N 2404 3096 M 2378 3108 I K N 2348 3121 M 2322 3132 I K N 2292 3146 M 2266 3157 I K N 2236 3171 M 2210 3182 I K N 2180 3196 M 2154 3207 I K N 2124 3221 M 2098 3232 I K N 3056 2803 M 3030 2815 I K N 3000 2828 M 2974 2840 I K N 2944 2853 M 2918 2865 I K N 2888 2879 M 2862 2890 I K N 2832 2904 M 2806 2916 I K N 2776 2929 M 2750 2941 I K N 2720 2954 M 2694 2966 I K N 2664 2979 M 2638 2991 I K N 3596 2558 M 3570 2570 I K N 3540 2583 M 3514 2595 I K N 3484 2609 M 3458 2621 I K N 3428 2634 M 3402 2646 I K N 3372 2660 M 3346 2672 I K N 3316 2685 M 3290 2697 I K N 3260 2711 M 3234 2723 I K N 3204 2736 M 3178 2748 I K N 4136 2311 M 4110 2323 I K N 4080 2337 M 4054 2349 I K N 4024 2362 M 3998 2374 I K N 3968 2388 M 3942 2400 I K N 3912 2414 M 3886 2426 I K N 3856 2440 M 3830 2452 I K N 3800 2465 M 3774 2477 I K N 3744 2491 M 3718 2503 I K N 4676 2064 M 4650 2076 I K N 4620 2090 M 4594 2102 I K N 4564 2115 M 4538 2127 I K N 4508 2141 M 4482 2153 I K N 4452 2167 M 4426 2179 I K N 4396 2193 M 4370 2205 I K N 4340 2218 M 4314 2230 I K N 4284 2244 M 4258 2256 I K N 5216 1818 M 5190 1830 I K N 5160 1844 M 5134 1855 I K N 5104 1869 M 5078 1881 I K N 5048 1895 M 5022 1907 I K N 4992 1920 M 4966 1932 I K N 4936 1946 M 4910 1958 I K N 4880 1972 M 4854 1983 I K N 4824 1997 M 4798 2009 I K N 5756 1572 M 5730 1584 I K N 5700 1598 M 5674 1609 I K N 5644 1623 M 5618 1635 I K N 5588 1649 M 5562 1661 I K N 5532 1674 M 5506 1686 I K N 5476 1700 M 5450 1712 I K N 5420 1726 M 5394 1737 I K N 5364 1751 M 5338 1763 I K N 6296 1326 M 6270 1338 I K N 6240 1352 M 6214 1363 I K N 6184 1377 M 6158 1389 I K N 6128 1403 M 6102 1415 I K N 6072 1428 M 6046 1440 I K N 6016 1454 M 5990 1466 I K N 5960 1480 M 5934 1491 I K N 5904 1505 M 5878 1517 I K 5 Lw : 945 3699 40 80 rc N 980 3738 M 980 3718 964 3703 944 3703 -c 924 3703 909 3718 909 3738 -c 909 3758 924 3774 944 3774 -c 964 3774 980 3758 980 3738 -c C : 1 1 1 1 scol O ; K ; N 1520 3502 M 1520 3482 1504 3467 1484 3467 -c 1464 3467 1449 3482 1449 3502 -c 1449 3522 1464 3538 1484 3538 -c 1504 3538 1520 3522 1520 3502 -c C : 1 1 1 1 scol O ; K N 2060 3264 M 2060 3244 2044 3229 2024 3229 -c 2004 3229 1989 3244 1989 3264 -c 1989 3284 2004 3300 2024 3300 -c 2044 3300 2060 3284 2060 3264 -c C : 1 1 1 1 scol O ; K N 2600 3023 M 2600 3003 2584 2988 2564 2988 -c 2544 2988 2529 3003 2529 3023 -c 2529 3043 2544 3059 2564 3059 -c 2584 3059 2600 3043 2600 3023 -c C : 1 1 1 1 scol O ; K N 3140 2780 M 3140 2760 3124 2745 3104 2745 -c 3084 2745 3069 2760 3069 2780 -c 3069 2800 3084 2816 3104 2816 -c 3124 2816 3140 2800 3140 2780 -c C : 1 1 1 1 scol O ; K N 3680 2535 M 3680 2515 3664 2500 3644 2500 -c 3624 2500 3609 2515 3609 2535 -c 3609 2555 3624 2571 3644 2571 -c 3664 2571 3680 2555 3680 2535 -c C : 1 1 1 1 scol O ; K N 4220 2288 M 4220 2268 4204 2253 4184 2253 -c 4164 2253 4149 2268 4149 2288 -c 4149 2308 4164 2324 4184 2324 -c 4204 2324 4220 2308 4220 2288 -c C : 1 1 1 1 scol O ; K N 4760 2041 M 4760 2021 4744 2006 4724 2006 -c 4704 2006 4689 2021 4689 2041 -c 4689 2061 4704 2077 4724 2077 -c 4744 2077 4760 2061 4760 2041 -c C : 1 1 1 1 scol O ; K N 5300 1795 M 5300 1775 5284 1760 5264 1760 -c 5244 1760 5229 1775 5229 1795 -c 5229 1815 5244 1831 5264 1831 -c 5284 1831 5300 1815 5300 1795 -c C : 1 1 1 1 scol O ; K N 5840 1549 M 5840 1529 5824 1514 5804 1514 -c 5784 1514 5769 1529 5769 1549 -c 5769 1569 5784 1585 5804 1585 -c 5824 1585 5840 1569 5840 1549 -c C : 1 1 1 1 scol O ; K : 6305 1264 41 80 rc N 6380 1303 M 6380 1283 6364 1268 6344 1268 -c 6324 1268 6309 1283 6309 1303 -c 6309 1323 6324 1339 6344 1339 -c 6364 1339 6380 1323 6380 1303 -c C : 1 1 1 1 scol O ; K ; 18 Lw N 1070 460 M 1459 460 I K /F0S99 F0 [153.063 0 0 -153.063 0 0 ] mFS F0S99 Ji 1459 512 M ( thermal equilibrium T)[43 43 85 85 51 127 85 34 43 85 85 85 34 34 34 85 51 34 85 127 43 0]xS /F0S5B F0 [91.297 0 0 -91.297 0 0 ] mFS F0S5B Ji 2933 572 M (rot)[30 51 0]xS F0S99 Ji 3039 512 M (=T)[89 0]xS F0S5B Ji 3224 572 M (S)S 0 Lj 6 Lw N 1301 626 M 1226 626 I 1226 701 I 1301 701 I C : O ; K F0S99 Ji 1459 716 M ( experiment v=0 D)[43 85 76 85 85 51 34 127 85 85 43 43 77 89 85 43 0]xS F0S5B Ji 2705 776 M (2)S F0S99 Ji 2756 716 M ( S/Pd\(100\))[43 102 43 102 85 51 85 85 85 0]xS 1 Lj 7 Lw N 1307 867 M 1307 843 1287 824 1263 824 -c 1239 824 1220 843 1220 867 -c 1220 891 1239 911 1263 911 -c 1287 911 1307 891 1307 867 -c C : 1 1 1 1 scol O ; K 1459 920 M ( experiment v=1 D)[43 85 76 85 85 51 34 127 85 85 43 43 77 89 85 43 0]xS F0S5B Ji 2705 980 M (2)S F0S99 Ji 2756 920 M ( S/Pd\(100\))[43 102 43 102 85 51 85 85 85 0]xS 13 Lw N 1070 1072 M 1128 1072 I K N 1193 1072 M 1251 1072 I K N 1316 1072 M 1374 1072 I K N 1439 1072 M 1458 1072 I K 0 Lj 6 Lw N 1301 1034 M 1226 1034 I 1226 1109 I 1301 1109 I C : O ; K 1459 1124 M ( theory v=0 H)[43 43 85 85 85 51 76 43 77 89 85 43 0]xS F0S5B Ji 2374 1184 M (2)S F0S99 Ji 2425 1124 M ( / p\(2x2\) S/Pd\(100\))[43 43 43 85 51 85 76 85 51 43 102 43 102 85 51 85 85 85 0]xS 1 Lj 13 Lw N 1070 1276 M 1096 1276 I K N 1126 1276 M 1152 1276 I K N 1182 1276 M 1208 1276 I K N 1238 1276 M 1264 1276 I K N 1294 1276 M 1320 1276 I K N 1350 1276 M 1376 1276 I K N 1406 1276 M 1432 1276 I K 7 Lw N 1307 1275 M 1307 1251 1287 1232 1263 1232 -c 1239 1232 1220 1251 1220 1275 -c 1220 1299 1239 1319 1263 1319 -c 1287 1319 1307 1299 1307 1275 -c C : 1 1 1 1 scol O ; K 1459 1328 M ( theory v=1 H)[43 43 85 85 85 51 76 43 77 89 85 43 0]xS F0S5B Ji 2374 1388 M (2)S F0S99 Ji 2425 1328 M ( / p\(2x2\) S/Pd\(100\))[43 43 43 85 51 85 76 85 51 43 102 43 102 85 51 85 85 85 0]xS /F0S00IFFFFFF56 F0 [0 -169.172 -169.172 0 0 0 ] mFS F0S00IFFFFFF56 Ji 6610 2347 M ( )S : 3622 0 47 142 rc /F0SA9 F0 [169.172 0 0 -169.172 0 0 ] mFS F0SA9 Ji 3622 105 M ( )S ; /F0S00IFFFFFF29 F0 [0 -214.824 -214.824 0 0 0 ] mFS F0S00IFFFFFF29 Ji 340 4103 M (rotational temperature / k)[-126 -60 -60 -60 0]yS F0S00IFFFFFF7F Ji 423 1102 M (B)S F0S00IFFFFFF29 Ji 340 1018 M ( [K])[-60 -60 -60 -143 0]yS /F0SD6 F0 [214.824 0 0 -214.824 0 0 ] mFS F0SD6 Ji 2350 4645 M (surface temperature T)[108 120 72 60 120 108 120 60 60 120 179 120 120 72 120 60 120 72 120 60 0]xS /F0S80 F0 [128.895 0 0 -128.895 0 0 ] mFS F0S80 Ji 4472 4729 M (S)S F0SD6 Ji 4558 4645 M ( [K])[60 60 60 143 0]xS LH %%PageTrailer %%Trailer %%DocumentNeededResources: %%+ font Helvetica %%DocumentSuppliedResources: %%+ procset Pscript_WinNT_ErrorHandler 5.0 0 %%+ procset Pscript_FatalError 5.0 0 %%+ procset Pscript_Win_Basic 5.0 0 %%+ procset Pscript_Win_Utils_L2 5.0 0 %%+ procset Pscript_Text 5.0 0 %%+ procset Pscript_Encoding256 5.0 0 %%+ procset Pscript_Win_GdiObject 5.0 0 %%+ procset Pscript_Win_GdiObject_L2 5.0 0 Pscript_WinNT_Incr dup /terminate get exec %%EOF %%EndDocument @endspecial 170 x Fo(FIG.)34 b(2:)52 b(Rotational)35 b(energy)e Fk(E)3045 1475 y Fh(rot)3168 1465 y Fo(plotted)h(as)g Fk(T)3588 1475 y Fh(rot)3713 1465 y Fo(=)g Fk(E)3864 1475 y Fh(rot)3953 1465 y Fk(=k)4031 1473 y Fl(B)2042 1552 y Fo(v)n(ersus)28 b(the)g(surface)i(temp)r(erature)e Fk(T)3159 1560 y Fl(S)3203 1552 y Fo(.)43 b(Filled)30 b(squares:)40 b(D)3853 1560 y Fn(2)3888 1552 y Fo(\()p Fk(v)3958 1520 y Fj(00)4024 1552 y Fo(=)2042 1639 y(0\);)30 b(op)r(en)e(circles:)42 b(D)2675 1647 y Fn(2)2709 1639 y Fo(\()p Fk(v)2779 1607 y Fj(00)2845 1639 y Fo(=)26 b(1\);)k(solid)g(line:)40 b(thermal)28 b(equilibrium)2042 1726 y(with)i Fk(T)2266 1736 y Fh(rot)2383 1726 y Fo(=)e Fk(T)2516 1734 y Fl(S)2560 1726 y Fo(.)47 b(Theoretical)31 b(results)f(for)h(H)3465 1734 y Fn(2)3499 1726 y Fo(\()p Fk(v)3569 1695 y Fj(00)3638 1726 y Fo(=)d(0\))h(\(dashed)2042 1813 y(line\))21 b(and)f(H)2414 1821 y Fn(2)2448 1813 y Fo(\()p Fk(v)2518 1782 y Fj(00)2580 1813 y Fo(=)h(1\))f(\(dotted)g (line\))h(desorbing)g(from)g(the)f(p\(2)7 b Fm(\002)g Fo(2\))2042 1901 y(S/Pd\(100\))26 b(surface)h(are)f(also)h(sho)n(wn.) 2042 3569 y @beginspecial 20 @llx 245 @lly 810 @urx 810 @ury 2450 @rwi @setspecial %%BeginDocument: ne_nt_v01.ps %!PS-Adobe-3.0 EPSF-3.0 %%Title: v=0+1 ne/nt %%Creator: Pscript.dll Version 5.0 %%CreationDate: 4/9/2002 13:11:30 %%For: rutkowm %%BoundingBox: 20 245 810 810 %%Pages: 1 %%Orientation: Landscape %%PageOrder: Ascend %%DocumentNeededResources: (atend) %%DocumentSuppliedResources: (atend) %%DocumentData: Clean7Bit %%TargetDevice: (Colorwriter LSR 2000) (2015.108) 0 %%LanguageLevel: 2 %%EndComments %%BeginDefaults %%PageBoundingBox: 20 9 830 586 %%EndDefaults %%BeginProlog %%BeginResource: file Pscript_WinNT_ErrorHandler 5.0 0 /currentpacking where{pop/oldpack currentpacking def/setpacking 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dann erneut:) 100 485(Wählen Sie für das Ausgabeformat die Option "Optimale Portierung".)115 470 (Stellen Sie sicher, daß auf der Registerkarte "Geräteeinstellungen" die Angabe für "Verfügbarer Postscript-Speicher" korrekt ist.) 115 455(Reduzieren Sie die Anzahl der im Dokument verwendeten Schriftarten. ) 115 440(Drucken Sie das Dokument in verschiedenen Teilstücken. )115 425 12 /Times-Roman showpage(%%[ PrinterError: Low Printer VM ]%%)= true FatalErrorIf} if}bind def end version cvi 2016 ge{/VM?{pop}bind def}{/VM? userdict/PrtVMMsg get def}ifelse %%BeginResource: file Pscript_Win_Basic 5.0 0 /d/def load def/,/load load d/~/exch , d/?/ifelse , d/!/pop , d/`/begin , d/^ /index , d/@/dup , d/+/translate , d/$/roll , d/U/userdict , d/M/moveto , d/- /rlineto , d/&/currentdict , d/:/gsave , d/;/grestore , d/F/false , d/T/true , d/N/newpath , d/E/end , d/Ac/arc , d/An/arcn , d/A/ashow , d/D/awidthshow , d/C /closepath , d/V/div , d/O/eofill , d/L/fill , d/I/lineto , d/-c/curveto , d/-M 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F d reinitialize E}{U /Pscript_Win_Data 230 dict @ ` put/ADO_mxRot ~ d/TextInitialised? F d reinitialize}?}b/terminate{!{& self eq{exit}{E}?}loop E}b/suspend/terminate , d /resume{` Pscript_Win_Data `}b U `/lucas 21690 d/featurebegin{countdictstack lucas[}b/featurecleanup{stopped{cleartomark @ lucas eq{! exit}if}loop countdictstack ~ sub @ 0 gt{{E}repeat}{!}?}b E/snap{transform 0.25 sub round 0.25 add ~ 0.25 sub round 0.25 add ~ itransform}b/dsnap{dtransform round ~ round ~ idtransform}b/nonzero_round{@ 0.5 ge{round}{@ -0.5 lt{round}{0 ge{1} {-1}?}?}?}b/nonzero_dsnap{dtransform nonzero_round ~ nonzero_round ~ idtransform}b U<04>cvn{}put/rr{1 ^ 0 - 0 ~ - neg 0 - C}b/irp{4 -2 $ + +S fx 4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/rp{4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/solid{[]0 sd}b/g {@ not{U/DefIf_save save put}if U/DefIf_bool 2 ^ put}b/DefIf_El{if U/DefIf_bool get not @{U/DefIf_save get restore}if}b/e{DefIf_El !}b/UDF{L2?{undefinefont}{!} ?}b/UDR{L2?{undefineresource}{! !}?}b/freeVM{/Courier findfont[40 0 0 -40 0 0] makefont Ji 2 vmreclaim}b %%EndResource %%BeginResource: file Pscript_Win_Utils_L2 5.0 0 /rf/rectfill , d/fx{1 1 dtransform @ 0 ge{1 sub 0.5}{1 add -0.5}? 3 -1 $ @ 0 ge {1 sub 0.5}{1 add -0.5}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{4 -2 $ snap + +S fx rf}b/rs/rectstroke , d/rc/rectclip , d/UtilsInit{currentglobal{F setglobal}if}b/scol{! setcolor}b/colspA/DeviceGray d/colspABC/DeviceRGB d /colspRefresh{colspABC setcolorspace}b/SetColSpace{colspABC setcolorspace}b /resourcestatus where{!/ColorRendering/ProcSet resourcestatus{! ! T}{F}?}{F}? not{/ColorRendering<>/defineresource where{!/ProcSet defineresource !}{! !}?}if/buildcrdname{/ColorRendering/ProcSet findresource ` mark GetHalftoneName @ type @/nametype ne ~/stringtype ne and{!/none}if(.) GetPageDeviceName @ type @/nametype ne ~/stringtype ne and{!/none}if(.)5 ^ 0 5 -1 1{^ length add}for string 6 1 $ 5 ^ 5{~ 1 ^ cvs length 1 ^ length 1 ^ sub getinterval}repeat ! cvn 3 1 $ ! ! E}b/definecolorrendering{~ buildcrdname ~ /ColorRendering defineresource !}b/findcolorrendering where{!}{ /findcolorrendering{buildcrdname @/ColorRendering resourcestatus{! ! 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EncodeDict/ANSIEncodingOld get} if}if}if d E}b/mF{@ 7 1 $ findfont ~{@/Encoding get @ StandardEncoding eq{! T}{ {ISOLatin1Encoding}stopped{! F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{1 ^ ~ rF}{0 copyfont}? 6 -2 $ ! ! ~ !/pd_charset @ where{~ get 128 eq{@ FDV 2 copy get @ length array copy put pd_CoverFCRange}if}{!}? 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/xUP null d/yUP null d/uW null d/xSP null d/ySP null d/sW null d/sSU{N /uW ~ d/yUP ~ d/xUP ~ d}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ d/ySP ~ d/xSP ~ d}b/sT {xSP ySP sW sLT}b/sR{: + R 0 0 M}b/sRxy{: matrix astore concat 0 0 M}b/eR/; , d /AddOrigFP{{&/FontInfo known{&/FontInfo get length 6 add}{6}? dict ` /WinPitchAndFamily ~ d/WinCharSet ~ d/OrigFontType ~ d/OrigFontStyle ~ d /OrigFontName ~ d & E/FontInfo ~ d}{! ! ! ! !}?}b/mFS{makefont Pscript_Windows_Font 3 1 $ put}b/mF42D{0 copyfont `/FontName ~ d 2 copy ~ sub 1 add dict `/.notdef 0 d 2 copy 1 ~{@ 3 ^ sub Encoding ~ get ~ d}for & E /CharStrings ~ d ! ! & @ E/FontName get ~ definefont}b/mF42{15 dict ` @ 4 1 $ FontName ~ d/FontType 0 d/FMapType 2 d/FontMatrix[1 0 0 1 0 0]d 1 ^ 254 add 255 idiv @ array/Encoding ~ d 0 1 3 -1 $ 1 sub{@ Encoding 3 1 $ put}for/FDepVector Encoding length array d/CharStrings 2 dict `/.notdef 0 d & E d 0 1 Encoding length 1 sub{@ @ 10 lt{! FontName length 1 add string}{100 lt{FontName length 2 add string}{FontName length 3 add string}?}? @ 0 FontName @ length string cvs putinterval @ 3 -1 $ @ 4 1 $ 3 string cvs FontName length ~ putinterval cvn 1 ^ 256 mul @ 255 add 3 -1 $ 4 ^ findfont mF42D FDepVector 3 1 $ put}for & @ E /FontName get ~ definefont ! ! ! mF}b/mF_OTF_V{3{~ !}repeat 3 -1 $ ! findfont 1 ^ ~ definefont fM @ @ 5 0 put 4 0 put 90 matrix R matrix concatmatrix makefont Pscript_Windows_Font 3 1 $ put}b/UmF{L2?{Pscript_Windows_Font ~ undef}{!}?}b /UmF42{@ findfont/FDepVector get{/FontName get undefinefont}forall undefinefont}b %%EndResource end reinitialize Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Encoding256 5.0 0 /CharCol256Encoding[/.notdef/breve/caron/dotaccent/dotlessi/fi/fl/fraction /hungarumlaut/Lslash/lslash/minus/ogonek/ring/Zcaron/zcaron/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef 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/periodcentered/cedilla/onesuperior/ordmasculine/guillemotright/onequarter /onehalf/threequarters/questiondown/Agrave/Aacute/Acircumflex/Atilde/Adieresis /Aring/AE/Ccedilla/Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute /Icircumflex/Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute/Thorn/germandbls /agrave/aacute/acircumflex/atilde/adieresis/aring/ae/ccedilla/egrave/eacute /ecircumflex/edieresis/igrave/iacute/icircumflex/idieresis/eth/ntilde/ograve /oacute/ocircumflex/otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex /udieresis/yacute/thorn/ydieresis]def EncodeDict/256 CharCol256Encoding put %%EndResource end reinitialize %%IncludeResource: font Helvetica F /F0 0 /256 T /Helvetica mF /F0SB8 F0 [184.391 0 0 -184.391 0 0 ] mFS F0SB8 Ji 1101 4354 M (0)S 1516 4354 M (1)S 1931 4354 M (2)S 2347 4354 M (3)S 2762 4354 M (4)S 3178 4354 M (5)S 3593 4354 M (6)S 4008 4354 M (7)S 4424 4354 M (8)S 4839 4354 M (9)S 5204 4354 M (10)[103 0]xS 5619 4354 M (11)[103 0]xS 6034 4354 M (12)[103 0]xS 613 4185 M (0,1)[103 51 0]xS 767 2262 M (1)S 664 339 M (10)[103 0]xS Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Win_GdiObject 5.0 0 /SavedCTM null d/CTMsave{/SavedCTM SavedCTM currentmatrix d}b/CTMrestore {SavedCTM setmatrix}b/mp null d/ADO_mxRot null d/GDIHMatrix null d /GDIHPatternDict 22 dict d GDIHPatternDict `/PatternType 1 d/PaintType 2 d/Reps L2?{1}{5}? d/XStep 8 Reps mul d/YStep XStep d/BBox[0 0 XStep YStep]d/TilingType 1 d/PaintProc{` 1 Lw[]0 sd PaintData , exec E}b/FGnd null d/BGnd null d /HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b/HS_BDiagonal {biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? d/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b /vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag{Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E/makehatch{4 -2 $/yOrg ~ d /xOrg ~ d GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix xOrg yOrg + mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0 /HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{/h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5 /HS_DiagCross makehatch}b/GDIBWPatternMx null d/pfprep{save 8 1 $ /PatternOfTheDay 8 1 $ GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/yExt ~ d/Width ~ d/BGnd ~ d/FGnd ~ d/Height yExt RepsV mul d/mx[Width 0 0 Height 0 0]d E build_pattern ~ !}b/pfbf{/fEOFill ~ d pfprep hbf fEOFill{O}{L}? restore}b /GraphInit{GDIHMatrix null eq{/SavedCTM matrix d : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ nonzero_dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly d ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E nonzero_dsnap +S/GDIBWPatternMx matrix currentmatrix readonly d ; ;}if}b %%EndResource %%BeginResource: file Pscript_Win_GdiObject_L2 5.0 0 /GDIBWPatternDict 25 dict @ `/PatternType 1 d/PaintType 1 d/RepsV 1 d/RepsH 1 d /BBox[0 0 RepsH 1]d/TilingType 1 d/XStep 1 d/YStep 1 d/Height 8 RepsV mul d /Width 8 d/mx[Width 0 0 Height neg 0 Height]d/FGnd null d/BGnd null d /SetBGndFGnd{BGnd null ne{BGnd aload ! scol BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! scol}if}b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E d/mp/makepattern , d /build_pattern{CTMsave GDIBWPatternMx setmatrix/nupangle where{! nupangle -90 eq{nupangle R}if}if GDIBWPatternDict @ ` Width Height ne{Width Height gt{Width Height V 1}{1 Height Width V}? +S}if xOrg yOrg E matrix + mp CTMrestore}b/hbf {setpattern}b/hf{:/fEOFill ~ d ~ ! setpattern fEOFill{O}{L}? ;}b/pbf{: ! /fEOFill ~ d GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/OutputBPP ~ d /Height ~ d/Width ~ d/PaintType 1 d/PatternType 1 d/TilingType 1 d/BBox[0 0 Width Height]d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d 20 dict @ ` /ImageType 1 d/Width Width d/Height Height d/ImageMatrix[1 0 0 1 0 0]d /BitsPerComponent 8 d OutputBPP 24 eq{/Decode[0 1 0 1 0 1]d}{OutputBPP 8 eq{ /Decode[0 1]d}{/Decode[0 1 0 1 0 1 0 1]d}?}?/DataSource{PaintData}d E/ImageDict ~ d/PaintProc{` ImageDict image E}b & mx makepattern setpattern E fEOFill{O}{L} ? ;}b/mask_pbf{:/fEOFill ~ d 20 dict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/Height ~ d/Width ~ d/PatternType 1 d/PaintType 2 d/TilingType 1 d/BBox[0 0 Width Height] d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d/PaintProc{` Width Height T[1 0 0 1 0 0]{PaintData}imagemask E}b & mx makepattern setpattern E fEOFill{O} {L}? ;}b %%EndResource end reinitialize 1 Lj 1 Lc 13 Lw solid N 945 4134 M 945 4134 I K N 1153 4134 M 1153 4065 I K N 1360 4134 M 1360 4134 I K N 1568 4134 M 1568 4065 I K N 1776 4134 M 1776 4134 I K N 1983 4134 M 1983 4065 I K N 2191 4134 M 2191 4134 I K N 2399 4134 M 2399 4065 I K N 2607 4134 M 2607 4134 I K N 2814 4134 M 2814 4065 I K N 3022 4134 M 3022 4134 I K N 3230 4134 M 3230 4065 I K N 3437 4134 M 3437 4134 I K N 3645 4134 M 3645 4065 I K N 3853 4134 M 3853 4134 I K N 4060 4134 M 4060 4065 I K N 4268 4134 M 4268 4134 I K N 4476 4134 M 4476 4065 I K N 4683 4134 M 4683 4134 I K N 4891 4134 M 4891 4065 I K N 5099 4134 M 5099 4134 I K N 5307 4134 M 5307 4065 I K N 5514 4134 M 5514 4134 I K N 5722 4134 M 5722 4065 I K N 5930 4134 M 5930 4134 I K N 6137 4134 M 6137 4065 I K N 6345 4134 M 6345 4134 I K N 945 4134 M 6345 4134 I K N 945 4134 M 1014 4134 I K N 945 3555 M 980 3555 I K N 945 3216 M 980 3216 I K N 945 2976 M 980 2976 I K N 945 2790 M 980 2790 I K N 945 2638 M 980 2638 I K N 945 2509 M 980 2509 I K N 945 2397 M 980 2397 I K N 945 2299 M 980 2299 I K N 945 2211 M 1014 2211 I K N 945 1632 M 980 1632 I K N 945 1293 M 980 1293 I K N 945 1053 M 980 1053 I K N 945 867 M 980 867 I K N 945 715 M 980 715 I K N 945 586 M 980 586 I K N 945 474 M 980 474 I K N 945 376 M 980 376 I K N 945 288 M 1014 288 I K N 945 4134 M 945 288 I K N 945 288 M 945 288 I K N 1153 288 M 1153 288 I K N 1360 288 M 1360 288 I K N 1568 288 M 1568 288 I K N 1776 288 M 1776 288 I K N 1983 288 M 1983 288 I K N 2191 288 M 2191 288 I K N 2399 288 M 2399 288 I K N 2607 288 M 2607 288 I K N 2814 288 M 2814 288 I K N 3022 288 M 3022 288 I K N 3230 288 M 3230 288 I K N 3437 288 M 3437 288 I K N 3645 288 M 3645 288 I K N 3853 288 M 3853 288 I K N 4060 288 M 4060 288 I K N 4268 288 M 4268 288 I K N 4476 288 M 4476 288 I K N 4683 288 M 4683 288 I K N 4891 288 M 4891 288 I K N 5099 288 M 5099 288 I K N 5307 288 M 5307 288 I K N 5514 288 M 5514 288 I K N 5722 288 M 5722 288 I K N 5930 288 M 5930 288 I K N 6137 288 M 6137 288 I K N 6345 288 M 6345 288 I K N 945 288 M 6345 288 I K N 6345 4134 M 6345 4134 I K N 6345 3555 M 6345 3555 I K N 6345 3216 M 6345 3216 I K N 6345 2976 M 6345 2976 I K N 6345 2790 M 6345 2790 I K N 6345 2638 M 6345 2638 I K N 6345 2509 M 6345 2509 I K N 6345 2397 M 6345 2397 I K N 6345 2299 M 6345 2299 I K N 6345 2211 M 6345 2211 I K N 6345 1632 M 6345 1632 I K N 6345 1293 M 6345 1293 I K N 6345 1053 M 6345 1053 I K N 6345 867 M 6345 867 I K N 6345 715 M 6345 715 I K N 6345 586 M 6345 586 I K N 6345 474 M 6345 474 I K N 6345 376 M 6345 376 I K N 6345 288 M 6345 288 I K N 6345 4134 M 6345 288 I K 9 Lw N 1541 2182 M 1180 1893 I K N 1952 2025 M 1599 2189 I K N 2376 2422 M 2006 2036 I K N 2787 2732 M 2426 2467 I K N 3198 2605 M 2846 2740 I K N 3612 2477 M 3263 2583 I K N 4027 2358 M 3678 2458 I K N 4445 2162 M 4091 2334 I K 0 Lj 3 Lw N 1172 1852 M 1133 1852 I 1133 1891 I 1172 1891 I C : O ; K N 1587 2183 M 1548 2183 I 1548 2222 I 1587 2222 I C : O ; K N 2002 1991 M 1963 1991 I 1963 2030 I 2002 2030 I C : O ; K N 2418 2427 M 2379 2427 I 2379 2466 I 2418 2466 I C : O ; K N 2833 2732 M 2794 2732 I 2794 2771 I 2833 2771 I C : O ; K N 3249 2573 M 3210 2573 I 3210 2612 I 3249 2612 I C : O ; K N 3664 2447 M 3625 2447 I 3625 2486 I 3664 2486 I C : O ; K N 4079 2329 M 4040 2329 I 4040 2368 I 4079 2368 I C : O ; K N 4495 2127 M 4456 2127 I 4456 2166 I 4495 2166 I C : O ; K 1 Lj 9 Lw N 1539 2077 M 1499 2053 I K N 1454 2026 M 1414 2002 I K N 1369 1975 M 1329 1951 I K N 1284 1923 M 1244 1899 I K N 1199 1872 M 1183 1863 I K N 1949 2049 M 1909 2054 I K N 1864 2059 M 1824 2064 I K N 1779 2069 M 1739 2074 I K N 1694 2079 M 1654 2084 I K N 1609 2089 M 1603 2090 I K N 2371 2315 M 2331 2287 I K N 2286 2256 M 2246 2228 I K N 2201 2196 M 2161 2169 I K N 2116 2137 M 2076 2109 I K N 2031 2078 M 2012 2065 I K N 2789 2701 M 2749 2663 I K N 2704 2621 M 2664 2583 I K N 2619 2541 M 2579 2503 I K N 2534 2461 M 2494 2423 I K N 2449 2381 M 2425 2358 I K N 3196 2757 M 3156 2754 I K N 3111 2750 M 3071 2746 I K N 3026 2742 M 2986 2739 I K N 2941 2735 M 2901 2732 I K N 2856 2728 M 2849 2727 I K N 3618 2461 M 3578 2492 I K N 3533 2526 M 3493 2557 I K N 3448 2592 M 3408 2623 I K N 3363 2657 M 3323 2688 I K N 3278 2723 M 3258 2738 I K N 4031 2211 M 3991 2235 I K N 3946 2261 M 3906 2285 I K N 3861 2312 M 3821 2336 I K N 3776 2362 M 3736 2386 I K N 3691 2413 M 3675 2422 I K N 4442 2194 M 4402 2194 I K N 4357 2194 M 4317 2194 I K N 4272 2194 M 4232 2194 I K N 4187 2194 M 4147 2194 I K N 4102 2194 M 4095 2194 I K N 4858 2102 M 4818 2112 I K N 4773 2122 M 4733 2132 I K N 4688 2143 M 4648 2153 I K N 4603 2163 M 4563 2173 I K N 4518 2184 M 4510 2186 I K 3 Lw N 1175 1844 M 1175 1832 1164 1822 1152 1822 -c 1140 1822 1130 1832 1130 1844 -c 1130 1856 1140 1867 1152 1867 -c 1164 1867 1175 1856 1175 1844 -c C : O ; K N 1590 2093 M 1590 2081 1579 2071 1567 2071 -c 1555 2071 1545 2081 1545 2093 -c 1545 2105 1555 2116 1567 2116 -c 1579 2116 1590 2105 1590 2093 -c C : O ; K N 2005 2044 M 2005 2032 1994 2022 1982 2022 -c 1970 2022 1960 2032 1960 2044 -c 1960 2056 1970 2067 1982 2067 -c 1994 2067 2005 2056 2005 2044 -c C : O ; K N 2421 2333 M 2421 2321 2410 2311 2398 2311 -c 2386 2311 2376 2321 2376 2333 -c 2376 2345 2386 2356 2398 2356 -c 2410 2356 2421 2345 2421 2333 -c C : O ; K N 2836 2723 M 2836 2711 2825 2701 2813 2701 -c 2801 2701 2791 2711 2791 2723 -c 2791 2735 2801 2746 2813 2746 -c 2825 2746 2836 2735 2836 2723 -c C : O ; K N 3252 2759 M 3252 2747 3241 2737 3229 2737 -c 3217 2737 3207 2747 3207 2759 -c 3207 2771 3217 2782 3229 2782 -c 3241 2782 3252 2771 3252 2759 -c C : O ; K N 3667 2439 M 3667 2427 3656 2417 3644 2417 -c 3632 2417 3622 2427 3622 2439 -c 3622 2451 3632 2462 3644 2462 -c 3656 2462 3667 2451 3667 2439 -c C : O ; K N 4082 2193 M 4082 2181 4071 2171 4059 2171 -c 4047 2171 4037 2181 4037 2193 -c 4037 2205 4047 2216 4059 2216 -c 4071 2216 4082 2205 4082 2193 -c C : O ; K N 4498 2193 M 4498 2181 4487 2171 4475 2171 -c 4463 2171 4453 2181 4453 2193 -c 4453 2205 4463 2216 4475 2216 -c 4487 2216 4498 2205 4498 2193 -c C : O ; K N 4913 2093 M 4913 2081 4902 2071 4890 2071 -c 4878 2071 4868 2081 4868 2093 -c 4868 2105 4878 2116 4890 2116 -c 4902 2116 4913 2105 4913 2093 -c C : O ; K 9 Lw N 1537 2072 M 1527 2076 I K N 1486 2093 M 1476 2097 I K N 1435 2113 M 1425 2117 I K N 1384 2134 M 1374 2138 I K N 1333 2155 M 1323 2159 I K N 1282 2175 M 1272 2179 I K N 1231 2196 M 1221 2200 I K N 1956 1750 M 1946 1758 I K N 1905 1791 M 1895 1799 I K N 1854 1831 M 1844 1839 I K N 1803 1872 M 1793 1880 I K N 1752 1913 M 1742 1921 I K N 1701 1953 M 1691 1961 I K N 1650 1994 M 1640 2002 I K N 1599 2035 M 1596 2037 I K N 2388 2907 M 2385 2897 I K N 2370 2856 M 2367 2846 I K N 2353 2805 M 2349 2795 I K N 2335 2754 M 2332 2744 I K N 2318 2703 M 2314 2693 I K N 2300 2652 M 2297 2642 I K N 2283 2601 M 2279 2591 I K N 2265 2550 M 2262 2540 I K N 2248 2499 M 2244 2489 I K N 2230 2448 M 2227 2438 I K N 2213 2397 M 2209 2387 I K N 2195 2346 M 2192 2336 I K N 2178 2295 M 2174 2285 I K N 2160 2244 M 2157 2234 I K N 2143 2193 M 2139 2183 I K N 2125 2142 M 2122 2132 I K N 2107 2091 M 2104 2081 I K N 2090 2040 M 2086 2030 I K N 2072 1989 M 2069 1979 I K N 2055 1938 M 2051 1928 I K N 2037 1887 M 2034 1877 I K N 2020 1836 M 2016 1826 I K N 2002 1785 M 1999 1775 I K N 2781 3029 M 2771 3027 I K N 2730 3017 M 2720 3015 I K N 2679 3005 M 2669 3003 I K N 2628 2993 M 2618 2991 I K N 2577 2981 M 2567 2979 I K N 2526 2969 M 2516 2967 I K N 2475 2957 M 2465 2955 I K N 3199 2876 M 3189 2880 I K N 3148 2897 M 3138 2902 I K N 3097 2919 M 3087 2923 I K N 3046 2940 M 3036 2944 I K N 2995 2961 M 2985 2965 I K N 2944 2983 M 2934 2987 I K N 2893 3004 M 2883 3008 I K N 3619 2536 M 3609 2544 I K N 3568 2579 M 3558 2587 I K N 3517 2622 M 3507 2630 I K N 3466 2665 M 3456 2673 I K N 3415 2707 M 3405 2716 I K N 3364 2750 M 3354 2759 I K N 3313 2793 M 3303 2802 I K N 3262 2836 M 3257 2840 I K N 4027 2429 M 4017 2431 I K N 3976 2440 M 3966 2443 I K N 3925 2452 M 3915 2454 I K N 3874 2463 M 3864 2465 I K N 3823 2475 M 3813 2477 I K N 3772 2486 M 3762 2488 I K N 3721 2497 M 3711 2500 I K N 4449 2129 M 4439 2137 I K N 4398 2167 M 4388 2175 I K N 4347 2206 M 4337 2213 I K N 4296 2244 M 4286 2252 I K N 4245 2283 M 4235 2290 I K N 4194 2321 M 4184 2329 I K N 4143 2360 M 4133 2367 I K N 4092 2398 M 4088 2401 I K N 4857 2144 M 4847 2143 I K N 4806 2139 M 4796 2138 I K N 4755 2135 M 4745 2134 I K N 4704 2130 M 4694 2129 I K N 4653 2125 M 4643 2124 I K N 4602 2120 M 4592 2120 I K N 4551 2116 M 4541 2115 I K 4 Lw N 1153 2198 M 1178 2243 I 1127 2243 I C : O ; K N 1568 2029 M 1593 2074 I 1542 2074 I C : O ; K N 1983 1699 M 2008 1744 I 1957 1744 I C : O ; K N 2399 2909 M 2424 2954 I 2373 2954 I C : O ; K N 2814 3007 M 2839 3052 I 2788 3052 I C : O ; K N 3230 2833 M 3255 2878 I 3204 2878 I C : O ; K N 3645 2484 M 3670 2529 I 3619 2529 I C : O ; K N 4060 2392 M 4085 2437 I 4034 2437 I C : O ; K N 4476 2079 M 4501 2124 I 4450 2124 I C : O ; K N 4891 2117 M 4916 2162 I 4865 2162 I C : O ; K 9 Lw N 1540 2060 M 1492 2026 I K N 1468 2009 M 1458 2002 I K N 1433 1985 M 1385 1951 I K N 1361 1934 M 1351 1927 I K N 1326 1910 M 1278 1876 I K N 1254 1859 M 1244 1852 I K N 1219 1835 M 1182 1809 I K N 1949 2067 M 1901 2069 I K N 1877 2069 M 1867 2070 I K N 1842 2071 M 1794 2072 I K N 1770 2073 M 1760 2074 I K N 1735 2074 M 1687 2076 I K N 1663 2077 M 1653 2077 I K N 1628 2078 M 1603 2079 I K N 2369 2279 M 2321 2252 I K N 2297 2239 M 2287 2234 I K N 2262 2220 M 2214 2193 I K N 2190 2180 M 2180 2174 I K N 2155 2161 M 2107 2134 I K N 2083 2121 M 2073 2115 I K N 2048 2101 M 2014 2083 I K N 2790 2702 M 2744 2654 I K N 2721 2630 M 2711 2620 I K N 2687 2595 M 2641 2547 I K N 2618 2523 M 2608 2513 I K N 2584 2488 M 2538 2440 I K N 2515 2416 M 2506 2406 I K N 2482 2381 M 2435 2333 I K N 3199 2571 M 3151 2590 I K N 3127 2600 M 3117 2604 I K N 3092 2614 M 3044 2634 I K N 3020 2643 M 3010 2647 I K N 2985 2657 M 2937 2677 I K N 2913 2687 M 2903 2691 I K N 2878 2701 M 2846 2714 I K N 3616 2325 M 3568 2354 I K N 3544 2368 M 3534 2374 I K N 3509 2389 M 3461 2418 I K N 3437 2433 M 3427 2439 I K N 3402 2454 M 3354 2483 I K N 3330 2497 M 3320 2503 I K N 3295 2518 M 3260 2539 I K N 4026 2351 M 3978 2345 I K N 3954 2343 M 3944 2342 I K N 3919 2339 M 3871 2333 I K N 3847 2330 M 3837 2329 I K N 3812 2326 M 3764 2321 I K N 3740 2318 M 3730 2317 I K N 3705 2314 M 3680 2311 I K N 4447 2105 M 4399 2136 I K N 4375 2152 M 4365 2158 I K N 4340 2174 M 4292 2205 I K N 4268 2221 M 4258 2227 I K N 4233 2244 M 4185 2275 I K N 4161 2290 M 4151 2297 I K N 4126 2313 M 4090 2336 I K N 4857 2142 M 4809 2135 I K N 4785 2132 M 4775 2130 I K N 4750 2127 M 4702 2120 I K N 4678 2116 M 4668 2115 I K N 4643 2111 M 4595 2104 I K N 4571 2101 M 4561 2099 I K N 4536 2096 M 4511 2092 I K N 5289 1505 M 5259 1553 I K N 5244 1577 M 5238 1587 I K N 5223 1612 M 5193 1660 I K N 5178 1684 M 5172 1694 I K N 5156 1719 M 5127 1767 I K N 5112 1791 M 5106 1801 I K N 5090 1826 M 5060 1874 I K N 5045 1898 M 5039 1908 I K N 5024 1933 M 4994 1981 I K N 4979 2005 M 4973 2015 I K N 4957 2040 M 4928 2088 I K N 4913 2112 M 4910 2117 I K 4 Lw N 1178 1773 M 1153 1818 I 1127 1773 I C : O ; K N 1593 2065 M 1568 2110 I 1542 2065 I C : O ; K N 2008 2051 M 1983 2096 I 1957 2051 I C : O ; K N 2424 2280 M 2399 2325 I 2373 2280 I C : O ; K N 2839 2712 M 2814 2757 I 2788 2712 I C : O ; K N 3255 2543 M 3230 2588 I 3204 2543 I C : O ; K N 3670 2292 M 3645 2337 I 3619 2292 I C : O ; K N 4085 2340 M 4060 2385 I 4034 2340 I C : O ; K N 4501 2072 M 4476 2117 I 4450 2072 I C : O ; K N 4916 2132 M 4891 2177 I 4865 2132 I C : O ; K N 5332 1461 M 5307 1506 I 5281 1461 I C : O ; K 9 Lw N 1534 2003 M 1498 2001 I K N 1474 2000 M 1464 2000 I K N 1440 1999 M 1430 1998 I K N 1405 1997 M 1369 1995 I K N 1345 1994 M 1335 1994 I K N 1311 1993 M 1301 1992 I K N 1276 1991 M 1240 1989 I K N 1216 1988 M 1206 1988 I K N 1949 2048 M 1913 2044 I K N 1889 2041 M 1879 2040 I K N 1855 2037 M 1845 2036 I K N 1820 2034 M 1784 2029 I K N 1760 2027 M 1750 2026 I K N 1726 2023 M 1716 2022 I K N 1691 2019 M 1655 2015 I K N 1631 2012 M 1621 2011 I K N 2368 2222 M 2332 2206 I K N 2308 2196 M 2298 2191 I K N 2274 2181 M 2264 2176 I K N 2239 2165 M 2203 2149 I K N 2179 2139 M 2169 2134 I K N 2145 2124 M 2135 2119 I K N 2110 2108 M 2074 2092 I K N 2050 2082 M 2040 2077 I K N 2016 2067 M 2015 2066 I K N 2790 2618 M 2754 2583 I K N 2730 2559 M 2720 2550 I K N 2696 2526 M 2686 2517 I K N 2661 2492 M 2625 2457 I K N 2601 2434 M 2591 2424 I K N 2567 2400 M 2557 2391 I K N 2532 2366 M 2496 2331 I K N 2472 2308 M 2462 2298 I K N 2438 2275 M 2428 2265 I K N 3196 2632 M 3160 2633 I K N 3136 2634 M 3126 2634 I K N 3102 2634 M 3092 2635 I K N 3067 2635 M 3031 2636 I K N 3007 2637 M 2997 2637 I K N 2973 2638 M 2963 2638 I K N 2938 2639 M 2902 2640 I K N 2878 2640 M 2868 2640 I K N 3617 2355 M 3581 2381 I K N 3557 2398 M 3547 2405 I K N 3523 2422 M 3513 2429 I K N 3488 2447 M 3452 2473 I K N 3428 2490 M 3418 2497 I K N 3394 2514 M 3384 2521 I K N 3359 2539 M 3323 2565 I K N 3299 2582 M 3289 2589 I K N 3265 2606 M 3259 2610 I K N 4030 2132 M 3994 2151 I K N 3970 2164 M 3960 2169 I K N 3936 2182 M 3926 2187 I K N 3901 2200 M 3865 2219 I K N 3841 2232 M 3831 2237 I K N 3807 2249 M 3797 2255 I K N 3772 2268 M 3736 2287 I K N 3712 2300 M 3702 2305 I K N 3678 2317 M 3676 2318 I K N 4442 2089 M 4406 2092 I K N 4382 2093 M 4372 2094 I K N 4348 2096 M 4338 2096 I K N 4313 2098 M 4277 2101 I K N 4253 2103 M 4243 2103 I K N 4219 2105 M 4209 2106 I K N 4184 2108 M 4148 2110 I K N 4124 2112 M 4114 2113 I K N 4857 2042 M 4821 2046 I K N 4797 2049 M 4787 2050 I K N 4763 2053 M 4753 2054 I K N 4728 2057 M 4692 2061 I K N 4668 2064 M 4658 2066 I K N 4634 2068 M 4624 2070 I K N 4599 2072 M 4563 2077 I K N 4539 2080 M 4529 2081 I K N 5280 1732 M 5244 1760 I K N 5220 1779 M 5210 1787 I K N 5186 1806 M 5176 1814 I K N 5151 1834 M 5115 1862 I K N 5091 1881 M 5081 1889 I K N 5057 1908 M 5047 1915 I K N 5022 1935 M 4986 1963 I K N 4962 1982 M 4952 1990 I K N 4928 2009 M 4919 2016 I K N 5707 899 M 5689 935 I K N 5677 959 M 5673 969 I K N 5661 993 M 5656 1003 I K N 5643 1028 M 5626 1064 I K N 5614 1088 M 5609 1098 I K N 5597 1122 M 5592 1132 I K N 5580 1157 M 5562 1193 I K N 5550 1217 M 5546 1227 I K N 5534 1251 M 5529 1261 I K N 5516 1286 M 5499 1322 I K N 5487 1346 M 5482 1356 I K N 5470 1380 M 5465 1390 I K N 5453 1415 M 5435 1451 I K N 5423 1475 M 5418 1485 I K N 5407 1509 M 5402 1519 I K N 5389 1544 M 5372 1580 I K N 5360 1604 M 5355 1614 I K N 5343 1638 M 5338 1648 I K N 5326 1673 M 5322 1680 I K N 6110 571 M 6074 599 I K N 6050 617 M 6040 625 I K N 6016 643 M 6006 651 I K N 5981 670 M 5945 698 I K N 5921 716 M 5911 724 I K N 5887 742 M 5877 750 I K N 5852 769 M 5816 797 I K N 5792 815 M 5782 823 I K N 5758 841 M 5750 847 I K 4 Lw N 1125 1985 M 1153 1957 I 1181 1985 I 1153 2013 I C : O ; K N 1540 2005 M 1568 1977 I 1596 2005 I 1568 2033 I C : O ; K N 1955 2052 M 1983 2024 I 2011 2052 I 1983 2080 I C : O ; K N 2371 2236 M 2399 2208 I 2427 2236 I 2399 2264 I C : O ; K N 2786 2642 M 2814 2614 I 2842 2642 I 2814 2670 I C : O ; K N 3202 2631 M 3230 2603 I 3258 2631 I 3230 2659 I C : O ; K N 3617 2335 M 3645 2307 I 3673 2335 I 3645 2363 I C : O ; K N 4032 2116 M 4060 2088 I 4088 2116 I 4060 2144 I C : O ; K N 4448 2087 M 4476 2059 I 4504 2087 I 4476 2115 I C : O ; K N 4863 2038 M 4891 2010 I 4919 2038 I 4891 2066 I C : O ; K N 5279 1711 M 5307 1683 I 5335 1711 I 5307 1739 I C : O ; K N 5694 869 M 5722 841 I 5750 869 I 5722 897 I C : O ; K N 6109 550 M 6137 522 I 6165 550 I 6137 578 I C : O ; K 9 Lw N 1535 1938 M 1517 1942 I K N 1496 1947 M 1478 1952 I K N 1457 1957 M 1439 1961 I K N 1418 1966 M 1400 1971 I K N 1379 1976 M 1361 1980 I K N 1340 1985 M 1322 1990 I K N 1301 1995 M 1283 1999 I K N 1262 2004 M 1244 2009 I K N 1223 2014 M 1205 2018 I K N 1949 1993 M 1931 1990 I K N 1910 1986 M 1892 1983 I K N 1871 1980 M 1853 1977 I K N 1832 1973 M 1814 1970 I K N 1793 1967 M 1775 1964 I K N 1754 1960 M 1736 1957 I K N 1715 1954 M 1697 1951 I K N 1676 1947 M 1658 1944 I K N 1637 1941 M 1619 1938 I K N 2376 2408 M 2359 2390 I K N 2339 2369 M 2321 2351 I K N 2301 2330 M 2284 2312 I K N 2264 2291 M 2246 2273 I K N 2226 2252 M 2209 2234 I K N 2189 2213 M 2171 2195 I K N 2151 2174 M 2134 2156 I K N 2114 2135 M 2096 2117 I K N 2076 2096 M 2059 2078 I K N 2039 2057 M 2021 2039 I K N 2780 2426 M 2762 2426 I K N 2741 2427 M 2723 2427 I K N 2702 2427 M 2684 2428 I K N 2663 2428 M 2645 2428 I K N 2624 2429 M 2606 2429 I K N 2585 2429 M 2567 2430 I K N 2546 2430 M 2528 2430 I K N 2507 2431 M 2489 2431 I K N 2468 2431 M 2450 2432 I K N 3202 2685 M 3184 2673 I K N 3163 2659 M 3145 2647 I K N 3124 2633 M 3106 2621 I K N 3085 2607 M 3067 2595 I K N 3046 2581 M 3028 2569 I K N 3007 2554 M 2989 2542 I K N 2968 2528 M 2950 2516 I K N 2929 2502 M 2911 2490 I K N 2890 2476 M 2872 2464 I K N 2851 2450 M 2843 2445 I K N 3614 2547 M 3596 2554 I K N 3575 2563 M 3557 2570 I K N 3536 2579 M 3518 2586 I K N 3497 2595 M 3479 2602 I K N 3458 2611 M 3440 2618 I K N 3419 2627 M 3401 2634 I K N 3380 2642 M 3362 2650 I K N 3341 2658 M 3323 2666 I K N 3302 2674 M 3284 2682 I K N 3263 2690 M 3262 2691 I K N 4029 2353 M 4011 2362 I K N 3990 2371 M 3972 2380 I K N 3951 2390 M 3933 2398 I K N 3912 2408 M 3894 2417 I K N 3873 2427 M 3855 2435 I K N 3834 2445 M 3816 2454 I K N 3795 2464 M 3777 2472 I K N 3756 2482 M 3738 2491 I K N 3717 2501 M 3699 2509 I K N 3678 2519 M 3677 2520 I K N 4444 2198 M 4426 2205 I K N 4405 2212 M 4387 2219 I K N 4366 2227 M 4348 2233 I K N 4327 2241 M 4309 2247 I K N 4288 2255 M 4270 2262 I K N 4249 2269 M 4231 2276 I K N 4210 2284 M 4192 2290 I K N 4171 2298 M 4153 2305 I K N 4132 2312 M 4114 2319 I K N 4093 2327 M 4093 2327 I K N 4857 2237 M 4839 2235 I K N 4818 2232 M 4800 2229 I K N 4779 2226 M 4761 2224 I K N 4740 2221 M 4722 2219 I K N 4701 2216 M 4683 2213 I K N 4662 2211 M 4644 2208 I K N 4623 2205 M 4605 2203 I K N 4584 2200 M 4566 2198 I K N 4545 2195 M 4527 2192 I K N 5276 2059 M 5258 2068 I K N 5237 2078 M 5219 2086 I K N 5198 2096 M 5180 2105 I K N 5159 2115 M 5141 2123 I K N 5120 2133 M 5102 2142 I K N 5081 2152 M 5063 2160 I K N 5042 2170 M 5024 2179 I K N 5003 2189 M 4985 2197 I K N 4964 2207 M 4946 2216 I K N 4925 2226 M 4923 2227 I K N 5709 1116 M 5701 1134 I K N 5692 1155 M 5684 1173 I K N 5675 1194 M 5667 1212 I K N 5658 1233 M 5651 1251 I K N 5641 1272 M 5634 1290 I K N 5625 1311 M 5617 1329 I K N 5608 1350 M 5600 1368 I K N 5591 1389 M 5583 1407 I K N 5574 1428 M 5566 1446 I K N 5557 1467 M 5549 1485 I K N 5540 1506 M 5532 1524 I K N 5523 1545 M 5515 1563 I K N 5506 1584 M 5498 1602 I K N 5489 1623 M 5482 1641 I K N 5472 1662 M 5465 1680 I K N 5456 1701 M 5448 1719 I K N 5439 1740 M 5431 1758 I K N 5422 1779 M 5414 1797 I K N 5405 1818 M 5397 1836 I K N 5388 1857 M 5380 1875 I K N 5371 1896 M 5363 1914 I K N 5354 1935 M 5346 1953 I K N 5337 1974 M 5330 1992 I K N 5320 2013 M 5320 2013 I K 4 Lw N 1123 2031 M 1168 2056 I 1168 2005 I C : O ; K N 1538 1930 M 1583 1955 I 1583 1904 I C : O ; K N 1953 1998 M 1998 2023 I 1998 1972 I C : O ; K N 2369 2433 M 2414 2458 I 2414 2407 I C : O ; K N 2784 2425 M 2829 2450 I 2829 2399 I C : O ; K N 3200 2704 M 3245 2729 I 3245 2678 I C : O ; K N 3615 2534 M 3660 2559 I 3660 2508 I C : O ; K N 4030 2339 M 4075 2364 I 4075 2313 I C : O ; K N 4446 2186 M 4491 2211 I 4491 2160 I C : O ; K N 4861 2241 M 4906 2266 I 4906 2215 I C : O ; K N 5277 2045 M 5322 2070 I 5322 2019 I C : O ; K N 5692 1085 M 5737 1110 I 5737 1059 I C : O ; K 9 Lw N 1534 1557 M 1504 1558 I K N 1488 1559 M 1482 1559 I K N 1465 1560 M 1435 1561 I K N 1419 1562 M 1413 1562 I K N 1396 1563 M 1366 1564 I K N 1350 1564 M 1344 1565 I K N 1327 1565 M 1297 1567 I K N 1281 1567 M 1275 1567 I K N 1258 1568 M 1228 1569 I K N 1212 1570 M 1206 1570 I K N 1189 1571 M 1188 1571 I K N 1968 2382 M 1953 2352 I K N 1946 2336 M 1943 2330 I K N 1935 2313 M 1920 2283 I K N 1912 2267 M 1909 2261 I K N 1901 2244 M 1887 2214 I K N 1879 2198 M 1876 2192 I K N 1868 2175 M 1853 2145 I K N 1845 2129 M 1843 2123 I K N 1834 2106 M 1820 2076 I K N 1812 2060 M 1809 2054 I K N 1801 2037 M 1786 2007 I K N 1779 1991 M 1776 1985 I K N 1768 1968 M 1753 1938 I K N 1745 1922 M 1742 1916 I K N 1734 1899 M 1720 1869 I K N 1712 1853 M 1709 1847 I K N 1701 1830 M 1686 1800 I K N 1678 1784 M 1675 1778 I K N 1667 1761 M 1653 1731 I K N 1645 1715 M 1642 1709 I K N 1634 1692 M 1619 1662 I K N 1612 1646 M 1609 1640 I K N 1600 1623 M 1586 1593 I K N 2365 2376 M 2335 2379 I K N 2319 2380 M 2313 2381 I K N 2296 2383 M 2266 2386 I K N 2250 2387 M 2244 2388 I K N 2227 2389 M 2197 2392 I K N 2181 2394 M 2175 2395 I K N 2158 2396 M 2128 2399 I K N 2112 2401 M 2106 2401 I K N 2089 2403 M 2059 2406 I K N 2043 2407 M 2037 2408 I K N 2020 2410 M 2018 2410 I K N 2785 2621 M 2755 2602 I K N 2739 2591 M 2733 2587 I K N 2716 2577 M 2686 2557 I K N 2670 2547 M 2664 2543 I K N 2647 2532 M 2617 2513 I K N 2601 2502 M 2595 2499 I K N 2578 2488 M 2548 2468 I K N 2532 2458 M 2526 2454 I K N 2509 2443 M 2479 2424 I K N 2463 2414 M 2457 2410 I K N 2440 2399 M 2429 2392 I K N 3198 2512 M 3168 2522 I K N 3152 2527 M 3146 2529 I K N 3129 2535 M 3099 2545 I K N 3083 2550 M 3077 2552 I K N 3060 2557 M 3030 2567 I K N 3014 2573 M 3008 2575 I K N 2991 2580 M 2961 2590 I K N 2945 2595 M 2939 2597 I K N 2922 2603 M 2892 2613 I K N 2876 2618 M 2870 2620 I K N 2853 2626 M 2847 2628 I K N 3612 2391 M 3582 2400 I K N 3566 2404 M 3560 2406 I K N 3543 2411 M 3513 2420 I K N 3497 2424 M 3491 2426 I K N 3474 2431 M 3444 2440 I K N 3428 2444 M 3422 2446 I K N 3405 2451 M 3375 2460 I K N 3359 2464 M 3353 2466 I K N 3336 2471 M 3306 2480 I K N 3290 2484 M 3284 2486 I K N 3267 2491 M 3264 2492 I K N 4027 2274 M 3997 2283 I K N 3981 2287 M 3975 2289 I K N 3958 2294 M 3928 2302 I K N 3912 2307 M 3906 2308 I K N 3889 2313 M 3859 2322 I K N 3843 2326 M 3837 2328 I K N 3820 2333 M 3790 2341 I K N 3774 2346 M 3768 2347 I K N 3751 2352 M 3721 2361 I K N 3705 2365 M 3699 2367 I K N 3682 2372 M 3679 2373 I K N 4444 2135 M 4414 2145 I K N 4398 2151 M 4392 2153 I K N 4375 2158 M 4345 2168 I K N 4329 2174 M 4323 2176 I K N 4306 2182 M 4276 2192 I K N 4260 2197 M 4254 2199 I K N 4237 2205 M 4207 2215 I K N 4191 2221 M 4185 2223 I K N 4168 2228 M 4138 2238 I K N 4122 2244 M 4116 2246 I K N 4099 2252 M 4093 2254 I K N 4857 2159 M 4827 2156 I K N 4811 2155 M 4805 2154 I K N 4788 2153 M 4758 2150 I K N 4742 2148 M 4736 2148 I K N 4719 2146 M 4689 2144 I K N 4673 2142 M 4667 2141 I K N 4650 2140 M 4620 2137 I K N 4604 2136 M 4598 2135 I K N 4581 2134 M 4551 2131 I K N 4535 2129 M 4529 2129 I K N 4512 2127 M 4511 2127 I K N 5278 1935 M 5248 1953 I K N 5232 1962 M 5226 1966 I K N 5209 1975 M 5179 1993 I K N 5163 2002 M 5157 2006 I K N 5140 2016 M 5110 2034 I K N 5094 2043 M 5088 2046 I K N 5071 2056 M 5041 2074 I K N 5025 2083 M 5019 2087 I K N 5002 2097 M 4972 2114 I K N 4956 2124 M 4950 2127 I K N 4933 2137 M 4921 2144 I K N 5701 1399 M 5678 1429 I K N 5666 1445 M 5662 1451 I K N 5649 1468 M 5626 1498 I K N 5614 1514 M 5609 1520 I K N 5596 1537 M 5574 1567 I K N 5562 1583 M 5557 1589 I K N 5544 1606 M 5521 1636 I K N 5509 1652 M 5505 1658 I K N 5492 1675 M 5469 1705 I K N 5457 1721 M 5452 1727 I K N 5439 1744 M 5417 1774 I K N 5405 1790 M 5400 1796 I K N 5387 1813 M 5364 1843 I K N 5352 1859 M 5348 1865 I K N 5335 1882 M 5329 1890 I K N 6107 1162 M 6077 1178 I K N 6061 1187 M 6055 1190 I K N 6038 1200 M 6008 1216 I K N 5992 1225 M 5986 1228 I K N 5969 1237 M 5939 1254 I K N 5923 1263 M 5917 1266 I K N 5900 1275 M 5870 1292 I K N 5854 1300 M 5848 1304 I K N 5831 1313 M 5801 1329 I K N 5785 1338 M 5779 1341 I K N 5762 1351 M 5753 1355 I K 4 Lw N 1183 1572 M 1138 1597 I 1138 1546 I C : O ; K N 1598 1556 M 1553 1581 I 1553 1530 I C : O ; K N 2013 2413 M 1968 2438 I 1968 2387 I C : O ; K N 2429 2373 M 2384 2398 I 2384 2347 I C : O ; K N 2844 2639 M 2799 2664 I 2799 2613 I C : O ; K N 3260 2501 M 3215 2526 I 3215 2475 I C : O ; K N 3675 2382 M 3630 2407 I 3630 2356 I C : O ; K N 4090 2265 M 4045 2290 I 4045 2239 I C : O ; K N 4506 2124 M 4461 2149 I 4461 2098 I C : O ; K N 4921 2162 M 4876 2187 I 4876 2136 I C : O ; K N 5337 1918 M 5292 1943 I 5292 1892 I C : O ; K N 5752 1372 M 5707 1397 I 5707 1346 I C : O ; K N 6167 1146 M 6122 1171 I 6122 1120 I C : O ; K 9 Lw N 1534 768 M 1187 794 I K N 1951 902 M 1600 777 I K N 2368 1084 M 2014 927 I K N 2782 1236 M 2431 1109 I K 0 Lj 3 Lw N 1172 776 M 1133 776 I 1133 815 I 1172 815 I C : O ; K N 1587 746 M 1548 746 I 1548 785 I 1587 785 I C : O ; K N 2002 893 M 1963 893 I 1963 932 I 2002 932 I C : O ; K N 2418 1078 M 2379 1078 I 2379 1117 I 2418 1117 I C : O ; K N 2833 1227 M 2794 1227 I 2794 1266 I 2833 1266 I C : O ; K 1 Lj 9 Lw N 1536 1069 M 1496 1084 I K N 1451 1100 M 1411 1115 I K N 1366 1131 M 1326 1146 I K N 1281 1162 M 1241 1177 I K N 1196 1193 M 1186 1197 I K N 1952 1228 M 1912 1210 I K N 1867 1190 M 1827 1172 I K N 1782 1152 M 1742 1135 I K N 1697 1115 M 1657 1097 I K N 1612 1077 M 1600 1071 I K N 2370 1483 M 2330 1458 I K N 2285 1430 M 2245 1405 I K N 2200 1377 M 2160 1352 I K N 2115 1324 M 2075 1299 I K N 2030 1271 M 2013 1261 I K N 2781 1420 M 2741 1428 I K N 2696 1438 M 2656 1447 I K N 2611 1456 M 2571 1465 I K N 2526 1474 M 2486 1483 I K N 2441 1492 M 2433 1494 I K N 3197 1500 M 3157 1491 I K N 3112 1481 M 3072 1472 I K N 3027 1462 M 2987 1453 I K N 2942 1442 M 2902 1433 I K N 2857 1423 M 2848 1421 I K 3 Lw N 1175 1208 M 1175 1196 1164 1186 1152 1186 -c 1140 1186 1130 1196 1130 1208 -c 1130 1220 1140 1231 1152 1231 -c 1164 1231 1175 1220 1175 1208 -c C : O ; K N 1590 1056 M 1590 1044 1579 1034 1567 1034 -c 1555 1034 1545 1044 1545 1056 -c 1545 1068 1555 1079 1567 1079 -c 1579 1079 1590 1068 1590 1056 -c C : O ; K N 2005 1241 M 2005 1229 1994 1219 1982 1219 -c 1970 1219 1960 1229 1960 1241 -c 1960 1253 1970 1264 1982 1264 -c 1994 1264 2005 1253 2005 1241 -c C : O ; K N 2421 1500 M 2421 1488 2410 1478 2398 1478 -c 2386 1478 2376 1488 2376 1500 -c 2376 1512 2386 1523 2398 1523 -c 2410 1523 2421 1512 2421 1500 -c C : O ; K N 2836 1412 M 2836 1400 2825 1390 2813 1390 -c 2801 1390 2791 1400 2791 1412 -c 2791 1424 2801 1435 2813 1435 -c 2825 1435 2836 1424 2836 1412 -c C : O ; K N 3252 1507 M 3252 1495 3241 1485 3229 1485 -c 3217 1485 3207 1495 3207 1507 -c 3207 1519 3217 1530 3229 1530 -c 3241 1530 3252 1519 3252 1507 -c C : O ; K 9 Lw N 1534 1138 M 1524 1140 I K N 1483 1146 M 1473 1148 I K N 1432 1155 M 1422 1156 I K N 1381 1163 M 1371 1165 I K N 1330 1172 M 1320 1173 I K N 1279 1180 M 1269 1182 I K N 1228 1188 M 1218 1190 I K N 1955 1391 M 1945 1384 I K N 1904 1357 M 1894 1350 I K N 1853 1323 M 1843 1316 I K N 1802 1289 M 1792 1282 I K N 1751 1255 M 1741 1248 I K N 1700 1221 M 1690 1214 I K N 1649 1186 M 1639 1180 I K N 1598 1152 M 1597 1152 I K N 2370 1653 M 2360 1647 I K N 2319 1621 M 2309 1615 I K N 2268 1589 M 2258 1583 I K N 2217 1557 M 2207 1551 I K N 2166 1525 M 2156 1519 I K N 2115 1493 M 2105 1486 I K N 2064 1461 M 2054 1454 I K N 2013 1429 M 2013 1429 I K N 2783 1484 M 2773 1489 I K N 2732 1509 M 2722 1514 I K N 2681 1534 M 2671 1539 I K N 2630 1559 M 2620 1563 I K N 2579 1583 M 2569 1588 I K N 2528 1608 M 2518 1613 I K N 2477 1633 M 2467 1638 I K N 3198 1322 M 3188 1326 I K N 3147 1342 M 3137 1345 I K N 3096 1361 M 3086 1365 I K N 3045 1381 M 3035 1385 I K N 2994 1400 M 2984 1404 I K N 2943 1420 M 2933 1424 I K N 2892 1439 M 2882 1443 I K N 3612 1208 M 3602 1211 I K N 3561 1222 M 3551 1224 I K N 3510 1235 M 3500 1238 I K N 3459 1249 M 3449 1251 I K N 3408 1262 M 3398 1265 I K N 3357 1276 M 3347 1279 I K N 3306 1290 M 3296 1292 I K 4 Lw N 1153 1171 M 1178 1216 I 1127 1216 I C : O ; K N 1568 1102 M 1593 1147 I 1542 1147 I C : O ; K N 1983 1380 M 2008 1425 I 1957 1425 I C : O ; K N 2399 1641 M 2424 1686 I 2373 1686 I C : O ; K N 2814 1439 M 2839 1484 I 2788 1484 I C : O ; K N 3230 1280 M 3255 1325 I 3204 1325 I C : O ; K N 3645 1169 M 3670 1214 I 3619 1214 I C : O ; K 9 Lw N 1534 1042 M 1486 1038 I K N 1462 1036 M 1452 1035 I K N 1427 1033 M 1379 1029 I K N 1355 1028 M 1345 1027 I K N 1320 1025 M 1272 1021 I K N 1248 1019 M 1238 1018 I K N 1213 1016 M 1188 1014 I K N 1951 1187 M 1903 1169 I K N 1879 1160 M 1869 1157 I K N 1844 1147 M 1796 1130 I K N 1772 1121 M 1762 1117 I K N 1737 1108 M 1689 1090 I K N 1665 1081 M 1655 1077 I K N 1630 1068 M 1601 1057 I K N 2371 1457 M 2323 1425 I K N 2299 1409 M 2289 1403 I K N 2264 1386 M 2216 1354 I K N 2192 1338 M 2182 1332 I K N 2157 1315 M 2109 1283 I K N 2085 1267 M 2075 1260 I K N 2050 1244 M 2012 1219 I K N 2782 1334 M 2734 1352 I K N 2710 1361 M 2700 1364 I K N 2675 1374 M 2627 1391 I K N 2603 1400 M 2593 1404 I K N 2568 1413 M 2520 1431 I K N 2496 1440 M 2486 1444 I K N 2461 1453 M 2432 1464 I K N 3198 1474 M 3150 1455 I K N 3126 1446 M 3116 1442 I K N 3091 1432 M 3043 1413 I K N 3019 1403 M 3009 1399 I K N 2984 1389 M 2936 1371 I K N 2912 1361 M 2902 1357 I K N 2877 1347 M 2847 1335 I K N 3615 1285 M 3567 1310 I K N 3543 1323 M 3533 1328 I K N 3508 1341 M 3460 1366 I K N 3436 1379 M 3426 1384 I K N 3401 1397 M 3353 1422 I K N 3329 1435 M 3319 1440 I K N 3294 1453 M 3261 1470 I K 4 Lw N 1178 996 M 1153 1041 I 1127 996 I C : O ; K N 1593 1030 M 1568 1075 I 1542 1030 I C : O ; K N 2008 1184 M 1983 1229 I 1957 1184 I C : O ; K N 2424 1461 M 2399 1506 I 2373 1461 I C : O ; K N 2839 1307 M 2814 1352 I 2788 1307 I C : O ; K N 3255 1472 M 3230 1517 I 3204 1472 I C : O ; K N 3670 1254 M 3645 1299 I 3619 1254 I C : O ; K 9 Lw N 1534 1170 M 1498 1168 I K N 1474 1167 M 1464 1167 I K N 1440 1165 M 1430 1165 I K N 1405 1164 M 1369 1162 I K N 1345 1161 M 1335 1160 I K N 1311 1159 M 1301 1159 I K N 1276 1157 M 1240 1156 I K N 1216 1154 M 1206 1154 I K N 1951 1316 M 1915 1302 I K N 1891 1293 M 1881 1290 I K N 1857 1281 M 1847 1277 I K N 1822 1267 M 1786 1254 I K N 1762 1245 M 1752 1241 I K N 1728 1232 M 1718 1228 I K N 1693 1219 M 1657 1205 I K N 1633 1196 M 1623 1193 I K N 2365 1391 M 2329 1385 I K N 2305 1381 M 2295 1380 I K N 2271 1376 M 2261 1374 I K N 2236 1370 M 2200 1364 I K N 2176 1360 M 2166 1358 I K N 2142 1354 M 2132 1353 I K N 2107 1349 M 2071 1343 I K N 2047 1339 M 2037 1337 I K N 2782 1551 M 2746 1537 I K N 2722 1527 M 2712 1523 I K N 2688 1513 M 2678 1509 I K N 2653 1499 M 2617 1485 I K N 2593 1475 M 2583 1471 I K N 2559 1461 M 2549 1457 I K N 2524 1447 M 2488 1433 I K N 2464 1423 M 2454 1419 I K N 3201 1339 M 3165 1360 I K N 3141 1374 M 3131 1380 I K N 3107 1394 M 3097 1399 I K N 3072 1414 M 3036 1435 I K N 3012 1449 M 3002 1455 I K N 2978 1469 M 2968 1474 I K N 2943 1489 M 2907 1510 I K N 2883 1524 M 2873 1530 I K N 2849 1544 M 2844 1546 I K N 3616 1073 M 3580 1096 I K N 3556 1112 M 3546 1118 I K N 3522 1134 M 3512 1140 I K N 3487 1156 M 3451 1180 I K N 3427 1195 M 3417 1202 I K N 3393 1217 M 3383 1224 I K N 3358 1240 M 3322 1263 I K N 3298 1279 M 3288 1285 I K N 3264 1301 M 3260 1303 I K N 4027 973 M 3991 981 I K N 3967 986 M 3957 988 I K N 3933 993 M 3923 995 I K N 3898 1001 M 3862 1008 I K N 3838 1014 M 3828 1016 I K N 3804 1021 M 3794 1023 I K N 3769 1028 M 3733 1036 I K N 3709 1041 M 3699 1043 I K 4 Lw N 1125 1151 M 1153 1123 I 1181 1151 I 1153 1179 I C : O ; K N 1540 1172 M 1568 1144 I 1596 1172 I 1568 1200 I C : O ; K N 1955 1328 M 1983 1300 I 2011 1328 I 1983 1356 I C : O ; K N 2371 1397 M 2399 1369 I 2427 1397 I 2399 1425 I C : O ; K N 2786 1564 M 2814 1536 I 2842 1564 I 2814 1592 I C : O ; K N 3202 1322 M 3230 1294 I 3258 1322 I 3230 1350 I C : O ; K N 3617 1055 M 3645 1027 I 3673 1055 I 3645 1083 I C : O ; K N 4032 966 M 4060 938 I 4088 966 I 4060 994 I C : O ; K 9 Lw N 1535 1419 M 1517 1424 I K N 1496 1429 M 1478 1434 I K N 1457 1439 M 1439 1444 I K N 1418 1450 M 1400 1454 I K N 1379 1460 M 1361 1464 I K N 1340 1470 M 1322 1475 I K N 1301 1480 M 1283 1485 I K N 1262 1490 M 1244 1495 I K N 1223 1500 M 1205 1505 I K N 1949 1449 M 1931 1447 I K N 1910 1445 M 1892 1443 I K N 1871 1441 M 1853 1439 I K N 1832 1437 M 1814 1435 I K N 1793 1433 M 1775 1431 I K N 1754 1429 M 1736 1427 I K N 1715 1425 M 1697 1423 I K N 1676 1421 M 1658 1419 I K N 1637 1417 M 1619 1415 I K N 2367 1329 M 2349 1335 I K N 2328 1342 M 2310 1347 I K N 2289 1354 M 2271 1360 I K N 2250 1367 M 2232 1372 I K N 2211 1379 M 2193 1385 I K N 2172 1392 M 2154 1397 I K N 2133 1404 M 2115 1410 I K N 2094 1417 M 2076 1422 I K N 2055 1429 M 2037 1435 I K N 2016 1442 M 2016 1442 I K N 2782 1468 M 2764 1461 I K N 2743 1453 M 2725 1446 I K N 2704 1438 M 2686 1431 I K N 2665 1422 M 2647 1415 I K N 2626 1407 M 2608 1400 I K N 2587 1392 M 2569 1385 I K N 2548 1377 M 2530 1370 I K N 2509 1361 M 2491 1354 I K N 2470 1346 M 2452 1339 I K N 3196 1493 M 3178 1492 I K N 3157 1492 M 3139 1491 I K N 3118 1490 M 3100 1490 I K N 3079 1489 M 3061 1488 I K N 3040 1488 M 3022 1487 I K N 3001 1486 M 2983 1486 I K N 2962 1485 M 2944 1484 I K N 2923 1484 M 2905 1483 I K N 2884 1482 M 2866 1482 I K N 3611 1475 M 3593 1476 I K N 3572 1477 M 3554 1478 I K N 3533 1479 M 3515 1480 I K N 3494 1481 M 3476 1482 I K N 3455 1483 M 3437 1484 I K N 3416 1485 M 3398 1485 I K N 3377 1486 M 3359 1487 I K N 3338 1488 M 3320 1489 I K N 3299 1490 M 3281 1491 I K N 4036 1079 M 4018 1097 I K N 3997 1118 M 3979 1136 I K N 3959 1157 M 3941 1175 I K N 3920 1196 M 3902 1214 I K N 3881 1235 M 3863 1253 I K N 3843 1274 M 3825 1292 I K N 3804 1313 M 3786 1331 I K N 3765 1352 M 3747 1370 I K N 3727 1391 M 3709 1409 I K N 3688 1430 M 3670 1448 I K N 4446 847 M 4428 857 I K N 4407 868 M 4389 878 I K N 4368 889 M 4350 899 I K N 4329 910 M 4311 920 I K N 4290 931 M 4272 941 I K N 4251 952 M 4233 962 I K N 4212 973 M 4194 983 I K N 4173 994 M 4155 1004 I K N 4134 1015 M 4116 1025 I K N 4095 1036 M 4091 1038 I K 4 Lw N 1123 1519 M 1168 1544 I 1168 1493 I C : O ; K N 1538 1410 M 1583 1435 I 1583 1384 I C : O ; K N 1953 1452 M 1998 1477 I 1998 1426 I C : O ; K N 2369 1319 M 2414 1344 I 2414 1293 I C : O ; K N 2784 1480 M 2829 1505 I 2829 1454 I C : O ; K N 3200 1494 M 3245 1519 I 3245 1468 I C : O ; K N 3615 1473 M 3660 1498 I 3660 1447 I C : O ; K N 4030 1055 M 4075 1080 I 4075 1029 I C : O ; K N 4446 831 M 4491 856 I 4491 805 I C : O ; K 9 Lw N 1534 1293 M 1528 1293 I K N 1515 1293 M 1509 1293 I K N 1496 1293 M 1490 1293 I K N 1477 1293 M 1471 1294 I K N 1458 1294 M 1452 1294 I K N 1439 1294 M 1433 1294 I K N 1420 1294 M 1414 1294 I K N 1401 1294 M 1395 1294 I K N 1382 1294 M 1376 1294 I K N 1363 1294 M 1357 1295 I K N 1344 1295 M 1338 1295 I K N 1325 1295 M 1319 1295 I K N 1306 1295 M 1300 1295 I K N 1287 1295 M 1281 1295 I K N 1268 1295 M 1262 1295 I K N 1249 1295 M 1243 1296 I K N 1230 1296 M 1224 1296 I K N 1211 1296 M 1205 1296 I K N 1192 1296 M 1188 1296 I K N 1952 1450 M 1946 1448 I K N 1933 1442 M 1927 1440 I K N 1914 1434 M 1908 1432 I K N 1895 1427 M 1889 1424 I K N 1876 1419 M 1870 1417 I K N 1857 1411 M 1851 1409 I K N 1838 1403 M 1832 1401 I K N 1819 1396 M 1813 1393 I K N 1800 1388 M 1794 1386 I K N 1781 1380 M 1775 1378 I K N 1762 1372 M 1756 1370 I K N 1743 1365 M 1737 1362 I K N 1724 1357 M 1718 1355 I K N 1705 1349 M 1699 1347 I K N 1686 1341 M 1680 1339 I K N 1667 1334 M 1661 1331 I K N 1648 1326 M 1642 1324 I K N 1629 1318 M 1623 1316 I K N 1610 1310 M 1604 1308 I K N 2367 1612 M 2361 1610 I K N 2348 1605 M 2342 1602 I K N 2329 1597 M 2323 1595 I K N 2310 1590 M 2304 1587 I K N 2291 1582 M 2285 1580 I K N 2272 1575 M 2266 1573 I K N 2253 1568 M 2247 1565 I K N 2234 1560 M 2228 1558 I K N 2215 1553 M 2209 1551 I K N 2196 1545 M 2190 1543 I K N 2177 1538 M 2171 1536 I K N 2158 1531 M 2152 1528 I K N 2139 1523 M 2133 1521 I K N 2120 1516 M 2114 1514 I K N 2101 1508 M 2095 1506 I K N 2082 1501 M 2076 1499 I K N 2063 1494 M 2057 1491 I K N 2044 1486 M 2038 1484 I K N 2025 1479 M 2019 1477 I K N 2781 1712 M 2775 1711 I K N 2762 1708 M 2756 1706 I K N 2743 1703 M 2737 1702 I K N 2724 1699 M 2718 1698 I K N 2705 1695 M 2699 1693 I K N 2686 1690 M 2680 1689 I K N 2667 1686 M 2661 1684 I K N 2648 1682 M 2642 1680 I K N 2629 1677 M 2623 1676 I K N 2610 1673 M 2604 1671 I K N 2591 1668 M 2585 1667 I K N 2572 1664 M 2566 1663 I K N 2553 1660 M 2547 1658 I K N 2534 1655 M 2528 1654 I K N 2515 1651 M 2509 1650 I K N 2496 1647 M 2490 1645 I K N 2477 1642 M 2471 1641 I K N 2458 1638 M 2452 1637 I K N 2439 1634 M 2433 1632 I K N 3196 1691 M 3190 1691 I K N 3177 1692 M 3171 1693 I K N 3158 1694 M 3152 1694 I K N 3139 1695 M 3133 1696 I K N 3120 1697 M 3114 1697 I K N 3101 1698 M 3095 1699 I K N 3082 1700 M 3076 1700 I K N 3063 1701 M 3057 1701 I K N 3044 1702 M 3038 1703 I K N 3025 1704 M 3019 1704 I K N 3006 1705 M 3000 1706 I K N 2987 1707 M 2981 1707 I K N 2968 1708 M 2962 1708 I K N 2949 1709 M 2943 1710 I K N 2930 1711 M 2924 1711 I K N 2911 1712 M 2905 1713 I K N 2892 1714 M 2886 1714 I K N 2873 1715 M 2867 1716 I K N 2854 1717 M 2849 1717 I K N 3613 1542 M 3607 1544 I K N 3594 1549 M 3588 1552 I K N 3575 1557 M 3569 1559 I K N 3556 1564 M 3550 1566 I K N 3537 1571 M 3531 1573 I K N 3518 1578 M 3512 1581 I K N 3499 1586 M 3493 1588 I K N 3480 1593 M 3474 1595 I K N 3461 1600 M 3455 1602 I K N 3442 1607 M 3436 1610 I K N 3423 1615 M 3417 1617 I K N 3404 1622 M 3398 1624 I K N 3385 1629 M 3379 1631 I K N 3366 1636 M 3360 1639 I K N 3347 1644 M 3341 1646 I K N 3328 1651 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4201 1481 M 4195 1485 I K N 4182 1495 M 4176 1499 I K N 4163 1509 M 4157 1513 I K N 4144 1522 M 4138 1527 I K N 4125 1536 M 4119 1541 I K N 4106 1550 M 4100 1554 I K 4 Lw N 1183 1296 M 1138 1321 I 1138 1270 I C : O ; K N 1598 1293 M 1553 1318 I 1553 1267 I C : O ; K N 2013 1463 M 1968 1488 I 1968 1437 I C : O ; K N 2429 1624 M 2384 1649 I 2384 1598 I C : O ; K N 2844 1720 M 2799 1745 I 2799 1694 I C : O ; K N 3260 1688 M 3215 1713 I 3215 1662 I C : O ; K N 3675 1530 M 3630 1555 I 3630 1504 I C : O ; K N 4090 1583 M 4045 1608 I 4045 1557 I C : O ; K N 4506 1282 M 4461 1307 I 4461 1256 I C : O ; K 2921 1098 M (v''=1)[93 35 35 108 0]xS 5749 1977 M (v''=0)[93 35 35 108 0]xS : 3626 0 38 148 rc /F0S89 F0 [137.844 0 0 -137.844 0 0 ] mFS F0S89 Ji 3626 117 M ( )S ; /F0S00IFFFFFF76 F0 [0 -137.844 -137.844 0 0 0 ] mFS F0S00IFFFFFF76 Ji 6581 2322 M ( )S 0 Lj 9 Lw N 6190 2911 M 3746 2911 I 3746 3988 I 6190 3988 I C : 1 1 1 1 scol O ; K 1 Lj N 3769 3113 M 4238 3113 I K 0 Lj 4 Lw N 4027 3088 M 3978 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%%+ procset Pscript_WinNT_ErrorHandler 5.0 0 %%+ procset Pscript_FatalError 5.0 0 %%+ procset Pscript_Win_Basic 5.0 0 %%+ procset Pscript_Win_Utils_L2 5.0 0 %%+ procset Pscript_Text 5.0 0 %%+ procset Pscript_Encoding256 5.0 0 %%+ procset Pscript_Win_GdiObject 5.0 0 %%+ procset Pscript_Win_GdiObject_L2 5.0 0 Pscript_WinNT_Incr dup /terminate get exec %%EOF %%EndDocument @endspecial 171 x(FIG.)22 b(3:)33 b Fk(N)2376 3748 y Fh(exp)2482 3740 y Fk(=)l(N)2577 3754 y Fh(B)2650 3740 y Fo(of)23 b(D)2793 3748 y Fn(2)2827 3740 y Fo(\()p Fk(v)2897 3708 y Fj(00)2959 3740 y Fo(=)e(0,)i(1\))g(desorbing)f(from)g (S/Pd\(100\))2042 3827 y(as)j(a)f(function)h(of)g(the)f(rotational)i (quan)n(tum)21 b(state)k Fk(J)3625 3795 y Fj(00)3690 3827 y Fo(for)h(di\013eren)n(t)2042 3914 y(surface)h(temp)r(eratures.) 2125 4267 y Fr(The)19 b(rotational)e(co)r(oling)h(is)h(caused)f(b)n(y)h (the)g(rotational)e(steer-)2042 4363 y(ing)36 b(e\013ect.)65 b(The)37 b(ma)5 b(jorit)n(y)36 b(of)g(molecules)h(are)e(desorbing)h(in) 2042 4458 y(rotational)21 b(states)i(with)h(lo)n(w)e(quan)n(tum)i(n)n (um)n(b)r(er)f(and)g(th)n(us)g(lo)n(w)2042 4554 y(rotational)k(energy) -7 b(.)38 b(The)28 b(a)n(v)n(erage)d(rotational)i(energy)g(is)i(then) 2042 4649 y(lo)n(w)n(er)21 b(than)i(exp)r(ected)g(for)f(molecules)g(in) h(thermal)f(equilibrium)2042 4745 y(at)29 b Fg(T)2194 4757 y Ff(S)2242 4745 y Fr(.)43 b(Molecules)29 b(desorbing)f(in)i(the)g (\014rst)f(vibrational)f(state)2042 4840 y(ha)n(v)n(e)34 b(rotational)g(energies)g(on)h(a)n(v)n(erage)e(larger)g(than)j Fg(T)3877 4852 y Ff(S)3925 4840 y Fr(.)60 b(In)2042 4936 y(this)20 b(state)f(rotational)f(steering)h(is)h(th)n(us)g(not)f(imp)r (ortan)n(t)h(to)f(pro-)2042 5031 y(mote)24 b(disso)r(ciativ)n(e)g(stic) n(king.)35 b(Rather,)25 b(vibrationally)e(assisted)2042 5127 y(stic)n(king)2320 5096 y Fh(22)2426 5127 y Fr(is)37 b(the)g(dominan)n(t)f(mec)n(hanism)g(to)g(o)n(v)n(ercome)f(the)2042 5222 y(reaction)29 b(barrier,)g(see)h(b)r(elo)n(w.)45 b(In)30 b(addition)g(in)h(all)f(rotational)2042 5318 y(states)h(of)g Fg(v)2423 5287 y Fq(00)2496 5318 y Fr(=)e(1)i (rotational-translational)d(energy)i(transfer)2042 5413 y(supp)r(orts)d(the)h(reaction.)p eop %%Page: 5 5 5 4 bop 4043 -299 a Fr(5)-150 1295 y @beginspecial 20 @llx 245 @lly 810 @urx 810 @ury 2450 @rwi @setspecial %%BeginDocument: vibtemp.ps %!PS-Adobe-3.0 EPSF-3.0 %%Title: Evib %%Creator: Pscript.dll Version 5.0 %%CreationDate: 4/9/2002 13:14:12 %%For: rutkowm %%BoundingBox: 20 245 810 810 %%Pages: 1 %%Orientation: Landscape %%PageOrder: Ascend %%DocumentNeededResources: (atend) %%DocumentSuppliedResources: (atend) %%DocumentData: Clean7Bit %%TargetDevice: (Colorwriter LSR 2000) (2015.108) 0 %%LanguageLevel: 2 %%EndComments %%BeginDefaults %%PageBoundingBox: 20 9 830 586 %%EndDefaults %%BeginProlog %%BeginResource: file Pscript_WinNT_ErrorHandler 5.0 0 /currentpacking where{pop/oldpack currentpacking def/setpacking where{pop false setpacking}if}if/$brkpage 64 dict def $brkpage begin/prnt{dup type/stringtype ne{=string cvs}if dup length 6 mul/tx exch def/ty 10 def currentpoint/toy exch def/tox exch def 1 setgray newpath tox toy 2 sub moveto 0 ty rlineto tx 0 rlineto 0 ty neg rlineto closepath fill tox toy moveto 0 setgray show}bind def /nl{currentpoint exch pop lmargin exch moveto 0 -10 rmoveto}def/=={/cp 0 def typeprint nl}def/typeprint{dup type exec}readonly def/lmargin 72 def/rmargin 72 def/tprint{dup length cp add rmargin gt{nl/cp 0 def}if dup length cp add/cp exch def prnt}readonly def/cvsprint{=string cvs tprint( )tprint}readonly def /integertype{cvsprint}readonly def/realtype{cvsprint}readonly def/booleantype {cvsprint}readonly def/operatortype{(--)tprint =string cvs tprint(-- )tprint} readonly def/marktype{pop(-mark- )tprint}readonly def/dicttype{pop (-dictionary- )tprint}readonly def/nulltype{pop(-null- )tprint}readonly def /filetype{pop(-filestream- )tprint}readonly def/savetype{pop(-savelevel- ) tprint}readonly def/fonttype{pop(-fontid- )tprint}readonly def/nametype{dup xcheck not{(/)tprint}if cvsprint}readonly def/stringtype{dup rcheck{(\()tprint tprint(\))tprint}{pop(-string- )tprint}ifelse}readonly def/arraytype{dup rcheck {dup xcheck{({)tprint{typeprint}forall(})tprint}{([)tprint{typeprint}forall(]) tprint}ifelse}{pop(-array- )tprint}ifelse}readonly def/packedarraytype{dup rcheck{dup xcheck{({)tprint{typeprint}forall(})tprint}{([)tprint{typeprint} forall(])tprint}ifelse}{pop(-packedarray- )tprint}ifelse}readonly def/courier /Courier findfont 10 scalefont def end errordict/handleerror{systemdict begin $error begin $brkpage begin newerror{/newerror false store vmstatus pop pop 0 ne{grestoreall}if showpage initgraphics courier setfont lmargin 720 moveto errorname(VMError)eq{PrtVMMsg}{(ERROR: )prnt errorname prnt nl (OFFENDING COMMAND: )prnt/command load prnt $error/ostack known{nl nl(STACK:) prnt nl nl $error/ostack get aload length{==}repeat}if}ifelse systemdict /showpage 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Ausgabeformat die Option "Optimale Portierung".)115 470 (Stellen Sie sicher, daß auf der Registerkarte "Geräteeinstellungen" die Angabe für "Verfügbarer Postscript-Speicher" korrekt ist.) 115 455(Reduzieren Sie die Anzahl der im Dokument verwendeten Schriftarten. ) 115 440(Drucken Sie das Dokument in verschiedenen Teilstücken. )115 425 12 /Times-Roman showpage(%%[ PrinterError: Low Printer VM ]%%)= true FatalErrorIf} if}bind def end version cvi 2016 ge{/VM?{pop}bind def}{/VM? userdict/PrtVMMsg get def}ifelse %%BeginResource: file Pscript_Win_Basic 5.0 0 /d/def load def/,/load load d/~/exch , d/?/ifelse , d/!/pop , d/`/begin , d/^ /index , d/@/dup , d/+/translate , d/$/roll , d/U/userdict , d/M/moveto , d/- /rlineto , d/&/currentdict , d/:/gsave , d/;/grestore , d/F/false , d/T/true , d/N/newpath , d/E/end , d/Ac/arc , d/An/arcn , d/A/ashow , d/D/awidthshow , d/C /closepath , d/V/div , d/O/eofill , d/L/fill , d/I/lineto , d/-c/curveto , d/-M /rmoveto , d/+S/scale , d/Ji/setfont , d/Lc/setlinecap , d/Lj/setlinejoin , d /Lw/setlinewidth , d/Lm/setmiterlimit , d/sd/setdash , d/S/show , d/LH/showpage , d/K/stroke , d/W/widthshow , d/R/rotate , d/L2? false/languagelevel where{pop languagelevel 2 ge{pop true}if}if d L2?{/xS/xshow , d/yS/yshow , d/zS/xyshow , d}if/b{bind d}bind d/bd{bind d}bind d/xd{~ d}bd/ld{, d}bd/bn/bind ld/lw/Lw ld /lc/Lc ld/lj/Lj ld/sg/setgray ld/ADO_mxRot null d/self & d/OrgMx matrix currentmatrix d/reinitialize{: OrgMx setmatrix[/TextInit/GraphInit/UtilsInit counttomark{@ where{self eq}{F}?{cvx exec}{!}?}repeat cleartomark ;}b /initialize{`{/ADO_mxRot ~ d/TextInitialised? F d reinitialize E}{U /Pscript_Win_Data 230 dict @ ` put/ADO_mxRot ~ d/TextInitialised? F d reinitialize}?}b/terminate{!{& self eq{exit}{E}?}loop E}b/suspend/terminate , d /resume{` Pscript_Win_Data `}b U `/lucas 21690 d/featurebegin{countdictstack lucas[}b/featurecleanup{stopped{cleartomark @ lucas eq{! exit}if}loop countdictstack ~ sub @ 0 gt{{E}repeat}{!}?}b E/snap{transform 0.25 sub round 0.25 add ~ 0.25 sub round 0.25 add ~ itransform}b/dsnap{dtransform round ~ round ~ idtransform}b/nonzero_round{@ 0.5 ge{round}{@ -0.5 lt{round}{0 ge{1} {-1}?}?}?}b/nonzero_dsnap{dtransform nonzero_round ~ nonzero_round ~ idtransform}b U<04>cvn{}put/rr{1 ^ 0 - 0 ~ - neg 0 - C}b/irp{4 -2 $ + +S fx 4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/rp{4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/solid{[]0 sd}b/g {@ not{U/DefIf_save save put}if U/DefIf_bool 2 ^ put}b/DefIf_El{if U/DefIf_bool get not @{U/DefIf_save get restore}if}b/e{DefIf_El !}b/UDF{L2?{undefinefont}{!} ?}b/UDR{L2?{undefineresource}{! !}?}b/freeVM{/Courier findfont[40 0 0 -40 0 0] makefont Ji 2 vmreclaim}b %%EndResource %%BeginResource: file Pscript_Win_Utils_L2 5.0 0 /rf/rectfill , d/fx{1 1 dtransform @ 0 ge{1 sub 0.5}{1 add -0.5}? 3 -1 $ @ 0 ge {1 sub 0.5}{1 add -0.5}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{4 -2 $ snap + +S fx rf}b/rs/rectstroke , d/rc/rectclip , d/UtilsInit{currentglobal{F setglobal}if}b/scol{! setcolor}b/colspA/DeviceGray d/colspABC/DeviceRGB d /colspRefresh{colspABC setcolorspace}b/SetColSpace{colspABC setcolorspace}b /resourcestatus where{!/ColorRendering/ProcSet resourcestatus{! ! T}{F}?}{F}? not{/ColorRendering<>/defineresource where{!/ProcSet defineresource !}{! !}?}if/buildcrdname{/ColorRendering/ProcSet findresource ` mark GetHalftoneName @ type @/nametype ne ~/stringtype ne and{!/none}if(.) GetPageDeviceName @ type @/nametype ne ~/stringtype ne and{!/none}if(.)5 ^ 0 5 -1 1{^ length add}for string 6 1 $ 5 ^ 5{~ 1 ^ cvs length 1 ^ length 1 ^ sub getinterval}repeat ! cvn 3 1 $ ! ! E}b/definecolorrendering{~ buildcrdname ~ /ColorRendering defineresource !}b/findcolorrendering where{!}{ /findcolorrendering{buildcrdname @/ColorRendering resourcestatus{! ! T}{ /ColorRendering/ProcSet findresource ` GetSubstituteCRD E F}?}b}? /selectcolorrendering{findcolorrendering !/ColorRendering findresource setcolorrendering}b %%EndResource end %%EndProlog %%BeginSetup [ 0 1 -1 0 0 0 ] false Pscript_WinNT_Incr dup /initialize get exec 1 setlinecap 1 setlinejoin /mysetup [ 0.11999 0 0 -0.11999 9 821.99908 ] def %%EndSetup %%Page: 1 1 %%PageBoundingBox: 20 9 830 586 %%EndPageComments %%BeginPageSetup /DeviceRGB dup setcolorspace /colspABC exch def mysetup concat colspRefresh %%EndPageSetup 0 0 0 1 scol Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Text 5.0 0 /TextInit{TextInitialised? not{/Pscript_Windows_Font & d/TextInitialised? T d /fM[1 0 0 1 0 0]d/mFM matrix d/iMat[1 0 0.212557 1 0 0]d}if}b/copyfont{1 ^ length add dict `{1 ^/FID ne{d}{! !}?}forall & E}b/EncodeDict 11 dict d/bullets {{/bullet}repeat}b/rF{3 copyfont @ ` ~ EncodeDict ~ get/Encoding ~ 3 ^/0 eq{& /CharStrings known{CharStrings/Eth known not{! EncodeDict/ANSIEncodingOld get} if}if}if d E}b/mF{@ 7 1 $ findfont ~{@/Encoding get @ StandardEncoding eq{! T}{ {ISOLatin1Encoding}stopped{! F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{1 ^ ~ rF}{0 copyfont}? 6 -2 $ ! ! ~ !/pd_charset @ where{~ get 128 eq{@ FDV 2 copy get @ length array copy put pd_CoverFCRange}if}{!}? 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/xUP null d/yUP null d/uW null d/xSP null d/ySP null d/sW null d/sSU{N /uW ~ d/yUP ~ d/xUP ~ d}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ d/ySP ~ d/xSP ~ d}b/sT {xSP ySP sW sLT}b/sR{: + R 0 0 M}b/sRxy{: matrix astore concat 0 0 M}b/eR/; , d /AddOrigFP{{&/FontInfo known{&/FontInfo get length 6 add}{6}? dict ` /WinPitchAndFamily ~ d/WinCharSet ~ d/OrigFontType ~ d/OrigFontStyle ~ d /OrigFontName ~ d & E/FontInfo ~ d}{! ! ! ! !}?}b/mFS{makefont Pscript_Windows_Font 3 1 $ put}b/mF42D{0 copyfont `/FontName ~ d 2 copy ~ sub 1 add dict `/.notdef 0 d 2 copy 1 ~{@ 3 ^ sub Encoding ~ get ~ d}for & E /CharStrings ~ d ! ! & @ E/FontName get ~ definefont}b/mF42{15 dict ` @ 4 1 $ FontName ~ d/FontType 0 d/FMapType 2 d/FontMatrix[1 0 0 1 0 0]d 1 ^ 254 add 255 idiv @ array/Encoding ~ d 0 1 3 -1 $ 1 sub{@ Encoding 3 1 $ put}for/FDepVector Encoding length array d/CharStrings 2 dict `/.notdef 0 d & E d 0 1 Encoding length 1 sub{@ @ 10 lt{! FontName length 1 add string}{100 lt{FontName length 2 add string}{FontName length 3 add string}?}? @ 0 FontName @ length string cvs putinterval @ 3 -1 $ @ 4 1 $ 3 string cvs FontName length ~ putinterval cvn 1 ^ 256 mul @ 255 add 3 -1 $ 4 ^ findfont mF42D FDepVector 3 1 $ put}for & @ E /FontName get ~ definefont ! ! ! mF}b/mF_OTF_V{3{~ !}repeat 3 -1 $ ! findfont 1 ^ ~ definefont fM @ @ 5 0 put 4 0 put 90 matrix R matrix concatmatrix makefont Pscript_Windows_Font 3 1 $ put}b/UmF{L2?{Pscript_Windows_Font ~ undef}{!}?}b /UmF42{@ findfont/FDepVector get{/FontName get undefinefont}forall undefinefont}b %%EndResource end reinitialize Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Encoding256 5.0 0 /CharCol256Encoding[/.notdef/breve/caron/dotaccent/dotlessi/fi/fl/fraction /hungarumlaut/Lslash/lslash/minus/ogonek/ring/Zcaron/zcaron/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/exclam/quotedbl/numbersign /dollar/percent/ampersand/quotesingle/parenleft/parenright/asterisk/plus/comma /hyphen/period/slash/zero/one/two/three/four/five/six/seven/eight/nine/colon /semicolon/less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N/O/P/Q/R/S /T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright/asciicircum/underscore/grave /a/b/c/d/e/f/g/h/i/j/k/l/m/n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright /asciitilde/.notdef/Euro/.notdef/quotesinglbase/florin/quotedblbase/ellipsis /dagger/daggerdbl/circumflex/perthousand/Scaron/guilsinglleft/OE/.notdef /.notdef/.notdef/.notdef/quoteleft/quoteright/quotedblleft/quotedblright/bullet /endash/emdash/tilde/trademark/scaron/guilsinglright/oe/.notdef/.notdef /Ydieresis/.notdef/exclamdown/cent/sterling/currency/yen/brokenbar/section /dieresis/copyright/ordfeminine/guillemotleft/logicalnot/.notdef/registered /macron/degree/plusminus/twosuperior/threesuperior/acute/mu/paragraph /periodcentered/cedilla/onesuperior/ordmasculine/guillemotright/onequarter /onehalf/threequarters/questiondown/Agrave/Aacute/Acircumflex/Atilde/Adieresis /Aring/AE/Ccedilla/Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute /Icircumflex/Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute/Thorn/germandbls /agrave/aacute/acircumflex/atilde/adieresis/aring/ae/ccedilla/egrave/eacute /ecircumflex/edieresis/igrave/iacute/icircumflex/idieresis/eth/ntilde/ograve /oacute/ocircumflex/otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex /udieresis/yacute/thorn/ydieresis]def EncodeDict/256 CharCol256Encoding put %%EndResource end reinitialize %%IncludeResource: font Helvetica F /F0 0 /256 T /Helvetica mF /F0SB8 F0 [184.391 0 0 -184.391 0 0 ] mFS F0SB8 Ji 790 4354 M (400)[103 103 0]xS 1870 4354 M (500)[103 103 0]xS 2950 4354 M (600)[103 103 0]xS 4030 4354 M (700)[103 103 0]xS 5110 4354 M (800)[103 103 0]xS 6190 4354 M (900)[103 103 0]xS 561 4185 M (400)[103 103 0]xS 561 3636 M (500)[103 103 0]xS 561 3086 M (600)[103 103 0]xS 561 2537 M (700)[103 103 0]xS 561 1987 M (800)[103 103 0]xS 561 1438 M (900)[103 103 0]xS 458 888 M (1000)[103 103 103 0]xS 458 339 M (1100)[103 103 103 0]xS Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Win_GdiObject 5.0 0 /SavedCTM null d/CTMsave{/SavedCTM SavedCTM currentmatrix d}b/CTMrestore {SavedCTM setmatrix}b/mp null d/ADO_mxRot null d/GDIHMatrix null d /GDIHPatternDict 22 dict d GDIHPatternDict `/PatternType 1 d/PaintType 2 d/Reps L2?{1}{5}? d/XStep 8 Reps mul d/YStep XStep d/BBox[0 0 XStep YStep]d/TilingType 1 d/PaintProc{` 1 Lw[]0 sd PaintData , exec E}b/FGnd null d/BGnd null d /HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b/HS_BDiagonal {biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? d/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b /vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag{Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E/makehatch{4 -2 $/yOrg ~ d /xOrg ~ d GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix xOrg yOrg + mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0 /HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{/h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5 /HS_DiagCross makehatch}b/GDIBWPatternMx null d/pfprep{save 8 1 $ /PatternOfTheDay 8 1 $ GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/yExt ~ d/Width ~ d/BGnd ~ d/FGnd ~ d/Height yExt RepsV mul d/mx[Width 0 0 Height 0 0]d E build_pattern ~ !}b/pfbf{/fEOFill ~ d pfprep hbf fEOFill{O}{L}? restore}b /GraphInit{GDIHMatrix null eq{/SavedCTM matrix d : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ nonzero_dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly d ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E nonzero_dsnap +S/GDIBWPatternMx matrix currentmatrix readonly d ; ;}if}b %%EndResource %%BeginResource: file Pscript_Win_GdiObject_L2 5.0 0 /GDIBWPatternDict 25 dict @ `/PatternType 1 d/PaintType 1 d/RepsV 1 d/RepsH 1 d /BBox[0 0 RepsH 1]d/TilingType 1 d/XStep 1 d/YStep 1 d/Height 8 RepsV mul d /Width 8 d/mx[Width 0 0 Height neg 0 Height]d/FGnd null d/BGnd null d /SetBGndFGnd{BGnd null ne{BGnd aload ! scol BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! scol}if}b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E d/mp/makepattern , d /build_pattern{CTMsave GDIBWPatternMx setmatrix/nupangle where{! nupangle -90 eq{nupangle R}if}if GDIBWPatternDict @ ` Width Height ne{Width Height gt{Width Height V 1}{1 Height Width V}? +S}if xOrg yOrg E matrix + mp CTMrestore}b/hbf {setpattern}b/hf{:/fEOFill ~ d ~ ! setpattern fEOFill{O}{L}? ;}b/pbf{: ! /fEOFill ~ d GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/OutputBPP ~ d /Height ~ d/Width ~ d/PaintType 1 d/PatternType 1 d/TilingType 1 d/BBox[0 0 Width Height]d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d 20 dict @ ` /ImageType 1 d/Width Width d/Height Height d/ImageMatrix[1 0 0 1 0 0]d /BitsPerComponent 8 d OutputBPP 24 eq{/Decode[0 1 0 1 0 1]d}{OutputBPP 8 eq{ /Decode[0 1]d}{/Decode[0 1 0 1 0 1 0 1]d}?}?/DataSource{PaintData}d E/ImageDict ~ d/PaintProc{` ImageDict image E}b & mx makepattern setpattern E fEOFill{O}{L} ? ;}b/mask_pbf{:/fEOFill ~ d 20 dict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/Height ~ d/Width ~ d/PatternType 1 d/PaintType 2 d/TilingType 1 d/BBox[0 0 Width Height] d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d/PaintProc{` Width Height T[1 0 0 1 0 0]{PaintData}imagemask E}b & mx makepattern setpattern E fEOFill{O} {L}? ;}b %%EndResource end reinitialize 1 Lj 1 Lc 13 Lw solid N 945 4134 M 945 4065 I K N 1485 4134 M 1485 4099 I K N 2025 4134 M 2025 4065 I K N 2565 4134 M 2565 4099 I K N 3105 4134 M 3105 4065 I K N 3645 4134 M 3645 4099 I K N 4185 4134 M 4185 4065 I K N 4725 4134 M 4725 4099 I K N 5265 4134 M 5265 4065 I K N 5805 4134 M 5805 4099 I K N 6345 4134 M 6345 4065 I K N 945 4134 M 6345 4134 I K N 945 4134 M 1014 4134 I K N 945 3859 M 980 3859 I K N 945 3585 M 1014 3585 I K N 945 3310 M 980 3310 I K N 945 3035 M 1014 3035 I K N 945 2760 M 980 2760 I K N 945 2486 M 1014 2486 I K N 945 2211 M 980 2211 I K N 945 1936 M 1014 1936 I K N 945 1662 M 980 1662 I K N 945 1387 M 1014 1387 I K N 945 1112 M 980 1112 I K N 945 837 M 1014 837 I K N 945 563 M 980 563 I K N 945 288 M 1014 288 I K N 945 4134 M 945 288 I K N 945 288 M 945 288 I K N 1485 288 M 1485 288 I K N 2025 288 M 2025 288 I K N 2565 288 M 2565 288 I K N 3105 288 M 3105 288 I K N 3645 288 M 3645 288 I K N 4185 288 M 4185 288 I K N 4725 288 M 4725 288 I K N 5265 288 M 5265 288 I K N 5805 288 M 5805 288 I K N 6345 288 M 6345 288 I K N 945 288 M 6345 288 I K N 6345 4134 M 6345 4134 I K N 6345 3859 M 6345 3859 I K N 6345 3585 M 6345 3585 I K N 6345 3310 M 6345 3310 I K N 6345 3035 M 6345 3035 I K N 6345 2760 M 6345 2760 I K N 6345 2486 M 6345 2486 I K N 6345 2211 M 6345 2211 I K N 6345 1936 M 6345 1936 I K N 6345 1662 M 6345 1662 I K N 6345 1387 M 6345 1387 I K N 6345 1112 M 6345 1112 I K N 6345 837 M 6345 837 I K N 6345 563 M 6345 563 I K N 6345 288 M 6345 288 I K N 6345 4134 M 6345 288 I K 18 Lw : 945 288 5401 3847 rc N -3375 6332 M 9585 -261 I K ; 13 Lw N 975 4043 M 989 4035 I K N 1048 4004 M 1062 3996 I K N 1121 3965 M 1135 3957 I K N 1194 3926 M 1208 3918 I K N 1267 3887 M 1281 3879 I K N 1340 3848 M 1354 3840 I K N 1413 3809 M 1427 3801 I K N 1486 3769 M 1500 3762 I K N 1559 3730 M 1573 3723 I K N 1632 3691 M 1646 3683 I K N 1705 3651 M 1719 3644 I K N 1778 3612 M 1792 3605 I K N 1851 3573 M 1865 3565 I K N 1924 3533 M 1938 3526 I K N 1997 3494 M 2011 3487 I K N 2070 3455 M 2084 3447 I K N 2143 3415 M 2157 3407 I K N 2216 3375 M 2230 3367 I K N 2289 3335 M 2303 3328 I K N 2362 3296 M 2376 3288 I K N 2435 3256 M 2449 3248 I K N 2508 3216 M 2522 3208 I K N 2581 3176 M 2595 3169 I K N 2654 3136 M 2668 3129 I K N 2727 3097 M 2741 3089 I K N 2800 3057 M 2814 3049 I K N 2873 3017 M 2887 3009 I K N 2946 2977 M 2960 2969 I K N 3019 2937 M 3033 2929 I K N 3092 2897 M 3104 2891 I K N 3104 2891 M 3106 2889 I K N 3165 2857 M 3179 2849 I K N 3238 2817 M 3252 2809 I K N 3311 2777 M 3325 2769 I K N 3384 2737 M 3398 2729 I K N 3457 2696 M 3471 2689 I K N 3530 2656 M 3544 2649 I K N 3603 2616 M 3617 2608 I K N 3676 2576 M 3690 2568 I K N 3749 2535 M 3763 2528 I K N 3822 2495 M 3836 2487 I K N 3895 2455 M 3909 2447 I K N 3968 2414 M 3982 2406 I K N 4041 2374 M 4055 2366 I K N 4114 2333 M 4128 2326 I K N 4187 2293 M 4201 2285 I K N 4260 2252 M 4274 2244 I K N 4333 2211 M 4347 2203 I K N 4406 2170 M 4420 2163 I K N 4479 2130 M 4493 2122 I K N 4552 2089 M 4566 2081 I K N 4625 2048 M 4639 2040 I K N 4698 2007 M 4712 1999 I K N 4771 1966 M 4785 1958 I K N 4844 1925 M 4858 1917 I K N 4917 1884 M 4931 1876 I K N 4990 1843 M 5004 1835 I K N 5063 1802 M 5077 1794 I K N 5136 1761 M 5150 1754 I K N 5209 1720 M 5223 1713 I K N 5282 1679 M 5296 1671 I K N 5355 1638 M 5369 1630 I K N 5428 1597 M 5442 1589 I K N 5501 1556 M 5515 1548 I K N 5574 1514 M 5588 1507 I K N 5647 1473 M 5661 1465 I K N 5720 1432 M 5734 1424 I K N 5793 1391 M 5804 1385 I K N 5804 1385 M 5807 1383 I K N 5866 1349 M 5880 1341 I K N 5939 1308 M 5953 1300 I K N 6012 1266 M 6026 1258 I K N 6085 1225 M 6099 1217 I K N 6158 1183 M 6172 1175 I K N 6231 1142 M 6245 1134 I K N 6304 1100 M 6318 1092 I K 8 Lw N 2035 3047 M 2035 3018 2011 2994 1981 2994 -c 1951 2994 1928 3018 1928 3047 -c 1928 3077 1951 3101 1981 3101 -c 2011 3101 2035 3077 2035 3047 -c C : O ; K N 2586 2814 M 2586 2785 2562 2761 2532 2761 -c 2502 2761 2479 2785 2479 2814 -c 2479 2844 2502 2868 2532 2868 -c 2562 2868 2586 2844 2586 2814 -c C : O ; K N 3169 2443 M 3169 2414 3145 2390 3115 2390 -c 3085 2390 3062 2414 3062 2443 -c 3062 2473 3085 2497 3115 2497 -c 3145 2497 3169 2473 3169 2443 -c C : O ; K N 3633 2021 M 3633 1992 3609 1968 3579 1968 -c 3549 1968 3526 1992 3526 2021 -c 3526 2051 3549 2075 3579 2075 -c 3609 2075 3633 2051 3633 2021 -c C : O ; K N 4108 1689 M 4108 1660 4084 1636 4054 1636 -c 4024 1636 4001 1660 4001 1689 -c 4001 1719 4024 1743 4054 1743 -c 4084 1743 4108 1719 4108 1689 -c C : O ; K N 4724 1378 M 4724 1349 4700 1325 4670 1325 -c 4640 1325 4617 1349 4617 1378 -c 4617 1408 4640 1432 4670 1432 -c 4700 1432 4724 1408 4724 1378 -c C : O ; K N 5329 1107 M 5329 1078 5305 1054 5275 1054 -c 5245 1054 5222 1078 5222 1107 -c 5222 1137 5245 1161 5275 1161 -c 5305 1161 5329 1137 5329 1107 -c C : O ; K 18 Lw N 1187 579 M 1617 579 I K /F0SA9 F0 [169.172 0 0 -169.172 0 0 ] mFS F0SA9 Ji 1617 637 M ( thermal equilibrium T)[47 47 95 95 57 142 95 38 47 95 95 95 38 38 38 95 57 38 95 142 47 0]xS /F0S65 F0 [101.145 0 0 -101.145 0 0 ] mFS F0S65 Ji 3257 703 M (vib)[51 22 0]xS F0SA9 Ji 3386 637 M (=T)[99 0]xS F0S65 Ji 3589 703 M (S)S 7 Lw N 1450 804 M 1450 777 1428 756 1401 756 -c 1374 756 1353 777 1353 804 -c 1353 831 1374 853 1401 853 -c 1428 853 1450 831 1450 804 -c C : O ; K F0SA9 Ji 1617 863 M ( exp. D)[47 95 85 95 47 47 47 0]xS F0S65 Ji 2203 929 M (2)S F0SA9 Ji 2259 863 M ( S/Pd\(100\))[47 47 113 47 113 95 57 95 95 95 0]xS 13 Lw N 1187 1031 M 1201 1031 I K N 1260 1031 M 1274 1031 I K N 1333 1031 M 1347 1031 I K N 1406 1031 M 1420 1031 I K N 1479 1031 M 1493 1031 I K N 1552 1031 M 1566 1031 I K 1617 1089 M ( theo. H)[47 47 95 95 95 47 47 0]xS F0S65 Ji 2213 1155 M (2)S F0SA9 Ji 2269 1089 M ( / p\(2x2\) S/Pd\(100\))[47 47 47 95 57 95 85 95 57 47 113 47 113 95 57 95 95 95 0]xS /F0S00IFFFFFF56 F0 [0 -169.172 -169.172 0 0 0 ] mFS F0S00IFFFFFF56 Ji 6610 2347 M ( )S : 3622 0 47 142 rc F0SA9 Ji 3622 105 M ( )S ; /F0S00IFFFFFF38 F0 [0 -199.605 -199.605 0 0 0 ] mFS F0S00IFFFFFF38 Ji 299 3900 M (vibrational temperature E)[-100 -44 -111 -67 -111 -56 -44 -111 -111 -111 -44 -56 -56 -111 -167 -111 -111 -67 -111 -56 -111 -67 -111 -56 0]yS /F0S00IFFFFFF88 F0 [0 -119.047 -119.047 0 0 0 ] mFS F0S00IFFFFFF88 Ji 376 1667 M (vib)[-59 -26 0]yS F0S00IFFFFFF38 Ji 299 1518 M ( / k)[-56 -56 -56 0]yS F0S00IFFFFFF88 Ji 376 1251 M (B)S F0S00IFFFFFF38 Ji 299 1174 M ( [K])[-56 -56 -56 -133 0]yS /F0SD6 F0 [214.824 0 0 -214.824 0 0 ] mFS F0SD6 Ji 2350 4660 M (surface temperature T)[108 120 72 60 120 108 120 60 60 120 179 120 120 72 120 60 120 72 120 60 0]xS /F0S80 F0 [128.895 0 0 -128.895 0 0 ] mFS F0S80 Ji 4472 4744 M (S)S F0SD6 Ji 4558 4660 M ( [K])[60 60 60 143 0]xS LH %%PageTrailer %%Trailer %%DocumentNeededResources: %%+ font Helvetica %%DocumentSuppliedResources: %%+ procset Pscript_WinNT_ErrorHandler 5.0 0 %%+ procset Pscript_FatalError 5.0 0 %%+ procset Pscript_Win_Basic 5.0 0 %%+ procset Pscript_Win_Utils_L2 5.0 0 %%+ procset Pscript_Text 5.0 0 %%+ procset Pscript_Encoding256 5.0 0 %%+ procset Pscript_Win_GdiObject 5.0 0 %%+ procset Pscript_Win_GdiObject_L2 5.0 0 Pscript_WinNT_Incr dup /terminate get exec %%EOF %%EndDocument @endspecial 170 x Fo(FIG.)31 b(4:)43 b(Vibrational)32 b(energy)e Fk(E)862 1480 y Fh(vib)986 1465 y Fo(plotted)g(as)h Fk(T)1399 1480 y Fh(vib)1522 1465 y Fo(=)d Fk(E)1667 1480 y Fh(vib)1761 1465 y Fk(=k)1839 1473 y Fl(B)-150 1552 y Fo(v)n(ersus)23 b(the)h(surface)h(temp)r(erature)d Fk(T)947 1560 y Fl(S)992 1552 y Fo(.)33 b(Filled)25 b(circles:)35 b(exp)r(erimen-)-150 1639 y(tal)d(results)g(for)g(the)f(sulfur)h(co)n (v)n(ered)f(surface;)k(dashed)c(line:)47 b(theo-)-150 1726 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F d reinitialize}?}b/terminate{!{& self eq{exit}{E}?}loop E}b/suspend/terminate , d /resume{` Pscript_Win_Data `}b U `/lucas 21690 d/featurebegin{countdictstack lucas[}b/featurecleanup{stopped{cleartomark @ lucas eq{! exit}if}loop countdictstack ~ sub @ 0 gt{{E}repeat}{!}?}b E/snap{transform 0.25 sub round 0.25 add ~ 0.25 sub round 0.25 add ~ itransform}b/dsnap{dtransform round ~ round ~ idtransform}b/nonzero_round{@ 0.5 ge{round}{@ -0.5 lt{round}{0 ge{1} {-1}?}?}?}b/nonzero_dsnap{dtransform nonzero_round ~ nonzero_round ~ idtransform}b U<04>cvn{}put/rr{1 ^ 0 - 0 ~ - neg 0 - C}b/irp{4 -2 $ + +S fx 4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/rp{4 2 $ M 1 ^ 0 - 0 ~ - neg 0 -}b/solid{[]0 sd}b/g {@ not{U/DefIf_save save put}if U/DefIf_bool 2 ^ put}b/DefIf_El{if U/DefIf_bool get not @{U/DefIf_save get restore}if}b/e{DefIf_El !}b/UDF{L2?{undefinefont}{!} ?}b/UDR{L2?{undefineresource}{! !}?}b/freeVM{/Courier findfont[40 0 0 -40 0 0] makefont Ji 2 vmreclaim}b %%EndResource %%BeginResource: file Pscript_Win_Utils_L2 5.0 0 /rf/rectfill , d/fx{1 1 dtransform @ 0 ge{1 sub 0.5}{1 add -0.5}? 3 -1 $ @ 0 ge {1 sub 0.5}{1 add -0.5}? 3 1 $ 4 1 $ idtransform 4 -2 $ idtransform}b/BZ{4 -2 $ snap + +S fx rf}b/rs/rectstroke , d/rc/rectclip , d/UtilsInit{currentglobal{F setglobal}if}b/scol{! setcolor}b/colspA/DeviceGray d/colspABC/DeviceRGB d /colspRefresh{colspABC setcolorspace}b/SetColSpace{colspABC setcolorspace}b /resourcestatus where{!/ColorRendering/ProcSet resourcestatus{! ! T}{F}?}{F}? not{/ColorRendering<>/defineresource where{!/ProcSet defineresource !}{! !}?}if/buildcrdname{/ColorRendering/ProcSet findresource ` mark GetHalftoneName @ type @/nametype ne ~/stringtype ne and{!/none}if(.) GetPageDeviceName @ type @/nametype ne ~/stringtype ne and{!/none}if(.)5 ^ 0 5 -1 1{^ length add}for string 6 1 $ 5 ^ 5{~ 1 ^ cvs length 1 ^ length 1 ^ sub getinterval}repeat ! cvn 3 1 $ ! ! E}b/definecolorrendering{~ buildcrdname ~ /ColorRendering defineresource !}b/findcolorrendering where{!}{ /findcolorrendering{buildcrdname @/ColorRendering resourcestatus{! ! T}{ /ColorRendering/ProcSet findresource ` GetSubstituteCRD E F}?}b}? /selectcolorrendering{findcolorrendering !/ColorRendering findresource setcolorrendering}b %%EndResource end %%EndProlog %%BeginSetup [ 0 1 -1 0 0 0 ] false Pscript_WinNT_Incr dup /initialize get exec 1 setlinecap 1 setlinejoin /mysetup [ 0.11999 0 0 -0.11999 9 821.99908 ] def %%EndSetup %%Page: 1 1 %%PageBoundingBox: 20 9 830 586 %%EndPageComments %%BeginPageSetup /DeviceRGB dup setcolorspace /colspABC exch def mysetup concat colspRefresh %%EndPageSetup 0 0 0 1 scol Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Text 5.0 0 /TextInit{TextInitialised? not{/Pscript_Windows_Font & d/TextInitialised? T d /fM[1 0 0 1 0 0]d/mFM matrix d/iMat[1 0 0.212557 1 0 0]d}if}b/copyfont{1 ^ length add dict `{1 ^/FID ne{d}{! !}?}forall & E}b/EncodeDict 11 dict d/bullets {{/bullet}repeat}b/rF{3 copyfont @ ` ~ EncodeDict ~ get/Encoding ~ 3 ^/0 eq{& /CharStrings known{CharStrings/Eth known not{! 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F}{eq}?{T}{@ ` T 32 1 127{Encoding 1 ^ get StandardEncoding 3 -1 $ get eq and}for E}?}?}{F}?{1 ^ ~ rF}{0 copyfont}? 6 -2 $ ! ! ~ !/pd_charset @ where{~ get 128 eq{@ FDV 2 copy get @ length array copy put pd_CoverFCRange}if}{!}? 2 ^ ~ definefont fM 5 4 -1 $ put fM 4 0 put fM makefont Pscript_Windows_Font 3 1 $ put}b/sLT{: Lw -M currentpoint snap M 0 - 0 Lc K ;}b/xUP null d/yUP null d/uW null d/xSP null d/ySP null d/sW null d/sSU{N /uW ~ d/yUP ~ d/xUP ~ d}b/sU{xUP yUP uW sLT}b/sST{N/sW ~ d/ySP ~ d/xSP ~ d}b/sT {xSP ySP sW sLT}b/sR{: + R 0 0 M}b/sRxy{: matrix astore concat 0 0 M}b/eR/; , d /AddOrigFP{{&/FontInfo known{&/FontInfo get length 6 add}{6}? dict ` /WinPitchAndFamily ~ d/WinCharSet ~ d/OrigFontType ~ d/OrigFontStyle ~ d /OrigFontName ~ d & E/FontInfo ~ d}{! ! ! ! !}?}b/mFS{makefont Pscript_Windows_Font 3 1 $ put}b/mF42D{0 copyfont `/FontName ~ d 2 copy ~ sub 1 add dict `/.notdef 0 d 2 copy 1 ~{@ 3 ^ sub Encoding ~ get ~ d}for & E /CharStrings ~ d ! ! & @ E/FontName get ~ definefont}b/mF42{15 dict ` @ 4 1 $ FontName ~ d/FontType 0 d/FMapType 2 d/FontMatrix[1 0 0 1 0 0]d 1 ^ 254 add 255 idiv @ array/Encoding ~ d 0 1 3 -1 $ 1 sub{@ Encoding 3 1 $ put}for/FDepVector Encoding length array d/CharStrings 2 dict `/.notdef 0 d & E d 0 1 Encoding length 1 sub{@ @ 10 lt{! FontName length 1 add string}{100 lt{FontName length 2 add string}{FontName length 3 add string}?}? @ 0 FontName @ length string cvs putinterval @ 3 -1 $ @ 4 1 $ 3 string cvs FontName length ~ putinterval cvn 1 ^ 256 mul @ 255 add 3 -1 $ 4 ^ findfont mF42D FDepVector 3 1 $ put}for & @ E /FontName get ~ definefont ! ! ! mF}b/mF_OTF_V{3{~ !}repeat 3 -1 $ ! findfont 1 ^ ~ definefont fM @ @ 5 0 put 4 0 put 90 matrix R matrix concatmatrix makefont Pscript_Windows_Font 3 1 $ put}b/UmF{L2?{Pscript_Windows_Font ~ undef}{!}?}b /UmF42{@ findfont/FDepVector get{/FontName get undefinefont}forall undefinefont}b %%EndResource end reinitialize Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Encoding256 5.0 0 /CharCol256Encoding[/.notdef/breve/caron/dotaccent/dotlessi/fi/fl/fraction /hungarumlaut/Lslash/lslash/minus/ogonek/ring/Zcaron/zcaron/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/exclam/quotedbl/numbersign /dollar/percent/ampersand/quotesingle/parenleft/parenright/asterisk/plus/comma /hyphen/period/slash/zero/one/two/three/four/five/six/seven/eight/nine/colon /semicolon/less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N/O/P/Q/R/S /T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright/asciicircum/underscore/grave /a/b/c/d/e/f/g/h/i/j/k/l/m/n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright /asciitilde/.notdef/Euro/.notdef/quotesinglbase/florin/quotedblbase/ellipsis /dagger/daggerdbl/circumflex/perthousand/Scaron/guilsinglleft/OE/.notdef /.notdef/.notdef/.notdef/quoteleft/quoteright/quotedblleft/quotedblright/bullet /endash/emdash/tilde/trademark/scaron/guilsinglright/oe/.notdef/.notdef /Ydieresis/.notdef/exclamdown/cent/sterling/currency/yen/brokenbar/section /dieresis/copyright/ordfeminine/guillemotleft/logicalnot/.notdef/registered /macron/degree/plusminus/twosuperior/threesuperior/acute/mu/paragraph /periodcentered/cedilla/onesuperior/ordmasculine/guillemotright/onequarter /onehalf/threequarters/questiondown/Agrave/Aacute/Acircumflex/Atilde/Adieresis /Aring/AE/Ccedilla/Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute /Icircumflex/Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute/Thorn/germandbls /agrave/aacute/acircumflex/atilde/adieresis/aring/ae/ccedilla/egrave/eacute /ecircumflex/edieresis/igrave/iacute/icircumflex/idieresis/eth/ntilde/ograve /oacute/ocircumflex/otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex /udieresis/yacute/thorn/ydieresis]def EncodeDict/256 CharCol256Encoding put %%EndResource end reinitialize %%IncludeResource: font Helvetica F /F0 0 /256 T /Helvetica mF /F0SA9 F0 [169.172 0 0 -169.172 0 0 ] mFS F0SA9 Ji 1109 4342 M (1.2)[95 47 0]xS 1677 4342 M (1.3)[95 47 0]xS 2246 4342 M (1.4)[95 47 0]xS 2814 4342 M (1.5)[95 47 0]xS 3382 4342 M (1.6)[95 47 0]xS 3951 4342 M (1.7)[95 47 0]xS 4519 4342 M (1.8)[95 47 0]xS 5087 4342 M (1.9)[95 47 0]xS 5656 4342 M (2.0)[95 47 0]xS 6224 4342 M (2.1)[95 47 0]xS 575 4181 M (-7.5)[57 95 47 0]xS 575 3589 M (-7.0)[57 95 47 0]xS 575 2998 M (-6.5)[57 95 47 0]xS 575 2406 M (-6.0)[57 95 47 0]xS 575 1814 M (-5.5)[57 95 47 0]xS 575 1223 M (-5.0)[57 95 47 0]xS 575 631 M (-4.5)[57 95 47 0]xS Pscript_WinNT_Incr begin %%BeginResource: file Pscript_Win_GdiObject 5.0 0 /SavedCTM null d/CTMsave{/SavedCTM SavedCTM currentmatrix d}b/CTMrestore {SavedCTM setmatrix}b/mp null d/ADO_mxRot null d/GDIHMatrix null d /GDIHPatternDict 22 dict d GDIHPatternDict `/PatternType 1 d/PaintType 2 d/Reps L2?{1}{5}? d/XStep 8 Reps mul d/YStep XStep d/BBox[0 0 XStep YStep]d/TilingType 1 d/PaintProc{` 1 Lw[]0 sd PaintData , exec E}b/FGnd null d/BGnd null d /HS_Horizontal{horiz}b/HS_Vertical{vert}b/HS_FDiagonal{fdiag}b/HS_BDiagonal {biag}b/HS_Cross{horiz vert}b/HS_DiagCross{fdiag biag}b/MaxXYStep XStep YStep gt{XStep}{YStep}? d/horiz{Reps{0 4 M XStep 0 - 0 8 +}repeat 0 -8 Reps mul + K}b /vert{Reps{4 0 M 0 YStep - 8 0 +}repeat 0 -8 Reps mul + K}b/biag{Reps{0 0 M MaxXYStep @ - 0 YStep neg M MaxXYStep @ - 0 8 +}repeat 0 -8 Reps mul + 0 YStep M 8 8 - K}b/fdiag{Reps{0 0 M MaxXYStep @ neg - 0 YStep M MaxXYStep @ neg - 0 8 +}repeat 0 -8 Reps mul + MaxXYStep @ M 8 -8 - K}b E/makehatch{4 -2 $/yOrg ~ d /xOrg ~ d GDIHPatternDict/PaintData 3 -1 $ put CTMsave GDIHMatrix setmatrix GDIHPatternDict matrix xOrg yOrg + mp CTMrestore ~ U ~ 2 ^ put}b/h0{/h0 /HS_Horizontal makehatch}b/h1{/h1/HS_Vertical makehatch}b/h2{/h2/HS_FDiagonal makehatch}b/h3{/h3/HS_BDiagonal makehatch}b/h4{/h4/HS_Cross makehatch}b/h5{/h5 /HS_DiagCross makehatch}b/GDIBWPatternMx null d/pfprep{save 8 1 $ /PatternOfTheDay 8 1 $ GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/yExt ~ d/Width ~ d/BGnd ~ d/FGnd ~ d/Height yExt RepsV mul d/mx[Width 0 0 Height 0 0]d E build_pattern ~ !}b/pfbf{/fEOFill ~ d pfprep hbf fEOFill{O}{L}? restore}b /GraphInit{GDIHMatrix null eq{/SavedCTM matrix d : ADO_mxRot concat 0 0 snap + : 0.48 @ GDIHPatternDict ` YStep mul ~ XStep mul ~ nonzero_dsnap YStep V ~ XStep V ~ E +S/GDIHMatrix matrix currentmatrix readonly d ; : 0.24 -0.24 +S GDIBWPatternDict ` Width Height E nonzero_dsnap +S/GDIBWPatternMx matrix currentmatrix readonly d ; ;}if}b %%EndResource %%BeginResource: file Pscript_Win_GdiObject_L2 5.0 0 /GDIBWPatternDict 25 dict @ `/PatternType 1 d/PaintType 1 d/RepsV 1 d/RepsH 1 d /BBox[0 0 RepsH 1]d/TilingType 1 d/XStep 1 d/YStep 1 d/Height 8 RepsV mul d /Width 8 d/mx[Width 0 0 Height neg 0 Height]d/FGnd null d/BGnd null d /SetBGndFGnd{BGnd null ne{BGnd aload ! scol BBox aload ! 2 ^ sub ~ 3 ^ sub ~ rf}if FGnd null ne{FGnd aload ! scol}if}b/PaintProc{` SetBGndFGnd RepsH{Width Height F mx PaintData imagemask Width 0 +}repeat E}b E d/mp/makepattern , d /build_pattern{CTMsave GDIBWPatternMx setmatrix/nupangle where{! nupangle -90 eq{nupangle R}if}if GDIBWPatternDict @ ` Width Height ne{Width Height gt{Width Height V 1}{1 Height Width V}? +S}if xOrg yOrg E matrix + mp CTMrestore}b/hbf {setpattern}b/hf{:/fEOFill ~ d ~ ! setpattern fEOFill{O}{L}? ;}b/pbf{: ! /fEOFill ~ d GDIBWPatternDict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/OutputBPP ~ d /Height ~ d/Width ~ d/PaintType 1 d/PatternType 1 d/TilingType 1 d/BBox[0 0 Width Height]d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d 20 dict @ ` /ImageType 1 d/Width Width d/Height Height d/ImageMatrix[1 0 0 1 0 0]d /BitsPerComponent 8 d OutputBPP 24 eq{/Decode[0 1 0 1 0 1]d}{OutputBPP 8 eq{ /Decode[0 1]d}{/Decode[0 1 0 1 0 1 0 1]d}?}?/DataSource{PaintData}d E/ImageDict ~ d/PaintProc{` ImageDict image E}b & mx makepattern setpattern E fEOFill{O}{L} ? ;}b/mask_pbf{:/fEOFill ~ d 20 dict `/yOrg ~ d/xOrg ~ d/PaintData ~ d/Height ~ d/Width ~ d/PatternType 1 d/PaintType 2 d/TilingType 1 d/BBox[0 0 Width Height] d/XStep Width d/YStep Height d/mx xOrg yOrg matrix + d/PaintProc{` Width Height T[1 0 0 1 0 0]{PaintData}imagemask E}b & mx makepattern setpattern E fEOFill{O} {L}? ;}b %%EndResource end reinitialize 1 Lj 1 Lc 13 Lw solid N 944 4134 M 944 4099 I K N 1228 4134 M 1228 4065 I K N 1512 4134 M 1512 4099 I K N 1796 4134 M 1796 4065 I K N 2081 4134 M 2081 4099 I K N 2365 4134 M 2365 4065 I K N 2649 4134 M 2649 4099 I K N 2933 4134 M 2933 4065 I K N 3217 4134 M 3217 4099 I K N 3501 4134 M 3501 4065 I K N 3786 4134 M 3786 4099 I K N 4070 4134 M 4070 4065 I K N 4354 4134 M 4354 4099 I K N 4638 4134 M 4638 4065 I K N 4922 4134 M 4922 4099 I K N 5206 4134 M 5206 4065 I K N 5491 4134 M 5491 4099 I K N 5775 4134 M 5775 4065 I K N 6059 4134 M 6059 4099 I K N 6343 4134 M 6343 4065 I K N 944 4134 M 6343 4134 I K N 944 4134 M 1013 4134 I K N 944 3838 M 979 3838 I K N 944 3542 M 1013 3542 I K N 944 3246 M 979 3246 I K N 944 2951 M 1013 2951 I K N 944 2655 M 979 2655 I K N 944 2359 M 1013 2359 I K N 944 2063 M 979 2063 I K N 944 1767 M 1013 1767 I K N 944 1471 M 979 1471 I K N 944 1176 M 1013 1176 I K N 944 880 M 979 880 I K N 944 584 M 1013 584 I K N 944 288 M 979 288 I K N 944 4134 M 944 288 I K N 944 288 M 944 288 I K N 1228 288 M 1228 288 I K N 1512 288 M 1512 288 I K N 1796 288 M 1796 288 I K N 2081 288 M 2081 288 I K N 2365 288 M 2365 288 I K N 2649 288 M 2649 288 I K N 2933 288 M 2933 288 I K N 3217 288 M 3217 288 I K N 3501 288 M 3501 288 I K N 3786 288 M 3786 288 I K N 4070 288 M 4070 288 I K N 4354 288 M 4354 288 I K N 4638 288 M 4638 288 I K N 4922 288 M 4922 288 I K N 5206 288 M 5206 288 I K N 5491 288 M 5491 288 I K N 5775 288 M 5775 288 I K N 6059 288 M 6059 288 I K N 6343 288 M 6343 288 I K N 944 288 M 6343 288 I K N 6343 4134 M 6343 4134 I K N 6343 3838 M 6343 3838 I K N 6343 3542 M 6343 3542 I K N 6343 3246 M 6343 3246 I K N 6343 2951 M 6343 2951 I K N 6343 2655 M 6343 2655 I K N 6343 2359 M 6343 2359 I K N 6343 2063 M 6343 2063 I K N 6343 1767 M 6343 1767 I K N 6343 1471 M 6343 1471 I K N 6343 1176 M 6343 1176 I K N 6343 880 M 6343 880 I K N 6343 584 M 6343 584 I K N 6343 288 M 6343 288 I K N 6343 4134 M 6343 288 I K 8 Lw N 5919 3785 M 5919 3756 5895 3732 5865 3732 -c 5835 3732 5812 3756 5812 3785 -c 5812 3815 5835 3839 5865 3839 -c 5895 3839 5919 3815 5919 3785 -c C : O ; K N 4851 3222 M 4851 3193 4827 3169 4797 3169 -c 4767 3169 4744 3193 4744 3222 -c 4744 3252 4767 3276 4797 3276 -c 4827 3276 4851 3252 4851 3222 -c C : O ; K N 3918 2460 M 3918 2431 3894 2407 3864 2407 -c 3834 2407 3811 2431 3811 2460 -c 3811 2490 3834 2514 3864 2514 -c 3894 2514 3918 2490 3918 2460 -c C : O ; K N 3286 1756 M 3286 1727 3262 1703 3232 1703 -c 3202 1703 3179 1727 3179 1756 -c 3179 1786 3202 1810 3232 1810 -c 3262 1810 3286 1786 3286 1756 -c C : O ; K N 2722 1291 M 2722 1262 2698 1238 2668 1238 -c 2638 1238 2615 1262 2615 1291 -c 2615 1321 2638 1345 2668 1345 -c 2698 1345 2722 1321 2722 1291 -c C : O ; K N 2090 894 M 2090 865 2066 841 2036 841 -c 2006 841 1983 865 1983 894 -c 1983 924 2006 948 2036 948 -c 2066 948 2090 924 2090 894 -c C : O ; K N 1556 580 M 1556 551 1532 527 1502 527 -c 1472 527 1449 551 1449 580 -c 1449 610 1472 634 1502 634 -c 1532 634 1556 610 1556 580 -c C : O ; K 13 Lw N 5866 3833 M 4798 3033 I 3865 2335 I 3233 1863 I 2669 1441 I 2037 967 I 1503 568 I K N 4325 661 M 4833 661 I K /F0SC7 F0 [199.605 0 0 -199.605 0 0 ] mFS F0SC7 Ji 4833 729 M ( 310 meV)[56 111 111 111 56 167 111 0]xS /F0S00IFFFFFF56 F0 [0 -169.172 -169.172 0 0 0 ] mFS F0S00IFFFFFF56 Ji 6608 2347 M ( )S : 3620 0 47 142 rc F0SA9 Ji 3620 105 M ( )S ; /F0S00IFFFFFF38 F0 [0 -199.605 -199.605 0 0 0 ] mFS F0S00IFFFFFF38 Ji 438 3272 M (ln [N\(v''=1\) / N\(v''=0\)])[-44 -111 -56 -56 -144 -67 -100 -38 -38 -117 -111 -67 -56 -56 -56 -144 -67 -100 -38 -38 -117 -111 -67 0]yS F0SC7 Ji 1731 4648 M (inverse surface temperature 1 / T)[44 111 100 111 67 100 111 56 100 111 67 56 111 100 111 56 56 111 167 111 111 67 111 56 111 67 111 56 56 111 56 56 56 0]xS /F0S77 F0 [119.047 0 0 -119.047 0 0 ] mFS F0S77 Ji 4735 4726 M (S)S F0SC7 Ji 4814 4648 M ( [10)[56 56 56 111 0]xS F0S77 Ji 5204 4539 M (-3)[40 0]xS F0SC7 Ji 5310 4648 M ( K])[56 133 0]xS LH %%PageTrailer %%Trailer %%DocumentNeededResources: %%+ font Helvetica %%DocumentSuppliedResources: %%+ procset Pscript_WinNT_ErrorHandler 5.0 0 %%+ procset Pscript_FatalError 5.0 0 %%+ procset Pscript_Win_Basic 5.0 0 %%+ procset Pscript_Win_Utils_L2 5.0 0 %%+ procset Pscript_Text 5.0 0 %%+ procset Pscript_Encoding256 5.0 0 %%+ procset Pscript_Win_GdiObject 5.0 0 %%+ procset Pscript_Win_GdiObject_L2 5.0 0 Pscript_WinNT_Incr dup /terminate get exec %%EOF %%EndDocument @endspecial 170 x Fo(FIG.)23 b(5:)33 b(Arrhenius)22 b(plot)h(of)h(the)e(relativ)n(e)h(p)r(opulation)h(of)f(D)1644 1473 y Fn(2)1701 1465 y Fo(\()p Fk(v)1771 1433 y Fj(00)1833 1465 y Fo(=)-150 1552 y(1\))37 b(as)h(a)f(function)g(of)h(in)n(v)n (erse)f(surface)h(temp)r(erature)e Fk(T)1588 1519 y Fj(\000)p Fn(1)1577 1574 y Fl(S)1670 1552 y Fo(.)69 b(The)-150 1639 y(straigh)n(t)24 b(line)g(represen)n(ts)g(a)g(least-squares)h (\014t)e(to)h(the)f(data)h(with)g(an)-150 1726 y(activ)l(ation)i (energy)g(of)g(310)14 b(meV.)-150 2007 y Fr(S/Pd\(100\))32 b(surface.)54 b(In)34 b(the)g(vibrational)e(ground)h(state)g(the)-150 2102 y(a)n(v)n(erage)g(rotational)g(energy)i(of)g(the)h(desorbing)e (molecules)h(is)-150 2197 y(lo)n(w)n(er)21 b(than)i(exp)r(ected)g(for)f (molecules)g(in)h(thermal)f(equilibrium)-150 2293 y(with)j(the)f(Pd)g (surface.)35 b(F)-7 b(urther,)24 b(the)h(lo)n(w)e Fg(J)1274 2263 y Fq(00)1317 2293 y Fr(-states)g(are)g(more)-150 2388 y(p)r(opulated)i(than)f(exp)r(ected)h(for)f(an)h(equilibrium)f (distribution.)2042 -83 y(This)e(rotational)f(co)r(oling)g(can)h(b)r(e) g(explained)g(via)g(the)g(principle)2042 12 y(of)31 b(detailed)h (balance)f(b)n(y)g(the)h(rotational)e(steering)g(at)i(lo)n(w)f Fg(J)4042 -18 y Fq(00)2042 108 y Fr(and)23 b(as)g(the)h(rotational)e (hindering)h(in)h(adsorption)e(for)h(high-)p Fg(J)4042 78 y Fq(00)2042 203 y Fr(due)k(to)g(the)g(anisotrop)n(y)e(of)i(the)h (underlying)e(p)r(oten)n(tial)h(energy)2042 299 y(surface.)54 b(The)34 b(vibrational)e(temp)r(erature)h(in)h(desorption,)g(on)2042 394 y(the)e(other)e(hand,)j(is)e(signi\014can)n(tly)g(larger)e(than)j (exp)r(ected)g(for)2042 490 y(thermal)39 b(equilibrium)h(with)h(the)f (surface)f(temp)r(erature)g(and)2042 585 y(larger)22 b(than)h(the)h(vibrational)f(temp)r(eratures)g(of)g(D)3676 597 y Fh(2)3738 585 y Fr(desorbing)2042 681 y(from)39 b(the)i(clean)e(Pd\(100\))g(surface.)73 b(Theoretical)38 b(quan)n(tum)2042 776 y(dynamic)23 b(calculations)f(based)h(on)g(a)f (six-dimensional)g(PES)h(for)2042 872 y(the)f(p\(2)8 b Fe(\002)g Fr(2\))21 b(S/Pd\(100\))g(surface)g(can)h(curren)n(tly)f (not)h(satisfac-)2042 967 y(torily)31 b(describ)r(e)h(the)h(exp)r (erimen)n(tal)f(results)g(for)g(the)g(reaction)2042 1063 y(on)g(S/Pd\(100\).)49 b(In)n(v)n(estigations)31 b(of)h(the)h(sulfur)f (co)n(v)n(erage)d(b)r(e-)2042 1158 y(fore)22 b(and)h(after)g(a)g (desorption)f(exp)r(erimen)n(t)h(sho)n(w)f(a)h(decreasing)2042 1254 y(amoun)n(t)37 b(of)g(sulfur)g(whic)n(h)h(could)f(b)r(e)g(caused)g (b)n(y)g(desorption)2042 1349 y(of)h(D)2210 1361 y Fh(2)2248 1349 y Fr(S.)h(This)f(damaging)f(the)i(w)n(ell-ordered)e(sulfur)h(adla) n(y)n(er)2042 1445 y(ma)n(y)33 b(only)g(b)r(e)h(e\013ectiv)n(e)f(in)h (desorption)f(exp)r(erimen)n(ts,)i(where)2042 1540 y(the)e(adsorb)r(ed) f(D)h(atoms)g(come)f(closer)g(to)h(the)g(sulfur)g(atoms.)2042 1636 y(In)39 b(adsorption)f(exp)r(erimen)n(ts)g(thermal)h(molecules)f (with)i(lo)n(w)2042 1731 y(kinetic)34 b(energy)f(do)h(not)h(reac)n(h)e (the)h(surface,)i(b)r(ecause)e(of)g(the)2042 1826 y(high)26 b(repulsiv)n(e)f(p)r(oten)n(tial)h(barrier)e(at)i(the)h(c\(2)15 b Fe(\002)g Fr(2\))26 b(o)n(v)n(erla)n(y)n(er,)2042 1922 y(molecules)31 b(with)i(high)f(kinetic)g(energies)f(ma)n(y)-7 b(,)33 b(ho)n(w)n(ev)n(er,)e(also)2042 2017 y(react)f(with)h(adsorb)r (ed)f(S)h(atoms)f(leading)g(to)h(a)f(c)n(hange)g(of)h(the)2042 2113 y(co)n(v)n(erage.)2125 2293 y(W)-7 b(e)44 b(gratefully)e(ac)n(kno) n(wledge)f(\014nancial)i(supp)r(ort)h(b)n(y)f(the)2042 2388 y(Deutsc)n(he)28 b(F)-7 b(orsc)n(h)n(ungsgemeinsc)n(haft)24 b(\(Za)k(110/15\).)p 948 2586 2039 5 v 1203 2587 1529 7 v 1458 2588 1020 9 v 1712 2589 510 11 v -121 2802 a Fj(\003)-52 2834 y Fo(Electronic)f(address:)35 b Fa(rutkowm@uni-)t (muenster.de)-118 2889 y Fj(y)-52 2921 y Fo(Electronic)27 b(address:)35 b Fa(agross@ph.tum.de)-120 2976 y Fn(1)-52 3008 y Fo(A.)26 b(Gross,)35 b(Surf.)26 b(Sci.)g(Rep.)g Fi(32)p Fo(,)g(291)h(\(1998\).)-120 3063 y Fn(2)-52 3095 y Fo(G.)f(J.)h(Kro)r(es,)35 b(Prog.)27 b(Surf.)f(Sci.)g Fi(60)p Fo(,)g(1)g(\(1999\).)-120 3151 y Fn(3)-52 3182 y Fo(G.)e(Comsa,)h(R.)e(Da)n(vid,)h(and)f(Sc)n(h)n(umac)n(her,)29 b(Surf.)24 b(Sci.)g Fi(95)p Fo(,)g(L210)-52 3269 y(\(1980\).)-120 3325 y Fn(4)-52 3357 y Fo(K.)f(D.)f(Rendulic,)h(G.)h(Anger,)f(and)f(A.) h(Winkler,)30 b(Surf.)22 b(Sci.)h Fi(208)p Fo(,)-52 3444 y(404)k(\(1989\).)-120 3499 y Fn(5)-52 3531 y Fo(L.)k(Sc)n(hr\177)-38 b(oter,)32 b(R.)f(Da)n(vid,)h(and)e(H.)h(Zac)n(harias,)52 b(Surf.)31 b(Sci.)g Fi(258)p Fo(,)-52 3618 y(259)c(\(1991\).)-120 3674 y Fn(6)-52 3705 y Fo(L.)h(Sc)n(hr\177)-38 b(oter,)28 b(C.)g(T)-6 b(rame,)27 b(R.)g(Da)n(vid,)h(and)f(H.)g(Zac)n(harias,)41 b(Surf.)-52 3793 y(Sci.)26 b Fi(272)p Fo(,)h(229)g(\(1992\).)-120 3848 y Fn(7)-52 3880 y Fo(C.)36 b(Resc)n(h,)h(H.)e(F.)h(Berger,)j(K.)c (D.)g(Rendulic,)i(and)d(E.)i(Bertel,)-52 3967 y(Surf.)26 b(Sci.)g Fi(316)p Fo(,)h(L1105)g(\(1994\).)-120 4022 y Fn(8)-52 4054 y Fo(D.)38 b(W)-6 b(etzig,)41 b(R.)c(Dopheide,)k(M.)d (Rutk)n(o)n(wski,)i(R.)d(Da)n(vid,)k(and)-52 4141 y(H.)26 b(Zac)n(harias,)36 b(Ph)n(ys.)25 b(Rev.)g(Lett.)h Fi(76)p Fo(,)g(463)h(\(1996\).)-120 4197 y Fn(9)-52 4228 y Fo(D.)32 b(W)-6 b(etzig,)34 b(M.)f(Rutk)n(o)n(wski,)g(and)f(H.)f(Zac)n(harias,) 56 b(ph)n(ys.)32 b(stat.)-52 4316 y(sol.)27 b(\(a\))f Fi(159)p Fo(,)g(263)h(\(1997\).)-150 4371 y Fn(10)-52 4403 y Fo(D.)41 b(W)-6 b(etzig,)45 b(M.)d(Rutk)n(o)n(wski,)i(H.)d(Zac)n (harias,)47 b(and)40 b(A.)h(Gro\031,)-52 4490 y(Ph)n(ys.)26 b(Rev.)f(B)h Fi(63)p Fo(,)g(205412)i(\(2001\).)-150 4545 y Fn(11)-52 4577 y Fo(A.)23 b(Gross,)j(S.)d(Wilk)n(e,)h(and)f(M.)h(Sc)n (he\013)6 b(ler,)30 b(Ph)n(ys.)23 b(Rev.)g(Lett.)h Fi(75)p Fo(,)-52 4664 y(2718)j(\(1995\).)-150 4720 y Fn(12)-52 4751 y Fo(S.)f(Wilk)n(e)g(and)f(M.)h(Sc)n(he\013)6 b(ler,)34 b(Ph)n(ys.)26 b(Rev.)f(B)h Fi(53)p Fo(,)g(4926)h(\(1996\).)-150 4807 y Fn(13)-52 4839 y Fo(A.)i(Gross,)h(S.)f(Wilk)n(e,)h(and)e(M.)h (Sc)n(he\013)6 b(ler,)43 b(Surf.)29 b(Sci.)g Fi(357)p Fo(,)h(614)-52 4926 y(\(1996\).)-150 4981 y Fn(14)-52 5013 y Fo(A.)23 b(Gross)g(and)f(M.)i(Sc)n(he\013)6 b(ler,)29 b(Prog.)24 b(Surf.)e(Sci.)h Fi(53)p Fo(,)h(187)g(\(1997\).)-150 5068 y Fn(15)-52 5100 y Fo(W.)i(Dong)g(and)f(J.)i(Hafner,)34 b(Ph)n(ys.)26 b(Rev.)f(B)h Fi(56)p Fo(,)g(15396)i(\(1997\).)-150 5156 y Fn(16)-52 5187 y Fo(A.)d(Gross)i(and)e(M.)h(Sc)n(he\013)6 b(ler,)34 b(Ph)n(ys.)25 b(Rev.)g(B)h Fi(57)p Fo(,)g(2493)h(\(1998\).) -150 5243 y Fn(17)-52 5274 y Fo(A.)i(Eic)n(hler,)i(G.)e(Kresse,)i(and)e (J.)h(Hafner,)45 b(Surf.)29 b(Sci.)g Fi(397)p Fo(,)i(116)-52 5362 y(\(1998\).)2042 2802 y Fn(18)2140 2834 y Fo(V.)d(Leden)n(tu,)g (W.)g(Dong,)g(and)g(P)-6 b(.)28 b(Sautet,)41 b(Surf.)28 b(Sci.)h Fi(412)p Fo(,)g(518)2140 2921 y(\(1998\).)2042 2976 y Fn(19)2140 3008 y Fo(A.)k(Eic)n(hler,)i(J.)f(Hafner,)h(A.)e (Gro\031,)j(and)c(M.)i(Sc)n(he\013)6 b(ler,)57 b(Ph)n(ys.)2140 3095 y(Rev.)25 b(B)h Fi(59)p Fo(,)h(13297)g(\(1999\).)2042 3151 y Fn(20)2140 3182 y Fo(K.)20 b(D.)h(Rendulic)f(and)g(A.)g (Winkler,)27 b(Surf.)21 b(Sci.)f Fi(299)p Fo(,)j(261)e(\(1994\).)2042 3238 y Fn(21)2140 3269 y Fo(M.)31 b(Rutk)n(o)n(wski,)h(D.)f(W)-6 b(etzig,)33 b(and)d(H.)h(Zac)n(harias,)52 b(Ph)n(ys.)31 b(Rev.)2140 3357 y(Lett.)26 b Fi(87)p Fo(,)g(246101)i(\(2001\).)2042 3412 y Fn(22)2140 3444 y Fo(C.)g(M.)g(W)-6 b(ei,)28 b(A.)f(Gross,)i (and)d(M.)i(Sc)n(he\013)6 b(ler,)39 b(Ph)n(ys.)27 b(Rev.)g(B)g Fi(57)p Fo(,)2140 3531 y(15572)h(\(1998\).)2042 3586 y Fn(23)2140 3618 y Fo(S.)39 b(Wilk)n(e)h(and)f(M.)h(Sc)n(he\013)6 b(ler,)79 b(Ph)n(ys.)39 b(Rev.)g(Lett.)h Fi(76)p Fo(,)k(3380)2140 3705 y(\(1996\).)2042 3761 y Fn(24)2140 3793 y Fo(A.)26 b(Gro\031,)35 b(Appl.)25 b(Ph)n(ys.)h(A)f Fi(67)p Fo(,)h(627)h (\(1998\).)2042 3848 y Fn(25)2140 3880 y Fo(W.)17 b(Meier,)k(H.)c (Rottk)n(e,)h(H.)f(Zac)n(harias,)k(and)c(K.)g(W)-6 b(elge,)23 b(J.)18 b(Chem.)2140 3967 y(Ph)n(ys.)26 b Fi(83)p Fo(,)g(4360)h (\(1985\).)2042 4022 y Fn(26)2140 4054 y Fo(W.)f(Meier,)i(H.)e(Rottk)n (e,)g(and)f(H.)h(Zac)n(harias,)38 b(Inst.)26 b(Ph)n(ys.)g(Conf.)2140 4141 y(Ser.)g Fi(94)p Fo(,)g(93)h(\(1988\).)2042 4197 y Fn(27)2140 4228 y Fo(A.)35 b(Gross,)j(C.)d(M.)h(W)-6 b(ei,)37 b(and)d(M.)h(Sc)n(he\013)6 b(ler,)63 b(Surf.)35 b(Sci.)g Fi(416)p Fo(,)2140 4316 y(L1095)27 b(\(1998\).)2042 4371 y Fn(28)2140 4403 y Fo(W.)d(Brenig,)h(T.)g(Brunner,)f(A.)f (Gro\031,)j(and)d(R.)h(Russ,)31 b(Z.)24 b(Ph)n(ys.)g(B)2140 4490 y Fi(93)p Fo(,)i(91)h(\(1993\).)2042 4545 y Fn(29)2140 4577 y Fo(A.)32 b(Gross)i(and)e(M.)h(Sc)n(he\013)6 b(ler,)56 b(Chem.)32 b(Ph)n(ys.)g(Lett.)h Fi(263)p Fo(,)i(567)2140 4664 y(\(1996\).)2042 4720 y Fn(30)2140 4751 y Fo(M.)h(Gostein)h(and)e (G.)h(O.)g(Sitz,)66 b(J.)37 b(Chem.)e(Ph)n(ys.)h Fi(106)p Fo(,)j(7378)2140 4839 y(\(1997\).)2042 4894 y Fn(31)2140 4926 y Fo(W.)32 b(A.)g(Dino,)h(H.)f(Kasai,)i(and)e(A.)f(Okiji,)55 b(J.)32 b(Ph)n(ys.)g(So)r(c.)g(Jpn.)2140 5013 y Fi(66)p Fo(,)26 b(3344)i(\(1997\).)2042 5068 y Fn(32)2140 5100 y Fo(L.)d(Sc)n(hr\177)-38 b(oter,)25 b(H.)g(Zac)n(harias,)i(and)d(R.)h (Da)n(vid,)33 b(Ph)n(ys.)25 b(Rev.)f(Lett.)2140 5187 y Fi(62)p Fo(,)i(571)h(\(1989\).)2042 5243 y Fn(33)2140 5274 y Fo(J.E.)g(M)r(\177)-41 b(uller,)36 b(Ph)n(ys.)26 b(Rev.)f(Lett.)h Fi(59)p Fo(,)g(2943)h(\(1987\).)2042 5330 y Fn(34)2140 5362 y Fo(A.)21 b(D.)g(Kinnersley)-6 b(,)22 b(G.)f(R.)g(Darling,)i(S.)e(Hollo)n(w)n(a)n(y)-6 b(,)23 b(and)e(B.)h(Ham-)p eop %%Page: 7 7 7 6 bop 4043 -299 a Fr(7)-52 -83 y Fo(mer,)34 b(Surf.)26 b(Sci.)g Fi(364)p Fo(,)g(219)h(\(1996\).)-150 -28 y Fn(35)-52 4 y Fo(G.)49 b(J.)f(Kro)r(es,)55 b(G.)48 b(Wiesenekk)n(er,)53 b(E.)c(J.)f(Baerends,)55 b(R.)48 b(C.)-52 91 y(Mo)n(wrey)-6 b(,)38 b(and)d(D.)g(Neuhauser,)64 b(J.)36 b(Chem.)f(Ph)n(ys.)f Fi(105)p Fo(,)39 b(5979)-52 178 y(\(1996\).)2042 -115 y Fn(36)2140 -83 y Fo(H.)22 b(A.)f(Mic)n(helsen,)j(C.)f(T.)f(Rettner,)g (D.)g(J.)g(Auerbac)n(h,)g(and)g(R.)f(N.)2140 4 y(Zare,)35 b(J.)26 b(Chem.)g(Ph)n(ys.)f Fi(98)p Fo(,)h(8294)i(\(1993\).)p eop %%Trailer end userdict /end-hook known{end-hook}if %%EOF