%!PS-Adobe-2.0 %%Creator: dvips(k) 5.86 Copyright 1999 Radical Eye Software %%Title: NONiO_CPL.dvi %%Pages: 6 %%PageOrder: Ascend %%BoundingBox: 0 0 596 842 %%DocumentFonts: Helvetica %%DocumentPaperSizes: a4 %%EndComments %DVIPSWebPage: (www.radicaleye.com) %DVIPSCommandLine: dvips NONiO_CPL.dvi -o NONiO_CPL.ps %DVIPSParameters: dpi=600, compressed %DVIPSSource: TeX output 2003.04.30:1611 %%BeginProcSet: texc.pro %! /TeXDict 300 dict def TeXDict begin/N{def}def/B{bind def}N/S{exch}N/X{S N}B/A{dup}B/TR{translate}N/isls false N/vsize 11 72 mul N/hsize 8.5 72 mul N/landplus90{false}def/@rigin{isls{[0 landplus90{1 -1}{-1 1}ifelse 0 0 0]concat}if 72 Resolution div 72 VResolution div neg scale isls{ landplus90{VResolution 72 div vsize mul 0 exch}{Resolution -72 div hsize mul 0}ifelse TR}if Resolution VResolution vsize -72 div 1 add mul TR[ matrix currentmatrix{A A round sub abs 0.00001 lt{round}if}forall round exch round exch]setmatrix}N/@landscape{/isls true N}B/@manualfeed{ statusdict/manualfeed true put}B/@copies{/#copies X}B/FMat[1 0 0 -1 0 0] N/FBB[0 0 0 0]N/nn 0 N/IEn 0 N/ctr 0 N/df-tail{/nn 8 dict N nn begin /FontType 3 N/FontMatrix fntrx N/FontBBox FBB N string/base X array /BitMaps X/BuildChar{CharBuilder}N/Encoding IEn N end A{/foo setfont}2 array copy cvx N load 0 nn put/ctr 0 N[}B/sf 0 N/df{/sf 1 N/fntrx FMat N df-tail}B/dfs{div/sf X/fntrx[sf 0 0 sf neg 0 0]N df-tail}B/E{pop nn A definefont setfont}B/Cw{Cd A length 5 sub get}B/Ch{Cd A length 4 sub get }B/Cx{128 Cd A length 3 sub get sub}B/Cy{Cd A length 2 sub get 127 sub} B/Cdx{Cd A length 1 sub get}B/Ci{Cd A type/stringtype ne{ctr get/ctr ctr 1 add N}if}B/id 0 N/rw 0 N/rc 0 N/gp 0 N/cp 0 N/G 0 N/CharBuilder{save 3 1 roll S A/base get 2 index get S/BitMaps get S get/Cd X pop/ctr 0 N Cdx 0 Cx Cy Ch sub Cx Cw add Cy setcachedevice Cw Ch true[1 0 0 -1 -.1 Cx sub Cy .1 sub]/id Ci N/rw Cw 7 add 8 idiv string N/rc 0 N/gp 0 N/cp 0 N{ rc 0 ne{rc 1 sub/rc X rw}{G}ifelse}imagemask restore}B/G{{id gp get/gp gp 1 add N A 18 mod S 18 idiv pl S get exec}loop}B/adv{cp add/cp X}B /chg{rw cp id gp 4 index getinterval putinterval A gp add/gp X adv}B/nd{ /cp 0 N rw exit}B/lsh{rw cp 2 copy get A 0 eq{pop 1}{A 255 eq{pop 254}{ A A add 255 and S 1 and or}ifelse}ifelse put 1 adv}B/rsh{rw cp 2 copy get A 0 eq{pop 128}{A 255 eq{pop 127}{A 2 idiv S 128 and or}ifelse} ifelse put 1 adv}B/clr{rw cp 2 index string putinterval adv}B/set{rw cp fillstr 0 4 index getinterval putinterval adv}B/fillstr 18 string 0 1 17 {2 copy 255 put pop}for N/pl[{adv 1 chg}{adv 1 chg nd}{1 add chg}{1 add chg nd}{adv lsh}{adv lsh nd}{adv rsh}{adv rsh nd}{1 add adv}{/rc X nd}{ 1 add set}{1 add clr}{adv 2 chg}{adv 2 chg nd}{pop nd}]A{bind pop} forall N/D{/cc X A type/stringtype ne{]}if nn/base get cc ctr put nn /BitMaps get S ctr S sf 1 ne{A A length 1 sub A 2 index S get sf div put }if put/ctr ctr 1 add N}B/I{cc 1 add D}B/bop{userdict/bop-hook known{ bop-hook}if/SI save N @rigin 0 0 moveto/V matrix currentmatrix A 1 get A mul exch 0 get A mul add .99 lt{/QV}{/RV}ifelse load def pop pop}N/eop{ SI restore userdict/eop-hook known{eop-hook}if showpage}N/@start{ userdict/start-hook known{start-hook}if pop/VResolution X/Resolution X 1000 div/DVImag X/IEn 256 array N 2 string 0 1 255{IEn S A 360 add 36 4 index cvrs cvn put}for pop 65781.76 div/vsize X 65781.76 div/hsize X}N /p{show}N/RMat[1 0 0 -1 0 0]N/BDot 260 string N/Rx 0 N/Ry 0 N/V{}B/RV/v{ /Ry X/Rx X V}B statusdict begin/product where{pop false[(Display)(NeXT) (LaserWriter 16/600)]{A length product length le{A length product exch 0 exch getinterval eq{pop true exit}if}{pop}ifelse}forall}{false}ifelse end{{gsave TR -.1 .1 TR 1 1 scale Rx Ry false RMat{BDot}imagemask grestore}}{{gsave TR -.1 .1 TR Rx Ry scale 1 1 false RMat{BDot} imagemask grestore}}ifelse B/QV{gsave newpath transform round exch round exch itransform moveto Rx 0 rlineto 0 Ry neg rlineto Rx neg 0 rlineto fill grestore}B/a{moveto}B/delta 0 N/tail{A/delta X 0 rmoveto}B/M{S p delta add tail}B/b{S p tail}B/c{-4 M}B/d{-3 M}B/e{-2 M}B/f{-1 M}B/g{0 M} B/h{1 M}B/i{2 M}B/j{3 M}B/k{4 M}B/w{0 rmoveto}B/l{p -4 w}B/m{p -3 w}B/n{ p -2 w}B/o{p -1 w}B/q{p 1 w}B/r{p 2 w}B/s{p 3 w}B/t{p 4 w}B/x{0 S rmoveto}B/y{3 2 roll p a}B/bos{/SS save N}B/eos{SS restore}B end %%EndProcSet %%BeginProcSet: special.pro %! TeXDict begin/SDict 200 dict N SDict begin/@SpecialDefaults{/hs 612 N /vs 792 N/ho 0 N/vo 0 N/hsc 1 N/vsc 1 N/ang 0 N/CLIP 0 N/rwiSeen false N /rhiSeen false N/letter{}N/note{}N/a4{}N/legal{}N}B/@scaleunit 100 N /@hscale{@scaleunit div/hsc X}B/@vscale{@scaleunit div/vsc X}B/@hsize{ /hs X/CLIP 1 N}B/@vsize{/vs X/CLIP 1 N}B/@clip{/CLIP 2 N}B/@hoffset{/ho X}B/@voffset{/vo X}B/@angle{/ang X}B/@rwi{10 div/rwi X/rwiSeen true N}B /@rhi{10 div/rhi X/rhiSeen true N}B/@llx{/llx X}B/@lly{/lly X}B/@urx{ /urx X}B/@ury{/ury X}B/magscale true def end/@MacSetUp{userdict/md known {userdict/md get type/dicttype eq{userdict begin md length 10 add md maxlength ge{/md md dup length 20 add dict copy def}if end md begin /letter{}N/note{}N/legal{}N/od{txpose 1 0 mtx defaultmatrix dtransform S atan/pa X newpath clippath mark{transform{itransform moveto}}{transform{ itransform lineto}}{6 -2 roll transform 6 -2 roll transform 6 -2 roll transform{itransform 6 2 roll itransform 6 2 roll itransform 6 2 roll curveto}}{{closepath}}pathforall newpath counttomark array astore/gc xdf pop ct 39 0 put 10 fz 0 fs 2 F/|______Courier fnt invertflag{PaintBlack} if}N/txpose{pxs pys scale ppr aload pop por{noflips{pop S neg S TR pop 1 -1 scale}if xflip yflip and{pop S neg S TR 180 rotate 1 -1 scale ppr 3 get ppr 1 get neg sub neg ppr 2 get ppr 0 get neg sub neg TR}if xflip yflip not and{pop S neg S TR pop 180 rotate ppr 3 get ppr 1 get neg sub neg 0 TR}if yflip xflip not and{ppr 1 get neg ppr 0 get neg TR}if}{ noflips{TR pop pop 270 rotate 1 -1 scale}if xflip yflip and{TR pop pop 90 rotate 1 -1 scale ppr 3 get ppr 1 get neg sub neg ppr 2 get ppr 0 get neg sub neg TR}if xflip yflip not and{TR pop pop 90 rotate ppr 3 get ppr 1 get neg sub neg 0 TR}if yflip xflip not and{TR pop pop 270 rotate ppr 2 get ppr 0 get neg sub neg 0 S TR}if}ifelse scaleby96{ppr aload pop 4 -1 roll add 2 div 3 1 roll add 2 div 2 copy TR .96 dup scale neg S neg S TR}if}N/cp{pop pop showpage pm restore}N end}if}if}N/normalscale{ Resolution 72 div VResolution 72 div neg scale magscale{DVImag dup scale }if 0 setgray}N/psfts{S 65781.76 div N}N/startTexFig{/psf$SavedState save N userdict maxlength dict begin/magscale true def normalscale currentpoint TR/psf$ury psfts/psf$urx psfts/psf$lly psfts/psf$llx psfts /psf$y psfts/psf$x psfts currentpoint/psf$cy X/psf$cx X/psf$sx psf$x psf$urx psf$llx sub div N/psf$sy psf$y psf$ury psf$lly sub div N psf$sx psf$sy scale psf$cx psf$sx div psf$llx sub psf$cy psf$sy div psf$ury sub TR/showpage{}N/erasepage{}N/copypage{}N/p 3 def @MacSetUp}N/doclip{ psf$llx psf$lly psf$urx psf$ury currentpoint 6 2 roll newpath 4 copy 4 2 roll moveto 6 -1 roll S lineto S lineto S lineto closepath clip newpath moveto}N/endTexFig{end psf$SavedState restore}N/@beginspecial{SDict begin/SpecialSave save N gsave normalscale currentpoint TR @SpecialDefaults count/ocount X/dcount countdictstack N}N/@setspecial{ CLIP 1 eq{newpath 0 0 moveto hs 0 rlineto 0 vs rlineto hs neg 0 rlineto closepath clip}if ho vo TR hsc vsc scale ang rotate rwiSeen{rwi urx llx sub div rhiSeen{rhi ury lly sub div}{dup}ifelse scale llx neg lly neg TR }{rhiSeen{rhi ury lly sub div dup scale llx neg lly neg TR}if}ifelse CLIP 2 eq{newpath llx lly moveto urx lly lineto urx ury lineto llx ury lineto closepath clip}if/showpage{}N/erasepage{}N/copypage{}N newpath}N /@endspecial{count ocount sub{pop}repeat countdictstack dcount sub{end} repeat grestore SpecialSave restore end}N/@defspecial{SDict begin}N /@fedspecial{end}B/li{lineto}B/rl{rlineto}B/rc{rcurveto}B/np{/SaveX currentpoint/SaveY X N 1 setlinecap newpath}N/st{stroke SaveX SaveY moveto}N/fil{fill SaveX SaveY moveto}N/ellipse{/endangle X/startangle X /yrad X/xrad X/savematrix matrix currentmatrix N TR xrad yrad scale 0 0 1 startangle endangle arc savematrix setmatrix}N end %%EndProcSet TeXDict begin 39158280 55380996 1000 600 600 (NONiO_CPL.dvi) @start %DVIPSBitmapFont: Fa cmmi6 6 11 /Fa 11 122 df<91380FF0039138FFFE06903903F8070E90390FC0019E013FC712FE017C 147C5B4848143C485A48481438485A121F90C8FC481530123E007E1500A25AA516C0A2ED 0180A2007CEC0300A2003C1406003E5C6C5C6C6C13706C6C5B3903F807802600FFFEC7FC EB1FF028247CA22C>67 D79 D<131FEBFF8C3801E0DE3803 807E3807007C48133C121E123E003C5B127CA3485BA215401560903801E0C01278130339 3807E180391C1CF300380FF87F3807E03C1B177E9522>97 D100 DI108 D111 D<380F01F0381FC7F83831CE1CEA61F8EBF03C00C1137C13E014383803C000A4485AA448 C7FCA4121EA2120C16177D951D>114 DI<133013785BA4485AA4485AB51280 A23803C000485AA448C7FCA4121EA25B1480383C03001306A25BEA1C38EA0FF0EA07C011 217D9F18>I121 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fb cmmi9 9 5 /Fb 5 123 df<123C127E12FFA4127E123C08087A8715>58 D<010FB712FEA218FC903A 003FC000031700187C4B143CA2027F151C181892C8FCA25CA24A1303A201014A13380406 13304A1500160E13035E4A137C91B512FC5B5EECF0001638130F16305C1860011F027013 E0046013C04A140104001380133F17034A15005F017F150EA291C8121E5F49157C5F4914 030001ED1FF0B8FCA25F37337DB239>69 D<010FB612F017FE83903B003FC0007FC0EF1F E0EF07F05DEF03F8147FA292C713FCA25CEF07F85CA2010116F0170F4A15E0EF1FC00103 ED3F80EF7F004A14FEEE03FC0107EC1FF091B612C04CC7FC02F0C9FC130FA25CA2131FA2 5CA2133FA25CA2137FA291CAFCA25BA25B1201B512FCA336337DB231>80 D116 D<903807800390381FE0 0790383FF00690387FF80E9038FFFC1C48EBFE789038E03FF03803800190C712E0EC01C0 C7EA0380EC0700140E143C14705C495A495A49C7FC130E133C0170130C49131C48481318 4848133848C71278D80EC013F0380FFE03391F3FFFE0D8381F13C0486C1380D860071300 38E003FE38C000F020227DA024>122 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fc cmsy7 7 1 /Fc 1 4 df<1338A50060130C00F8133E00FC137E00FE13FE383FBBF83807FFC0000113 00EA007C48B4FC000713C0383FBBF838FE38FE00FC137E00F8133E0060130C00001300A5 17197B9A22>3 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fd msbm7 7 1 /Fd 1 127 df<133EEA07FEA2EA007CA213FCA2001FB512C06C1480D801F8C7FCA25BA2 120314FCEBE3FF9038EF0780D807FC13C0EBF00313E0A2EA0FC014071380A2121FEC0F80 1300A248EB1F00A2003E1406143E127EEC7C0C127C151800FCEB3C30157048EB1FE00070 EB0F801F297CA725>126 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fe msbm10 10 1 /Fe 1 127 df126 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Ff cmsy10 10 8 /Ff 8 115 df<007FB81280B912C0A26C17803204799641>0 D<007FB812F8B912FCA26C 17F8CCFCAE007FB812F8B912FCA26C17F8CCFCAE007FB812F8B912FCA26C17F836287BA8 41>17 D60 DI<14C0EB01E01303A214 C01307A21480130FA2EB1F00A2131E133EA25BA2137813F8A2485AA25B1203A25B1207A2 485AA290C7FC5AA2123EA2123C127CA2127812F8A41278127CA2123C123EA27EA27E7FA2 6C7EA212037FA212017FA26C7EA21378137CA27FA2131E131FA2EB0F80A2130714C0A213 0314E0A21301EB00C0135278BD20>104 D<126012F07EA21278127CA2123C123EA27EA2 7E7FA26C7EA212037FA26C7EA212007FA21378137CA27FA2131E131FA2EB0F80A2130714 C0A2130314E0A414C01307A21480130FA2EB1F00A2131E133EA25BA2137813F8A25B1201 A2485AA25B1207A2485AA290C7FC5AA2123EA2123C127CA2127812F8A25A126013527CBD 20>I<126012F0B3B3B3B3A91260045377BD17>I114 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fg cmbx7 7 1 /Fg 1 108 df107 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fh cmex10 10 4 /Fh 4 89 df20 DI80 D88 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fi cmmi7 7 12 /Fi 12 117 df<48B512F8000714FC4814F84814F0D83C07C7FC1270EAC006130E1200A3 131E131CA2133CA35BA313F8A3485AA26C5A1E1A7D981F>28 D<1303A5497EA500C0140C 00FC14FC397FE79FF8000FB512C000031400C613FCEB3FF06D5A497EA2EB7CF8EB7878EB F87CEBF03C48487E48487E497E3907000380000613011E1D7E9C22>63 D<013FB512E016FC903901FC007F4AEB0F80EE07C0010315E016035C17F01307EE07E05C A2010FEC0FC017804AEB1F00163E011F14F8ED07F091B51280A290393F800FE0ED03F002 007F15015BA2137EA201FE1303A2495CA20001160817184914E017380003EDF070B5D8C0 0113E0923800FFC0C9EA3F002D297DA732>82 D99 D<15F8141FA2EC01F0A21403A215E0A2 1407A215C0A2140FEB1F8F90387FCF80EBF0EF3803C03FEA0780390F001F00A2001E5B12 3E003C133E127C147E5A147CA214FC5AECF830A3903801F060A2EA7803010E13C0393C1C F980381FF07F3907C01E001D297CA723>III<130E131F5BA2133E131C90C7FCA7EA03E0487EEA0C78EA187C1230 A212605B12C0A2EA01F0A3485AA2485AA2EBC180EA0F81A2381F0300A213066C5A131CEA 07F06C5A11287DA617>105 D<1407EC0F80141FA21500140E91C7FCA7EB03E0EB07F8EB 0C3C1318EB303E136013C0A248485AA2C7FCA25CA4495AA4495AA4495AA4495AA21238D8 7C1FC7FC12FC133E485AEA70F8EA7FE0EA1F80193380A61B>I111 D115 D<131C133EA25BA45BA4485AB512E0A23801F000 485AA4485AA4485AA448C7FC1460A214C0123EEB0180EB0300EA1E06EA1F1CEA0FF8EA03 E013267EA419>I E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fj cmmi10 10 32 /Fj 32 123 df<1403EC3FF891387FFF80D901E313C014800103133F9138001F80ED0700 92C7FC80A280A2808013018080130080147F81143F8149B47E130790380F8FF0EB3E0F49 6C7E13F83801F003D803E07F1207380FC0011380121FEA3F0014005A127EA212FE5D4813 01A35DA24813035D6C13075D127C4A5A6C91C7FC5C6C133E6C6C5A3807C0F03801FFE0D8 003FC8FC223D7DBB25>14 D18 D<013FB612E090B712F05A120717E0270F807006C7FC391E 00600E48140C003813E04813C048141CEAC0011200148001035BA213071400A25B157801 1E137CA3133E133C137C157E13FC5B1201157F1203497FA3D801C0131C2C257EA32F>25 D<013FB512FE90B7FC5A5A4815FE260F801CC7FCEA1E005A00385B5A5A481378C7FC1470 14F0A4495AA31303A3495AA3130FA25C131FA3133FA291C8FC131E28257EA324>28 D<1503A35DA21506A2150EA2150CA2151CA21518A21538A21530A21570A2EC07FE91383F FFC0903901FCE3F0903907E0E0F890391F80C03ED93E007FEB7C01D801F8EC0F80D803F0 018013C0D807E014071403D80FC015E0D81F801300A248485AA2007E1306A2020E130F12 FE48010C14C0A2021CEB1F80A20218EB3F00A20238137E007C5D1430007E4A5A003E9038 7003F06CEC07C09138600F80D80F80013FC7FC3903E0E0FC3901F8E7F039007FFF80D90F FCC8FCEB01C0A25CA21303A291C9FCA25BA21306A2130EA2130CA22B4B7CB931>30 D<160C161C1618A316381630A316701660A316E05EA315015EA301F80103130FD803FE91 38001F80D8070F153F000E018015C0001C5C001814060038161F0030160FD8701F010E13 070060140C1703D8E03F168000C0EB001C491318EA007E180001FE13384913305F000116 064913700360130E5F000316184901E013384B133017705F0201495AD801F849485A4CC7 FC160E2600FC035B017EEB0078013FEB01E090390FE30F80902603FFFEC8FC9038003FF0 0206C9FCA2140E140CA3141C1418A314381430A314701460324B7EB936>32 D<0140151E01E0153F00015E484816805B120790C9123F000E161F170F5A1707481700A2 003014C014010070010314061260A2170E00E04948130C5A171C92C7FC5FA26C495C4A14 F04A7E6C017F495A4A6C485A3AF801F7E00F3BFE0FF3F83F80267FFFE3B5FC02C191C7FC 6C01815B02005BD80FFCEB7FF0D803F0EB0FC031267FA434>II<121C127FEAFF80A5EA7F00121C0909798817>58 D<121C127FEAFF80A213C0 A3127F121C1200A412011380A2120313005A1206120E5A5A5A12600A19798817>I<150C 151E153EA2153C157CA2157815F8A215F01401A215E01403A215C01407A21580140FA215 005CA2141E143EA2143C147CA2147814F8A25C1301A25C1303A2495AA25C130FA291C7FC 5BA2131E133EA2133C137CA2137813F8A25B1201A25B1203A25B1207A25B120FA290C8FC 5AA2121E123EA2123C127CA2127812F8A25A12601F537BBD2A>61 D<0103B812F05BA290260007F8C7123F4B1407F003E0020F150118005DA2141FA25D19C0 143FA24B1330A2027F1470190092C7126017E05C16014A495A160F49B6FCA25F9138FC00 0F01031407A24A6DC8FCA201075C18034A130660010F160693C7FC4A150E180C011F161C 18184A1538A2013F5E18F04A4A5AA2017F15074D5A91C8123F49913803FF80B9FCA295C7 FC3C397DB83D>69 D<0103B5D8F803B512F8495DA290260007F8C73807F8004B5DA2020F 150F615DA2021F151F615DA2023F153F615DA2027F157F96C7FC92C8FCA24A5D605CA249 B7FC60A202FCC7120101031503605CA201071507605CA2010F150F605CA2011F151F605C A2013F153F605CA2017F157F95C8FC91C8FC496C4A7EB690B6FCA345397DB845>72 D<902603FFF893383FFF80496081D900079438FF80000206DC01BFC7FCA2020E4C5A1A7E 020C1606190CDA1C7E16FE4F5A02181630A20238166162023016C1F00181DA703F158395 380303F002601506A202E0ED0C076202C01518183001016D6C140F06605B028015C0A201 03923801801FDD03005B140092380FC00649173F4D91C8FC01065DA2010E4B5B4D137E13 0C6F6C5A011C17FEDCE1805B011802E3C7FCA2013802E6130104EC5C1330ED03F8017016 034C5C01F05CD807FC4C7EB500E0D9C007B512F01680150151397CB851>77 D<0103B612F849EDFF8018E0903B0007F8001FF84BEB03FCEF00FE020F157FA24BEC3F80 A2021F16C0A25DA2143FF07F805DA2027FEDFF006092C7485A4D5A4A4A5A4D5A4AEC1F80 057FC7FC0101EC07F891B612E094C8FC9139FC000FC00103EC03F0707E4A6D7E83130717 7E5C177F010F5D5F5CA2011F1401A25CA2133F16034A4A1360A2017F17E019C091C71401 496C01011480B61503933900FE0700EF7E0ECAEA1FFCEF07F03B3B7DB83F>82 D<0003B812FEA25A903AF8003FC00101C0913880007E4848163C90C7007F141C121E001C 92C7FCA2485CA200305C007017180060130112E0485CA21403C716005DA21407A25DA214 0FA25DA2141FA25DA2143FA25DA2147FA292C9FCA25CA25CA21301A25CA21303A25CEB0F FC003FB6FC5AA237397EB831>84 D<267FFFFC91383FFFC0B55DA2000390C83807FC006C 48ED03E06060000094C7FC5F17065FA25F6D5DA26D5D17E05F4C5AA24CC8FC6E1306A201 3F5C161C16185EA25E6E5BA2011F495A150393C9FC1506A25D6E5AA2010F5B157015605D A2ECE18002E3CAFC14F3EB07F614FE5C5CA25C5CA26D5AA25C91CBFC3A3B7CB830>86 D<49B500F890387FFFF095B5FC1AE0D90003018090380FFC004BC713E00201ED07804EC7 FC6E6C140E606F5C705B606F6C485A4D5A031F91C8FCEEE0065F6F6C5A5F03075B705A16 F96FB45A94C9FC6F5AA36F7EA34B7FED037F9238063FC0150E4B6C7E1538ED700F03E07F 15C04A486C7EEC0300020613034A805C4A6D7E14704A1300494880495A49C86C7E130E01 1E153F017E4B7ED803FF4B7E007F01E0011FEBFFC0B5FC6144397EB845>88 D<147E903803FF8090390FC1C38090391F00EFC0017E137F49133F485A4848EB1F801207 5B000F143F48481400A2485A5D007F147E90C7FCA215FE485C5AA214015D48150CA21403 EDF01C16181407007C1538007E010F1330003E131F027B13706C01E113E03A0F83C0F9C0 3A03FF007F80D800FCEB1F0026267DA42C>97 D<133FEA1FFFA3C67E137EA313FE5BA312 015BA312035BA31207EBE0FCEBE3FF9038E707C0390FFE03E09038F801F001F013F8EBE0 00485A15FC5BA2123F90C7FCA214015A127EA2140312FE4814F8A2140715F05AEC0FE0A2 15C0EC1F80143F00781400007C137E5C383C01F86C485A380F07C06CB4C7FCEA01FC1E3B 7CB924>II101 D103 D<14E0EB03F8A21307A314F0EB01C090C7FCAB13F8EA03FEEA070F000E1380121C121812 381230EA701F1260133F00E0130012C05BEA007EA213FE5B1201A25B12035BA200071318 13E01438000F133013C01470EB806014E014C01381EB838038078700EA03FEEA00F81539 7EB71D>105 D<150FED3F80A2157FA31600151C92C7FCABEC0F80EC3FE0ECF0F0903801 C0F849487E14005B130E130C131CEB1801133801305BA2EB0003A25DA21407A25DA2140F A25DA2141FA25DA2143FA292C7FCA25CA2147EA214FEA25CA21301001E5B123F387F83F0 A238FF87E0495A00FE5BD87C1FC8FCEA707EEA3FF8EA0FC0214981B722>I109 D<90390F8003F090391FE00FFC903939F03C1F903A70F8700F80903AE0FDE007C09038C0 FF80030013E00001491303018015F05CEA038113015CA2D800031407A25CA20107140FA2 4A14E0A2010F141F17C05CEE3F80131FEE7F004A137E16FE013F5C6E485A4B5A6E485A90 397F700F80DA383FC7FC90387E1FFCEC07E001FEC9FCA25BA21201A25BA21203A25B1207 B512C0A32C3583A42A>112 D<3903E001F83907F807FE390E3C1E07391C3E381F3A183F 703F800038EBE07F0030EBC0FF00705B00601500EC007E153CD8E07F90C7FCEAC07EA212 0013FE5BA312015BA312035BA312075BA3120F5BA3121F5B0007C9FC21267EA425>114 D<14FF010313C090380F80F090383E00380178131C153C4913FC0001130113E0A33903F0 00F06D13007F3801FFE014FC14FF6C14806D13C0011F13E013039038003FF01407140300 1E1301127FA24814E0A348EB03C012F800E0EB07800070EB0F006C133E001E13F83807FF E0000190C7FC1E267CA427>II<01F816F0D803FE9138E001F8D8070F903801F003000ED9800314FC121C12180038 020713010030EDE000D8701F167C1260030F143CD8E03F163800C001005B5BD8007E131F 183001FE5C5B033F1470000117604991C7FCA218E000034A14C049137E17011880170318 005F03FE1306170E000101015C01F801BF5B3B00FC039F8070903A7E0F0FC0E0903A1FFC 03FFC0902703F0007FC7FC36267EA43B>119 D122 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fk cmti10 10 7 /Fk 7 117 df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ndDVIPSBitmapFont %DVIPSBitmapFont: Fl cmbx9 9 41 /Fl 41 118 df<120FEA3FC0EA7FE0EAFFF0A6EA7FE0EA3FC0EA0F000C0C7A8B19>46 D48 D<147814F81303131FEA03FFB5FCA3EAFC1F1200B3B2007FB512FEA41F317A B02C>III<151F5D5DA25D5C5C5C5CA25C 143D147D14F9EB01F114E1EB03C1EB0781130FEB1F01133E133C137813F01201EA03E0EA 07C01380EA0F00121E123E5A5AB712FEA4C700031300A80103B512FEA427317EB02C>I< 000C140ED80FE013FE90B5FC5D5D5D5D5D92C7FC14FC14F091C8FC1380A6EB87FE9038BF FFC090B512F09038FC0FF89038E003FE01C07F497E01001480000E6D13C0C8FCA216E0A3 121FEA7F807F487EA316C05B5CD87F801480D87C0014006C5B393F8007FE391FE01FFC00 07B512F06C14C0C691C7FCEB1FF823327CB02C>II<123C123F90B612F8A44815F016E016C01680 16005D007CC7127E00785C4A5A00F8495A48495A4A5A4A5AC7FC4AC7FC147E14FE5C1301 5C1303A2495AA2130FA2131FA25C133FA4137FA96D5AA2010FC8FC25337BB12C>III65 DIIII72 DI76 DII<913803FF80027F13FC 49B6FC0107010113C0903A1FF8003FF0D93FE0EB0FF8D9FFC0EB07FE48496D7E4890C76C 13804980000717C04848ED7FE0A24848ED3FF0A2003F17F8A2007F17FC49151FA300FF17 FEAB007F17FCA26D153FA2003F17F8A36C6CED7FF0A26C6CEDFFE0000717C06D5C6C1780 6C6D4913006C6D495AD97FF0EB1FFCD91FF8EB3FF0903A07FF01FFC0010190B5C7FC6D6C 13FC020713C037357BB342>II82 DI<003FB812F8A4D9F003EB801FD87F80ED03FC01001501007E1600007C177CA200 78173CA400F8173E48171EA4C71600B3A9011FB612F0A437327DB13E>III89 D97 D<903807FF80013F13F090B512FC 3903FE01FE4848487EEA0FF8EA1FF0EA3FE0A2007F6D5A496C5A153000FF91C7FCA9127F 7FA2003FEC07807F6C6C130F000FEC1F00D807FE133E3903FF80FCC6EBFFF8013F13E001 0790C7FC21217DA027>99 DI<903803FF80013F13F090B512FC48EB03FE3907FC007F4848EB3F804848EB1FC0 5B003FEC0FE0127F5B16F012FF150790B6FCA301C0C8FCA4127F7F123F16F06C7E000F14 016C6CEB03E0D803FEEB0FC03A01FF807F806C6CB51200011F13FC010313E024217EA029 >I105 D108 D<3901F803FF00FF010F13C0023F13F09138FC0FF89039F9E007FC380FFBC06CB4486C7E 1400A25BA25BB2B539E07FFFF0A42C217DA031>110 D<903803FF80011F13F090B512FE 48EB01FF3A07FC007FC0D80FF0EB1FE0001F15F049130F003F15F8491307007F15FCA300 FF15FEA8007F15FCA26D130F003F15F8001F15F06D131F6C6CEB3FE06C6CEB7FC03A01FF 01FF006CEBFFFE013F13F80103138027217EA02C>I<3901F81F8000FFEB7FF0ECFFF890 38F9E3FC9038FBC7FE380FFF876C1307A213FEEC03FCEC01F8EC0060491300B1B512F0A4 1F217EA024>114 D<9038FFE1C0000713FF5A383F803F387E000F14075A14037EA26C6C C7FC13FCEBFFE06C13FC806CEBFF80000F14C06C14E0C6FC010F13F0EB007F140F00F013 0714037EA26C14E06C13076CEB0FC09038C01F8090B5120000F913FC38E03FE01C217DA0 23>I<133CA5137CA313FCA21201A212031207001FB51280B6FCA3D807FCC7FCB0EC03C0 A79038FE078012033901FF0F006C13FEEB3FFCEB0FF01A2F7EAE22>II E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fm cmr8 8 26 /Fm 26 122 df<123C127EB4FCA21380A2127F123D1201A312031300A25A1206120E5A5A 5A126009157A8714>44 D<123C127E12FFA4127E123C08087A8714>46 D48 D50 D56 D<123C127E12FFA4127E123C12 00AD123C127E12FFA4127E123C081D7A9C14>58 D<4A7E4A7EA34A7EA24A7EA3EC1BF814 19A2EC30FCA2EC70FEEC607EA24A7EA349486C7EA2010380EC000FA201066D7EA3496D7E A2011FB57EA29038180001496D7EA349147EA201E0147F4980A20001ED1F801203000716 C0D80FF0EC3FE0D8FFFC0103B5FCA2302F7EAE35>65 D67 D71 D75 D80 D<90383F80303901FFF0703807C07C390F000EF000 1E13074813034813011400127000F01470A315307EA26C1400127E127FEA3FE013FE381F FFE06C13FC6C13FF00011480D8003F13E013039038003FF0EC07F81401140015FC157C12 C0153CA37EA215787E6C14706C14F06CEB01E039F78003C039E3F00F0038E07FFE38C00F F01E2F7CAD27>83 D87 D98 D<15F8141FA214011400ACEB0FE0EB7FF83801F81E3803E0073807C003380F80 01EA1F00481300123E127EA25AA9127C127EA2003E13017EEB8003000F13073903E00EFC 3A01F03CFFC038007FF090391FC0F800222F7EAD27>100 DI107 D<2607C07FEB07F03BFFC3FFC03FFC903AC783 F0783F3C0FCE01F8E01F803B07DC00F9C00F01F8D9FF8013C04990387F000749137EA249 137CB2486C01FEEB0FE03CFFFE0FFFE0FFFEA2371E7E9D3C>109 D<3807C0FE39FFC3FF809038C703E0390FDE01F0EA07F8496C7EA25BA25BB2486C487E3A FFFE1FFFC0A2221E7E9D27>II<380781F838FF87FE EB8E3FEA0F9CEA07B813B0EBF01EEBE000A45BB0487EB5FCA2181E7E9D1C>114 D<3801FE183807FFB8381E01F8EA3C00481378481338A21418A27E7EB41300EA7FF06CB4 FC6C13C06C13F0000113F838001FFC130138C0007E143EA26C131EA27EA26C133CA26C13 7838FF01F038E3FFC000C0130017207E9E1C>I<1360A413E0A312011203A21207121FB5 12F0A23803E000AF1418A714383801F03014703800F860EB3FE0EB0F80152A7FA81B>I< D807C013F800FF131FA2000F130100071300B21401A314033803E007EC0EFC3A01F81CFF C038007FF890391FE0F800221F7E9D27>I<3BFFFC3FFE07FFA23B0FE003F001F801C090 38E000F00007010114E0812603E00314C0A2913807F8012701F006781380A29039F80E7C 030000D90C3C1300A290397C181E06A2151F6D486C5AA2168C90391F600798A216D89039 0FC003F0A36D486C5AA36DC75A301E7F9C33>119 D<3AFFFC01FFC0A23A0FE0007E0000 07147C1538000314306D137000011460A26C6C5BA2EBFC01017C5BEB7E03013E90C7FCA2 EB1F06A2148EEB0F8CA2EB07D8A2EB03F0A36D5AA26D5AA2495AA2130391C8FC1278EAFC 06A25B131CEA7838EA7070EA3FE0EA0F80222B7F9C25>121 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fn cmr9 9 76 /Fn 76 128 df<91393FE00FE0903A01FFF83FF8903A07E01EF83C903A1F800FF07E903A 3F001FE0FE017E133F4914C0485A1738484890381F8000ACB812C0A33B03F0001F8000B3 A7486C497EB50083B5FCA32F357FB42D>11 DI15 D25 D<017C1503D803FEED078026078780 140F260F01C0141F261E00E0EC3F00003E01F8147E003C017CEB01FE007C90397F8007FC 913933FFFEF800789038307FF900F89039380001F00218495A16075F4C5A161F4CC7FC16 3E5E023813FC007801305B007C4A5AEC7003003C01605B003E9038E007C0001EEBC00FD8 0F015C270787801FC8FC3903FE003FD8007C133E90C748131F03FCEBFF809239F801E1E0 913A01F003C07002039038078030DBE00F1338DA07C0EB0018020F49131C0380140C9138 1F001E4A013E130E023E15065C14FC495A5C495A13075C4948150E011F021E130C91C712 1F013E161C017E6E1318017CED803849020713300001923803C07049913801E1E0499138 00FF806C48ED1F00373C7CB740>37 D<14C01301EB0380EB0F00130E5B133C5B5BA2485A 485AA212075B120F90C7FC5AA2121E123EA3123C127CA55AB0127CA5123C123EA3121E12 1FA27E7F12077F1203A26C7E6C7EA213787F131C7F130FEB0380EB01C01300124A79B71E >40 D<12C07E1270123C121C7E120F6C7E6C7EA26C7E6C7EA27F1378137C133C133EA213 1E131FA37F1480A5EB07C0B0EB0F80A514005BA3131E133EA2133C137C137813F85BA248 5A485AA2485A48C7FC120E5A123C12705A5A124A7CB71E>I<123C127EB4FCA21380A212 7F123D1201A412031300A25A1206120E120C121C5A5A126009177A8715>44 DI<123C127E12FFA4127E123C08087A8715>I48 D<13075B5B137FEA07FFB5FC13BFEAF83F 1200B3B3A2497E007FB51280A319327AB126>IIII<000C14C0380FC00F90B5 128015005C5C14F014C0D80C18C7FC90C8FCA9EB0FC0EB7FF8EBF07C380FC03F9038001F 80EC0FC0120E000CEB07E0A2C713F01403A215F8A41218127E12FEA315F0140712F80060 14E01270EC0FC06C131F003C14806CEB7F00380F80FE3807FFF8000113E038003F801D34 7CB126>I<14FE903807FF80011F13E090383F00F0017C13703901F801F8EBF003EA03E0 1207EA0FC0EC01F04848C7FCA248C8FCA35A127EEB07F0EB1FFC38FE381F9038700F8090 38E007C039FFC003E0018013F0EC01F8130015FC1400A24814FEA5127EA4127F6C14FCA2 6C1301018013F8000F14F0EBC0030007EB07E03903E00FC03901F81F806CB51200EB3FFC EB0FE01F347DB126>I<1230123C003FB6FCA34814FEA215FC0070C71238006014301570 15E04814C01401EC0380C7EA07001406140E5C141814385CA25CA2495A1303A3495AA213 0FA3131F91C7FCA25BA55BA9131C20347CB126>III<123C127E12FFA4127E123C1200B012 3C127E12FFA4127E123C08207A9F15>I<123C127E12FFA4127E123C1200B0123C127E12 FE12FFA3127F123F1203A412071206A3120E120C121C1238123012701260082F7A9F15> I<007FB812C0B912E0A26C17C0CCFCAC007FB812C0B912E0A26C17C033147C9C3C>61 D<15E0A34A7EA24A7EA34A7EA3EC0DFE140CA2EC187FA34A6C7EA202707FEC601FA202E0 7FECC00FA2D901807F1507A249486C7EA301066D7EA2010E80010FB5FCA249800118C77E A24981163FA2496E7EA3496E7EA20001821607487ED81FF04A7ED8FFFE49B512E0A33336 7DB53A>65 DIIIIIIII<017FB5FCA3 9038003FE0EC1FC0B3B1127EB4FCA4EC3F805A0060140000705B6C13FE6C485A380F03F0 3803FFC0C690C7FC20357DB227>IIIIIII82 D<90381FE00390387FFC0748B5FC3907F01FCF390F8003FF 48C7FC003E80814880A200788000F880A46C80A27E92C7FC127F13C0EA3FF013FF6C13F0 6C13FF6C14C06C14F0C680013F7F01037F9038003FFF140302001380157F153FED1FC015 0F12C0A21507A37EA26CEC0F80A26C15006C5C6C143E6C147E01C05B39F1FC03F800E0B5 12E0011F138026C003FEC7FC22377CB42B>I<007FB712FEA390398007F001D87C00EC00 3E0078161E0070160EA20060160600E01607A3481603A6C71500B3AB4A7E011FB512FCA3 30337DB237>IIII<003FB612FCA39039F80007 F813C090C7EA0FF0003EEC1FE0123C0038EC3FC00078EC7F801270EDFF004A5AA2006049 5AA24A5A4A5AC7FC4A5A4A5AA24A5A4AC7FCA2495A495AA2495A495AA24948130C495AA2 495A49C7FCA24848141CA2485A485A1638485A4848147816F84848130148481307153FB7 FCA326337CB22F>90 DI93 D97 DII<153FEC0FFFA3EC007F81AEEB07F0EB3F FCEBFC0F3901F003BF3907E001FF48487E48487F8148C7FCA25A127E12FEAA127E127FA2 7E6C6C5BA26C6C5B6C6C4813803A03F007BFFC3900F81E3FEB3FFCD90FE0130026357DB3 2B>III<151F90391FC07F809039FFF8E3C03901F07FC739 07E03F033A0FC01F83809039800F8000001F80EB00074880A66C5CEB800F000F5CEBC01F 6C6C48C7FCEBF07C380EFFF8380C1FC0001CC9FCA3121EA2121F380FFFFEECFFC06C14F0 6C14FC4880381F0001003EEB007F4880ED1F8048140FA56C141F007C15006C143E6C5C39 0FC001F83903F007E0C6B51280D91FFCC7FC22337EA126>IIIIII<2703F01FE013FF00FF90267FF803 13C0903BF1E07C0F03E0903BF3803E1C01F02807F7003F387FD803FE1470496D486C7EA2 495CA2495CB3486C496C487EB53BC7FFFE3FFFF0A33C217EA041>I<3903F01FC000FFEB 7FF09038F1E0FC9038F3807C3907F7007EEA03FE497FA25BA25BB3486CEB7F80B538C7FF FCA326217EA02B>II<3903 F03F8000FFEBFFE09038F3C0F89038F7007ED807FE7F6C48EB1F804914C049130F16E0ED 07F0A3ED03F8A9150716F0A216E0150F16C06D131F6DEB3F80160001FF13FC9038F381F8 9038F1FFE0D9F07FC7FC91C8FCAA487EB512C0A325307EA02B>I<903807F00390383FFC 07EBFC0F3901F8038F3807E001000F14DF48486CB4FC497F123F90C77E5AA25A5AA9127F A36C6C5B121F6D5B000F5B3907E003BF3903F0073F3800F81EEB3FF8EB0FE090C7FCAAED 7F8091380FFFFCA326307DA029>I<3803E07C38FFE1FF9038E38F809038E71FC0EA07EE EA03ECA29038FC0F8049C7FCA35BB2487EB512E0A31A217FA01E>II<1330A51370A313F0A21201A212031207381FFFFE B5FCA23803F000AF1403A814073801F806A23800FC0EEB7E1CEB1FF8EB07E0182F7FAD1E >IIIII<3A7FFF807FF8A33A07F8001FC00003EC0F800001EC070015 066C6C5BA26D131C017E1318A26D5BA2EC8070011F1360ECC0E0010F5BA2903807E180A2 14F3010390C7FC14FBEB01FEA26D5AA31478A21430A25CA214E05CA2495A1278D8FC03C8 FCA21306130EEA701CEA7838EA1FF0EA0FC025307F9F29>I<003FB512F0A2EB000F003C 14E00038EB1FC00030EB3F800070137F1500006013FE495A13035CC6485A495AA2495A49 5A49C7FC153013FE485A12035B48481370485A001F14604913E0485A387F000348130F90 B5FCA21C207E9F22>II<001C1370387F01FC00FF13FEA4007F13 FC381C0070170879B226>127 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fo cmti9 9 48 /Fo 48 128 df44 DI48 DI51 D<150E151FA2153F153EA3157E157CA215FC15F8A2140115F0A2EC03E0A3EC07C0A2 EC0F80A2EC1F00A2143EA25C147814F85C1301903803E0E0ECC1F0EB0781EB0F83EC03E0 131E133CEB7C0701F813C0EA01F0EA03E03807C00FD80F801380EA1FFC383FFFCF48EBFF 82D8F00313FF3860003FC7EA1FF8EC3F00143EA3147E147CA314FC5CA4146020417DB127 >I<010614C090380FC00F91B51280160015FC4913F015C0D91CFEC7FC91C8FC133C1338 A313781370A313F0EBE0FE9038E3FF809038EF03C03901FC01E001F87FEBF000497F485A 5BC8FCA41401A4003C130300FC5CA34A5A5A00E0495AA24A5A4AC7FC6C137E00705B3878 01F8383E07F0381FFFC06C90C8FCEA03F8223478B127>IIIII<0107B612C04915F017FC903A003F8000FE177FEF3F8092C7121FA24A15C0A214 7EA214FE18804A143FA20101ED7F00177E4A5C16010103EC03F04C5A4AEB1FC091B6C7FC 495C9139F0007F804AEB0FC0707E010F6E7E834A1301A2011F81A25CA2133F5F91C71203 A2494A5AA2017E4A5A4C5A01FE4A5A4CC7FC49EB01FE0001EC07FC007FB612F0B712C04B C8FC32337BB236>66 D<0107B612C04915F017FC903A003F8001FEEE007FEF1F8092C7EA 0FC0EF07E05CEF03F0147E170102FE15F8A25CA21301A25CA2130317035CA2130718F04A 1407A2130F18E04A140F18C0011F151F18805CEF3F00133F177E91C85AA2494A5A4C5A01 7E4A5A4C5A01FE4A5A047EC7FC49495A0001EC0FF8007FB612E0B7C8FC15F835337BB23A >68 D<0107B712E05B18C0903A003F80003F170F170792C7FC17035C1880147EA214FEA2 5C161C0101EC3C07043813004A91C7FCA20103147816704A13F0150349B5FCA25EECE003 130F6F5A14C0A2011F13035E1480A2013F90C9FCA291CAFCA25BA2137EA213FEA25B1201 387FFFFCB5FCA233337CB232>70 D<92391FE001809238FFF8030207EBFE07913A1FF01F 0F0091393F80079F9139FE0003DFD901F86DB4FCD907F05C49481300495A4948147E49C8 127C137E13FE485A48481578A2485AA248481570A2485A94C7FC123F5BA3127F90CBFCA4 00FE91383FFFFCA25F9238003F8094C7FCA2007E5DA2167EA2007F15FE7E5E6C6C1301A2 6C6C495A6D13076C6CEB0F786C6C133E3A00FF01FC3090387FFFF0011F01C0C8FCD903FE C9FC313775B43B>I<0107B548B512C0495CA2903C003FC0000FF0004B5CA292C75BA24A 141F60147EA202FE143F95C7FC5CA201015D177E5CA2010315FE5F5C91B6FC5B5F9138E0 0001A2010F14035F5CA2011F14075F5CA2013F140F5F91C7FCA249141F5F137EA201FE14 3F94C8FC5B00015D3B7FFFF01FFFFCB55BA23A337BB239>I<010FB51280A21600903800 3FC05DA292C7FCA25CA2147EA214FEA25CA21301A25CA21303A25CA21307A25CA2130FA2 5CA2131FA25CA2133FA291C8FCA25BA2137EA213FEA25B1201B512F8A25C21337BB21E> I<902607FFC0ED7FFC4917FF81D9003F4B1300611803023BED077CA2027BED0EFC610273 151C1838DAF1F01439F071F014E118E10101ED01C36102C1EC0383EF070301031607050E 5BEC80F8171C0107ED380F6102001470A249EDE01FDC01C090C7FC130EEE0380011E017C 5C933807003E011C140EA2013C4A137E187C01385C5E017816FC6F485B1370ED3FC001F0 EC80016000011500D807F81503277FFF803E90B512C0B5EB3C01151C46337BB245>77 D<0107B612C04915F883903A003F8001FEEE003FEF1F8092C713C0170F5C18E0147EA214 FEEF1FC05CA201011680173F4A1500177E010315FE5F4AEB03F8EE07E00107EC3FC091B6 C7FC16F802E0C9FC130FA25CA2131FA25CA2133FA291CAFCA25BA2137EA213FEA25B1201 387FFFF0B5FCA233337CB234>80 D<913901FC018091380FFF03023F13C791387E07EF90 3A01F801FF0049487E4A7F495A4948133E131F91C7FC5B013E143CA3137E1638A293C7FC 137FA26D7E14E014FE90381FFFC06D13F86D7F01017F6D6C7E020F7F1400153F6F7E150F A4120EA2001E5D121CA2151F003C92C7FCA2003E143E5D127E007F5C6D485A9038C007E0 39F3F80FC000F0B5C8FC38E03FFC38C00FF029377AB42B>83 D<0003B812C05A1880903A F800FC003F260FC001141F0180150F01005B001EEE07001403121C003C4A5BA200380107 140E127800705CA2020F141E00F0161CC74990C7FCA2141FA25DA2143FA292C9FCA25CA2 147EA214FEA25CA21301A25CA21303A25CA21307A25C497E001FB512F05AA2323374B237 >I<3B3FFFF801FFFE485CA2D801FEC7EA1FC049EC0F80170049140EA2161E120349141C A2163C1207491438A21678120F491470A216F0121F495CA21501123F90C75BA215035A00 7E5DA2150712FE4892C7FCA25D150E48141E151C153C153815786C5C5D007C1301007E49 5A003EEB0F806C011EC8FC380FC0FC6CB45A000113E06C6CC9FC2F3570B239>I87 D97 D<137EEA0FFE121F5B1200A35BA21201A25BA21203A25BA2 1207A2EBC3E0EBCFF8380FDC3EEBF81F497E01E01380EA1FC0138015C013005AA2123EA2 007E131F1580127CA2143F00FC14005AA2147EA25CA2387801F85C495A6C485A495A6C48 C7FCEA0FFCEA03F01A3578B323>I<14FCEB07FF90381F078090383E03C0EBFC013801F8 033803F0073807E00F13C0120F391F80070091C7FC48C8FCA35A127EA312FE5AA4007C14 C0EC01E0A2EC03C06CEB0F80EC1F006C137C380F81F03803FFC0C648C7FC1B2278A023> III<151FED7FC0EDF0E00201 13F0EC03E3A2EC07C316E0EDC1C091380FC0005DA4141F92C7FCA45C143E90381FFFFEA3 D9007EC7FC147CA414FC5CA513015CA413035CA413075CA3130FA25CA3131F91C8FCA35B 133E1238EA7E3CA2EAFE7812FC485AEA78E0EA3FC0000FC9FC244582B418>I<143FECFF 80903803E1E6903807C0FF90380F807FEB1F00133E017E133F49133EA24848137EA24848 137CA215FC12074913F8A21401A2D80FC013F0A21403120715E01407140F141F3903E03F C00001137FEBF0FF38007FCF90381F0F801300141FA21500A25C143E1238007E137E5C00 FE5B48485A387803E0387C0F80D81FFFC7FCEA07F820317CA023>III107 D<133FEA07FF5A13FEEA007EA3137CA213FCA213F8A21201A213F0A21203 A213E0A21207A213C0A2120FA21380A2121FA21300A25AA2123EA2127EA2127C1318EAFC 1C133CEAF838A21378137012F013F0EAF8E01279EA3FC0EA0F00103579B314>I<2703C0 03F8137F3C0FF00FFE01FFC03C1E783C1F07C1E03C1C7CF00F8F01F03B3C3DE0079E0026 383FC001FC7FD97F805B007001005B5E137ED8F0FC90380FC00100E05FD860F814801200 0001021F130360491400A200034A13076049013E130FF081800007027EEC83C0051F1380 49017C1403A2000F02FC1407053E130049495CEF1E0E001F01015D183C010049EB0FF000 0E6D48EB03E03A227AA03F>I<3903C007F0390FF01FFC391E787C1E391C7CF01F393C3D E00F26383FC01380EB7F8000781300EA707EA2D8F0FC131F00E01500EA60F8120000015C 153E5BA20003147E157C4913FCEDF8180007153C0201133801C013F0A2000F1578EDE070 018014F016E0001FECE1C015E390C7EAFF00000E143E26227AA02B>I<14FCEB07FF9038 1F07C090383E03E09038FC01F0EA01F83903F000F8485A5B120F484813FCA248C7FCA214 014814F8127EA2140300FE14F05AA2EC07E0A2007CEB0FC01580141FEC3F006C137E5C38 1F01F0380F83E03803FF80D800FCC7FC1E2278A027>I<011E137C90387F81FF9039F3C3 87C09039E3EF03E03901E1FE01D9C1FC13F0EBC3F8000313F0018314F814E0EA07871307 000313C01200010F130316F01480A2011F130716E01400A249EB0FC0A2013EEB1F80A201 7EEB3F00017F133E5D5D9038FF81F09038FDC3E09038F8FF80027EC7FC000190C8FCA25B A21203A25BA21207A25BB5FCA325307FA027>I<3903C00FC0390FF03FF0391E78F07839 1C7DE03C393C3FC0FC00381380EB7F00007814F8D8707E13701500EAF0FC12E0EA60F812 001201A25BA21203A25BA21207A25BA2120FA25BA2121FA290C8FC120E1E227AA020> 114 DI<1303EB0F80A3131F A21400A25BA2133EA2137EA2137C387FFFF8A2B5FC3800F800A21201A25BA21203A25BA2 1207A25BA2120FA25B1460001F13F014E01300130114C01303001E1380EB07005BEA0F1E EA07F8EA01E015307AAE19>II<01F01338D803FC13FCEA0F1E12 0E121C123C0038147CEA783E0070143CA2137ED8F07C1338EA60FCC65A1578000114705B A215F0000314E05BA2EC01C0A2EBC003158014071500EBE00EA26C6C5A3800F878EB7FE0 EB1F801E227AA023>II<13F0D803FC1307D80F1E130F000E141F121C123C0038143FD8783E133E1270A201 7E137ED8F07C137CEA60FCC65A15FC000114F85BA21401000314F013E0A2140315E0EA07 C0A20003130715C0EBE00F141F0001133F9038F07F8038007FEFEB1F8FEB001F1500A25C 003E133E007E137E147C5C007C5BEA7001495A38380780D83C1FC7FCEA0FFCEA07F02031 7AA025>121 D<903807801C90381FE03C90383FF038017F13789038FFF8F03901F07CE0 EBE01F3903C003C09038800780EC0F00C7121E141C143C5C5C495AEB07C0495A011EC7FC 5B5B4913704913F0000114E0485A38078001390FC003C0381FF80790383E0F80393C1FFF 00127838700FFE38F007F838E001E01E227CA01F>II<001E13F0 387F01F81303EAFF07A338FE03F0383801C015086CB227>127 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fp cmr6 6 5 /Fp 5 80 df<13FF000313C0380781E0380F00F0001E137848133CA248131EA400F8131F AD0078131EA2007C133E003C133CA26C13786C13F0380781E03803FFC0C6130018227DA0 1E>48 D<13E01201120712FF12F91201B3A7487EB512C0A212217AA01E>II<49B41320010FEBC06090393F80F0E09038FC0019D801F0 130D48481307484813034848130148C7FC481400123E127E1660127C12FC1600A7007C15 60127EA2123E003F15C07E6C6CEB01806C7E6C6CEB03006C6C1306D800FC131C90383F80 7890380FFFE0010190C7FC23247CA22B>67 D<49B4FC010F13E090383F01F89038F8003E 48487FD803C0EB0780000715C04848EB03E048C7EA01F04815F8003E1400007E15FCA200 7C157C00FC157EA8007E15FCA3003E15F8003F14016C15F06C6CEB03E06D13076C6CEB0F C0D801F0EB1F00D800FC137E90383F01F890380FFFE0010190C7FC27247CA22F>79 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fq cmr7 7 12 /Fq 12 112 df1 D<1306130C13181330136013E0EA01C0EA0380A2EA 07005A120E121EA2121C123CA35AA512F85AAB7E1278A57EA3121C121EA2120E120F7EEA 0380A2EA01C0EA00E0136013301318130C13060F3B7AAB1A>40 D<12C012607E7E7E120E 7EEA0380A2EA01C013E0120013F0A213701378A3133CA5133E131EAB133E133CA51378A3 137013F0A213E0120113C0EA0380A2EA0700120E120C5A5A5A5A0F3B7DAB1A>I<140EB3 A2B812E0A3C7000EC8FCB3A22B2B7DA333>43 D<13381378EA01F8121F12FE12E01200B3 AB487EB512F8A215267BA521>49 D<13FF000313E0380E03F0381800F848137C48137E00 787F12FC6CEB1F80A4127CC7FC15005C143E147E147C5C495A495A5C495A010EC7FC5B5B 903870018013E0EA0180390300030012065A001FB5FC5A485BB5FCA219267DA521>I54 D<91387FC002903903FFF80690390FE01E0E90383F0007017CEB019ED801F0EB00FE4848 147E4848143E5B000F151E48C8FC48150E123EA2007E1506A2127C00FC1500A8127C007E 1506A2123EA2003F150C7E6C7E000715186D14386C6C14306C6C1460D8007CEB01C0013F EB038090390FE01E00903803FFF89038007FC0272A7DA82F>67 D78 DI<13FE3807FFC0380F03E0381C00F0003E1378003F137C 143C143E121EC7FCA3EB3FFEEA01FF3807F03EEA1FC0EA3F00127EA2481418A3147E127E ECDF38393F838FF0390FFE0FE03903F807C01D1C7E9A21>97 D111 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fr cmr10 10 81 /Fr 81 128 df<1506150FA24B7EA24B7EA24B7EA2EDDFF0A29138018FF8A291380307FC A291380603FEA291380E01FF140CDA1C007F141802386D7E143002706D7E146002E06D7E 5C01016E7E5C01036E7E91C7FC496E7E1306010E6E7E130C011C6E7F131801386F7E1330 01706F7E136001E06F7E5B170F484882170748C97F17030006831701488383481880001F B9FC4818C0A24818E0A2BA12F0A23C3C7CBB45>1 D<011FB512FEA39026001FFEC8FCEC 07F8A8EC3FFE0103B512E0D91FF713FC90397F07F87F01FCEC1F80D803F8EC0FE0D807F0 6E7ED80FE06E7E001F82D83FC06E7EA2007F8201808000FF1780A7007F170001C05C003F 5EA2D81FE04A5A000F5ED807F04A5AD803F84A5AD800FCEC1F80017F027FC7FC90391FF7 FFFC0103B512E09026003FFEC8FCEC07F8A8EC1FFE011FB512FEA331397BB83C>8 D11 DIII<14FF 010713C090381F83F090383F00FC017E137E49137F4848EB3F80A24848131F16C0A7ED3F 80A2ED7F00157E5D4A5AEC07E000FFEB7F80A2EC07E00003EB01F0EC00FC157E81168015 1FED0FC0A216E0150716F0A3ED03F8AA16F0ECF007EBF1F816E0ED0FC0A200079038F01F 803AFFF0E03F00EC707CEC3FF0C7EA0FC0253C7EBA2A>25 D<001C131C007F137F39FF80 FF80A26D13C0A3007F137F001C131C00001300A40001130101801380A200031303010013 00485B00061306000E130E485B485B485B006013601A197DB92A>34 D<017C166048B416F02607C3801401260F81C01403D900E04A5A001E01784A5A003E6D14 1F003C013FEC7F80007C90271BE003FFC7FC0218B512BF007891381FFC3E00F8011CC75A 020C14FC5F4C5A16035F4C5A160F5F4CC8FC021C5B00780118133E007C5D16FC003C0138 5B003E90383001F0001EEB70036C01E05B903981C007C03907C3800F2601FF005BD8007C 49C9FC90C748EB07C0033EEB1FF04BEB3C3803FCEBF81C4B497E913A01F001E006020301 03130703E0497E912607C0071480020F15011580DA1F00018013C04A010F1300143E5C14 FC5C495A13035C495A130F4A0107130149C701C013805B013E1603490203140001FC6F5A 49020113064848913800F00E0003705A49ED3C3849ED1FF06C48ED07C03A437BBD45>37 D<121C127FEAFF80A213C0A3127F121C1200A412011380A2120313005A1206120E5A5A5A 12600A1979B917>39 D<146014E0EB01C0EB0380EB0700130E131E5B5BA25B485AA2485A A212075B120F90C7FCA25A121EA2123EA35AA65AB2127CA67EA3121EA2121F7EA27F1207 7F1203A26C7EA26C7E1378A27F7F130E7FEB0380EB01C0EB00E01460135278BD20>I<12 C07E12707E7E7E120F6C7E6C7EA26C7E6C7EA21378A2137C133C133E131EA2131F7FA214 80A3EB07C0A6EB03E0B2EB07C0A6EB0F80A31400A25B131EA2133E133C137C1378A25BA2 485A485AA2485A48C7FC120E5A5A5A5A5A13527CBD20>I<15301578B3A6007FB812F8B9 12FCA26C17F8C80078C8FCB3A6153036367BAF41>43 D<121C127FEAFF80A213C0A3127F 121C1200A412011380A2120313005A1206120E5A5A5A12600A19798817>II<121C127FEAFF80A5EA7F00121C0909798817>I48 DIII<1538A2157815F8A2140114031407A2140F 141F141B14331473146314C313011483EB030313071306130C131C131813301370136013 C01201EA038013005A120E120C5A123812305A12E0B712F8A3C73803F800AB4A7E0103B5 12F8A325397EB82A>I<0006140CD80780133C9038F003F890B5FC5D5D158092C7FC14FC 38067FE090C9FCABEB07F8EB3FFE9038780F803907E007E090388003F0496C7E12066E7E C87EA28181A21680A4123E127F487EA490C71300485C12E000605C12700030495A00385C 6C1303001E495A6C6C485A3907E03F800001B5C7FC38007FFCEB1FE0213A7CB72A>II<12301238123E003FB612E0A316C05A168016000070C7 12060060140E5D151800E01438485C5D5DC712014A5A92C7FC5C140E140C141C5CA25CA2 14F0495AA21303A25C1307A2130FA3495AA3133FA5137FA96DC8FC131E233B7BB82A>I< EB03F8EB1FFF017F13C09038FC07F03901E001F848486C7E4848137C90C77E48141E000E 141F001E80A3121FA27F5D01E0131E6C6C133E01FC133C6D5B6C6C6C5AECC1E06CEBF3C0 6C01FFC7FC6C5BEB3FFF6D13C081017F13F801F07F3903E07FFE3907801FFF48486C1380 481303003E6D13C0003CEB007F007C143F0078EC0FE000F814075A1503A21501A36C15C0 12781503007C15806CEC07006C5C6C6C131ED807E0137C3903F803F0C6B55A013F1380D9 07FCC7FC233A7DB72A>II<121C127FEAFF80A5EA7F00121C C7FCB2121C127FEAFF80A5EA7F00121C092479A317>I<121C127FEAFF80A5EA7F00121C C7FCB2121C127F5A1380A4127F121D1201A412031300A25A1206A2120E5A121812385A12 60093479A317>I<007FB812F8B912FCA26C17F8CCFCAE007FB812F8B912FCA26C17F836 167B9F41>61 D<1538A3157CA315FEA34A7EA34A6C7EA202077FEC063FA2020E7FEC0C1F A2021C7FEC180FA202387FEC3007A202707FEC6003A202C07F1501A2D901807F81A249C7 7F167FA20106810107B6FCA24981010CC7121FA2496E7EA3496E7EA3496E7EA213E0707E 1201486C81D80FFC02071380B56C90B512FEA3373C7DBB3E>65 DI< 913A01FF800180020FEBE003027F13F8903A01FF807E07903A03FC000F0FD90FF0EB039F 4948EB01DFD93F80EB00FF49C8127F01FE153F12014848151F4848150FA248481507A248 5A1703123F5B007F1601A35B00FF93C7FCAD127F6DED0180A3123F7F001F160318006C7E 5F6C7E17066C6C150E6C6C5D00001618017F15386D6C5CD91FE05C6D6CEB03C0D903FCEB 0F80902701FF803FC7FC9039007FFFFC020F13F002011380313D7BBA3C>IIIIIII75 D77 DIII82 DI<003FB812E0A3D9C003EB001F273E0001FE130348EE 01F00078160000701770A300601730A400E01738481718A4C71600B3B0913807FF80011F B612E0A335397DB83C>IIII91 D<3901800180000313033907000700000E130E485B00181318003813380030 13300070137000601360A200E013E0485BA400CE13CE39FF80FF806D13C0A3007F137FA2 393F803F80390E000E001A1974B92A>II<121E123FEA7F80A2EAFFC0EA7F80A2EA3F00121E0A097AB717>95 D97 DIIII<147E903803FF8090380FC1E0EB1F8790 383F0FF0137EA213FCA23901F803C091C7FCADB512FCA3D801F8C7FCB3AB487E387FFFF8 A31C3B7FBA19>IIII< EB01C0EB07F0EB0FF8A5EB07F0EB01C090C7FCAAEB01F813FFA313071301B3B3A2123C12 7E00FF13F01303A214E038FE07C0127C383C0F00EA0FFEEA03F8154984B719>III<2703F00FF0EB1FE000FFD93FFCEB7FF8913AF03F01E0 7E903BF1C01F83803F3D0FF3800FC7001F802603F70013CE01FE14DC49D907F8EB0FC0A2 495CA3495CB3A3486C496CEB1FE0B500C1B50083B5FCA340257EA445>I<3903F00FF000 FFEB3FFCECF03F9039F1C01F803A0FF3800FC03803F70013FE496D7EA25BA35BB3A3486C 497EB500C1B51280A329257EA42E>II<3903F01FE000FFEB7FF89038 F1E07E9039F3801F803A0FF7000FC0D803FEEB07E049EB03F04914F849130116FC150016 FEA3167FAA16FEA3ED01FCA26DEB03F816F06D13076DEB0FE001F614C09039F7803F0090 38F1E07E9038F0FFF8EC1FC091C8FCAB487EB512C0A328357EA42E>II<3807E01F00 FFEB7FC09038E1E3E09038E387F0380FE707EA03E613EE9038EC03E09038FC0080491300 A45BB3A2487EB512F0A31C257EA421>II<1318A51338A31378A313F8120112031207001FB5FCB6FC A2D801F8C7FCB215C0A93800FC011580EB7C03017E13006D5AEB0FFEEB01F81A347FB220 >IIIIII<003FB512FCA2EB8003D83E0013F8003CEB07F00038EB0FE012300070EB1FC0 EC3F800060137F150014FE495AA2C6485A495AA2495A495A495AA290387F000613FEA248 5A485A0007140E5B4848130C4848131CA24848133C48C7127C48EB03FC90B5FCA21F247E A325>II<001C131C007F137F39FF80FF80A5397F007F00001C13 1C190978B72A>127 D E %EndDVIPSBitmapFont %DVIPSBitmapFont: Fs cmbx12 12 22 /Fs 22 118 df40 D<12F07E127E7E6C7E6C7E6C7E7F6C7E6C7E12007F137F80133F806D7EA26D7EA26D7EA2 801303A2801301A280A27F1580A4EC7FC0A615E0A2143FAE147FA215C0A6ECFF80A41500 5BA25CA213035CA213075CA2495AA2495AA2495A5C137F91C7FC13FE5B1201485A485A5B 485A485A48C8FC127E12F85A1B647ACA2C>I48 DI78 D<923807FFC092B512FE0207ECFFC0021F 15F091267FFE0013FC902601FFF0EB1FFF01070180010313C04990C76C7FD91FFC6E6C7E 49486F7E49486F7E01FF8348496F7E48496F1380A248496F13C0A24890C96C13E0A24819 F04982003F19F8A3007F19FC49177FA400FF19FEAD007F19FC6D17FFA3003F19F8A26D5E 6C19F0A26E5D6C19E0A26C6D4B13C06C19806E5D6C6D4B13006C6D4B5A6D6C4B5A6D6C4B 5A6D6C4A5B6D01C001075B6D01F0011F5B010101FE90B5C7FC6D90B65A023F15F8020715 C002004AC8FC030713C047467AC454>I83 D<903801FFE0011F13FE017F6D7E48B612E03A03FE007FF84848EB1FFC6D6D7E 486C6D7EA26F7FA36F7F6C5A6C5AEA00F090C7FCA40203B5FC91B6FC1307013F13F19038 FFFC01000313E0000F1380381FFE00485A5B127F5B12FF5BA35DA26D5B6C6C5B4B13F0D8 3FFE013EEBFFC03A1FFF80FC7F0007EBFFF86CECE01FC66CEB8007D90FFCC9FC322F7DAD 36>97 D99 DIII<137C48B4FC4813804813C0A24813E0A56C13C0A2 6C13806C1300EA007C90C7FCAAEB7FC0EA7FFFA512037EB3AFB6FCA518467CC520>105 D108 D<90277F8007FEEC0FFC B590263FFFC090387FFF8092B5D8F001B512E002816E4880913D87F01FFC0FE03FF8913D 8FC00FFE1F801FFC0003D99F009026FF3E007F6C019E6D013C130F02BC5D02F86D496D7E A24A5D4A5DA34A5DB3A7B60081B60003B512FEA5572D7CAC5E>I<90397F8007FEB59038 3FFF8092B512E0028114F8913987F03FFC91388F801F000390399F000FFE6C139E14BC02 F86D7E5CA25CA35CB3A7B60083B512FEA5372D7CAC3E>II<90397FC00FF8B590B57E02C314E002CF14F89139DFC03F FC9139FF001FFE000301FCEB07FF6C496D13804A15C04A6D13E05C7013F0A2EF7FF8A4EF 3FFCACEF7FF8A318F017FFA24C13E06E15C06E5B6E4913806E4913006E495A9139DFC07F FC02CFB512F002C314C002C091C7FCED1FF092C9FCADB67EA536407DAC3E>I<90387F80 7FB53881FFE0028313F0028F13F8ED8FFC91389F1FFE000313BE6C13BC14F8A214F0ED0F FC9138E007F8ED01E092C7FCA35CB3A5B612E0A5272D7DAC2E>114 D<90391FFC038090B51287000314FF120F381FF003383FC00049133F48C7121F127E00FE 140FA215077EA27F01E090C7FC13FE387FFFF014FF6C14C015F06C14FC6C800003806C15 806C7E010F14C0EB003F020313E0140000F0143FA26C141F150FA27EA26C15C06C141FA2 6DEB3F8001E0EB7F009038F803FE90B55A00FC5CD8F03F13E026E007FEC7FC232F7CAD2C >III E %EndDVIPSBitmapFont end %%EndProlog %%BeginSetup %%Feature: *Resolution 600dpi TeXDict begin %%BeginPaperSize: a4 a4 %%EndPaperSize %%EndSetup %%Page: 1 1 1 0 bop 474 -83 a Fs(Sim)m(ulation)35 b(of)j(laser)f(induced)g (desorption)g(of)h(NO)f(from)g(NiO\(100\))1343 116 y Fr(C.)44 b(Bac)n(h)1652 86 y Fq(1)1688 116 y Fr(,)k(T.)c(Kl)r(\177)-44 b(uner)2136 86 y Fq(2)2173 116 y Fr(,)48 b(A.)c(Gro\031)2555 86 y Fq(1)485 172 y Fp(1)520 203 y Fo(Physik-Dep)l(artment)37 b(T30,)d(T)-6 b(e)l(chnische)35 b(Universit\177)-39 b(at)35 b(M)q(\177)-40 b(unchen,)35 b(85747)g(Gar)l(ching,)g(Germany)885 259 y Fp(2)919 291 y Fo(F)-6 b(ritz-Hab)l(er-Institut,)43 b(F)-6 b(ar)l(adaywe)l(g)40 b(4{6,)f(14195)f(Berlin,)h(Germany)1570 378 y Fn(\(Dated:)34 b(April)25 b(30,)i(2003\))383 519 y(W)-6 b(e)28 b(ha)n(v)n(e)e(implemen)n(ted)g(a)i(mixed)e(quan)n (tum-classical)h(sc)n(heme)g(for)h(the)f(sim)n(ulation)h(of)g(the)f (laser-induced)307 606 y(desorption)e(from)g(surfaces.)35 b(This)26 b(metho)r(d)d(allo)n(ws)k(a)e(m)n(ultidimensional)g(sim)n (ulation)f(of)i(the)f(desorption)g(pro-)307 693 y(cess)c(on)f (realistic)i(time)d(scales.)35 b(Using)20 b Fo(ab)j(initio)h Fn(deriv)n(ed)c(p)r(oten)n(tial)g(energy)g(surfaces,)j(w)n(e)e(compare) f(the)g(mixed)307 780 y(quan)n(tum-classical)29 b(sc)n(heme)h(to)g (jumping)f(w)n(a)n(v)n(e-pac)n(k)n(et)g(calculations)j(for)f(the)e (laser-induced)h(desorption)h(of)307 868 y(NO)c(from)g(NiO\(100\).)42 b(Our)27 b(results)i(demonstrate)e(the)g(signi\014can)n(t)i(role)f(of)h (the)e(m)n(ultidimensionalit)n(y)g(in)h(the)307 955 y(desorption)e(pro) r(cess,)h(in)e(particular)i(the)e(imp)r(ortance)g(of)i(surface)g (recoil)g(pro)r(cesses.)307 1121 y Fm(P)-6 b(A)n(CS)23 b(n)n(um)n(b)r(ers:)30 b(82.20.Gk,)25 b(82.20.Wt)307 1200 y(Keyw)n(ords:)436 1457 y Fl(I.)88 b(INTR)n(ODUCTION)-67 1679 y Fr(In)44 b(recen)n(t)f(y)n(ears)e(photo)r(c)n(hemical)i (reactions)f(on)i(surfaces)-150 1774 y(ha)n(v)n(e)33 b(receiv)n(ed)h(a)g(great)g(deal)g(of)g(atten)n(tion,)j(esp)r(ecially)d (from)-150 1870 y(an)d(exp)r(erimen)n(tal)g(p)r(oin)n(t)g(of)h(view)f ([1)o(].)49 b(New)31 b(tec)n(hnologies)f(al-)-150 1965 y(lo)n(w)n(ed)g(to)h(p)r(erform)g(state)f(resolv)n(ed)g(exp)r(erimen)n (ts)h(whic)n(h)g(pro-)-150 2061 y(vided)d(a)e(unpreceden)n(ted)i(amoun) n(t)f(of)g(information)g(ab)r(out)g(the)-150 2156 y(pro)r(cesses)34 b(in)n(v)n(olv)n(ed.)60 b(The)36 b(theoretical)f(description)g(of)h (suc)n(h)-150 2252 y(reactions)h(is)i(still)f(far)g(b)r(ehind.)71 b(P)n(art)37 b(of)h(the)h(di\016culties)g(in)-150 2347 y(mo)r(deling)29 b(of)g(suc)n(h)g(pro)r(cesses)f(result)h(from)g(the)g (fact)h(that)f(the)-150 2443 y(Born-Opp)r(enheimer)18 b(appro)n(ximation)f(is)i(explictly)g(violated)f(so)-150 2538 y(that)k(the)f(dynamics)g(of)h(b)r(oth)g(electrons)e(and)h(n)n (uclei)h(ha)n(v)n(e)e(to)h(b)r(e)-150 2634 y(tak)n(en)33 b(in)n(to)g(accoun)n(t.)52 b(Therefore,)34 b(most)f(dynamical)f(sim)n (ula-)-150 2729 y(tions)20 b(of)g(photo-induced)g(reactions)f(at)h (surfaces)f(are)h(limited)h(to)-150 2825 y(lo)n(w-dimensional)29 b(treatmen)n(ts)i(with)h(only)e(a)h(limited)h(n)n(um)n(b)r(er)-150 2920 y(of)c(molecular)e(degrees)g(of)i(freedom)f(tak)n(en)g(in)n(to)g (accoun)n(t)g([2].)-67 3023 y(Ho)n(w)n(ev)n(er,)40 b(dynamical)e(sim)n (ulations)h(of)g(pro)r(cesses)e(at)i(sur-)-150 3119 y(faces)j(ha)n(v)n (e)f(demonstrated)h(the)g(imp)r(ortance)g(of)g(a)g(realistic)-150 3214 y(m)n(ultidimensional)c(treatmen)n(t)h([3)o({6)o(].)70 b(F)-7 b(urthermore,)40 b(quan-)-150 3310 y(tum)45 b(e\013ects)g(in)g (the)f(motion)h(of)f(atoms)g(can)g(often)h(b)r(e)g(ne-)-150 3405 y(glected,)36 b(in)f(particular)e(for)h(atoms)g(hea)n(vier)f(than) i(h)n(ydrogen,)-150 3501 y(but)25 b(sometimes)g(ev)n(en)f(in)h(the)g(h) n(ydrogen)e(dynamics)h([7,)h(8].)36 b(W)-7 b(e)-150 3596 y(ha)n(v)n(e)20 b(recen)n(tly)g(implemen)n(ted,)k(as)c(a)h(mixed)g (quan)n(tum-classical)-150 3691 y(sc)n(heme,)j(the)g(few)n(est)g(switc) n(hes)g(algorithm)e([9])i(for)f(the)h(descrip-)-150 3787 y(tion)43 b(of)f(reactions)f(at)h(surfaces)g([10)o(,)k(11)o(].)82 b(In)43 b(this)f(elegan)n(t)-150 3882 y(surface-hopping)29 b(metho)r(d,)j(the)f(motion)g(of)f(the)h(n)n(uclei)g(is)g(de-)-150 3978 y(scrib)r(ed)d(classically)f(while)h(the)h(dynamics)e(of)i(the)f (electrons)g(is)-150 4073 y(treated)39 b(quan)n(tum)h(mec)n(hanically) -7 b(.)72 b(The)39 b(feedbac)n(k)g(b)r(et)n(w)n(een)-150 4169 y(quan)n(tum)c(and)g(classical)e(degrees)h(of)h(freedom)f(is)h (tak)n(en)g(in)n(to)-150 4264 y(accoun)n(t)i(self-consisten)n(tly)g(b)n (y)g(state)g(switc)n(hes)h(whose)f(n)n(um-)-150 4360 y(b)r(er)24 b(is)h(minimized)g(under)f(the)h(constrain)n(t)e(of)h(main) n(taining)g(the)-150 4455 y(correct)i(statistical)h(p)r(opulation)h(of) f(eac)n(h)g(state.)-67 4558 y(W)-7 b(e)31 b(ha)n(v)n(e)f(no)n(w)g (extended)h(this)g(algorithm)e(in)i(order)e(to)i(ad-)-150 4654 y(dress)41 b(photo-induced)g(reactions)f(at)h(surfaces.)78 b(Com)n(bining)-150 4749 y(ideas)31 b(of)g(previous)f(treatmen)n(ts)h ([9,)h(12)o({14)o(],)h(w)n(e)e(ha)n(v)n(e)f(in)i(par-)-150 4845 y(ticular)d(in)n(tro)r(duced)g(an)g(optical)g(p)r(oten)n(tial)g (in)h(order)e(to)h(sim)n(u-)-150 4940 y(late)34 b(the)g(electronic)f (system)g(of)h(the)g(substrate.)54 b(Due)34 b(to)g(the)-150 5036 y(computational)29 b(e\016ciency)g(of)h(the)g(mixed)f(quan)n (tum-classical)-150 5131 y(metho)r(d,)j(w)n(e)e(are)f(able)h(to)h(p)r (erform)f(m)n(ultidimensional)g(sim)n(u-)-150 5227 y(lations)f(of)g (the)h(laser-induced)e(desorption)h(on)g(realistic)f(time-)-150 5322 y(scales.)-67 5425 y(As)41 b(a)f(\014rst)g(example,)k(w)n(e)c(ha)n (v)n(e)f(applied)i(our)e(metho)r(d)j(to)2042 1457 y(the)47 b(laser-induced)f(desorption)g(of)h(NO)g(from)g(a)f(NiO\(100\))2042 1553 y(surface)52 b([15)o(,)60 b(16)o(].)114 b(In)53 b(order)f(to)h(establish)g(the)g(v)-5 b(alidit)n(y)2042 1648 y(of)39 b(our)g(mixed)h(quan)n(tum-classical)e(sc)n(heme,)k(w)n(e) d(ha)n(v)n(e)g(com-)2042 1744 y(pared)32 b(mixed)g(quan)n (tum-classical)f(t)n(w)n(o-dimensional)g(sim)n(ula-)2042 1839 y(tions)37 b(with)i(corresp)r(onding)c(jumping)k(w)n(a)n(v)n (e-pac)n(k)n(et)34 b(calcula-)2042 1935 y(tions)g([17)o(])h(on)g(the)g (same)f(p)r(oten)n(tial)h(energy)e(surface)h(deriv)n(ed)2042 2030 y(from)41 b(quan)n(tum)h(c)n(hemical)g(calculations.)79 b(Using)41 b(the)i(same)2042 2126 y(propagation)32 b(times,)k(w)n(e)e (obtain)g(go)r(o)r(d)g(agreemen)n(t)f(with)i(the)2042 2221 y(w)n(a)n(v)n(e-pac)n(k)n(et)27 b(calculations)j([17)o(].)46 b(Ho)n(w)n(ev)n(er,)30 b(our)g(sim)n(ulations)2042 2317 y(sho)n(w)25 b(that)i(it)f(is)g(imp)r(ortan)n(t)g(to)g(p)r(erform)g (the)h(dynamical)e(sim-)2042 2412 y(ulations)37 b(for)h(su\016cien)n (tly)g(long)f(run)g(times.)69 b(W)-7 b(e)38 b(ha)n(v)n(e)f(then)2042 2508 y(extended)d(the)g Fk(ab)i(initio)41 b Fr(p)r(oten)n(tial)34 b(energy)e(surface)h([17)o(,)j(18)o(])2042 2603 y(in)24 b(order)f(to)h(tak)n(e)f(in)n(to)h(accoun)n(t)g(all)f(NO)h(molecular)f (degrees)g(of)2042 2699 y(freedom)28 b(plus)h(one)f(surface)g (oscillator)e(co)r(ordinate)i(b)n(y)g(a)g(suit-)2042 2794 y(able)18 b(c)n(hoice)g(of)g(a)g(mo)r(del)h(p)r(oten)n(tial.)34 b(The)18 b(sim)n(ulations)g(indicate)2042 2890 y(the)30 b(imp)r(ortance)f(of)g(m)n(ultidimensionalit)n(y)g(e\013ects,)h(in)g (partic-)2042 2985 y(ular)d(surface)f(recoil)h(e\013ects,)h(on)f(the)h (desorption)f(dynamics.)2782 3278 y Fl(I)r(I.)89 b(THEOR)-7 b(Y)2851 3487 y(A.)87 b(Mo)r(del)2125 3704 y Fr(The)41 b(photo-induced)g(desorption)f(of)h(NO)g(from)g(NiO)g(has)2042 3799 y(b)r(een)29 b(prop)r(osed)f([15)o(])g(to)h(b)r(e)g(an)f(indirect) h(pro)r(cess)f(with)h(an)f(in-)2042 3895 y(termediate)39 b(c)n(harge)f(transfer)g(state.)72 b(This)40 b(pro)r(cess)e(can)h(b)r (e)2042 3990 y(view)n(ed)32 b(as)f(a)h(\014v)n(e)g(step)g(pro)r(cess)f (\(see)h(Fig.)g(1\):)46 b(The)32 b(creation)2042 4086 y(of)e(hot)h(electrons)f(in)h(the)g(substrate)f(due)h(to)f(the)h(laser) f(irradi-)2042 4181 y(ation)d(\(1\))g(is)g(follo)n(w)n(ed)g(b)n(y)g (the)g(transfer)g(of)g(one)g(electron)g(from)2042 4277 y(a)34 b(substrate)f(state)h(in)n(to)g(an)g(adsorbate)e(state)i(\(2\).) 57 b(No)n(w)34 b(the)2042 4372 y(adsorb)r(ed)d(molecule)h(is)h (accelerated)e(a)n(w)n(a)n(y)f(from)i(the)h(ground)2042 4468 y(state)g(minim)n(um)i(\(3\))f(and)f(after)h(the)g(return)f(of)h (the)g(electron)2042 4563 y(in)n(to)d(the)i(substrate)e(\(4\))h(the)g (adsorb)r(ed)f(molecule)g(ev)n(en)n(tually)2042 4658 y(desorbs)18 b(if)i(it)f(gained)g(enough)f(energy)g(in)i(the)g(excited) f(state)g(\(5\).)2042 4754 y(There)41 b(is)g(exp)r(erimen)n(tal)g (evidence)g(that)h(direct)f(excitations)2042 4849 y(also)35 b(pla)n(y)h(a)h(role)e([19)o(].)65 b(They)36 b(can)h(b)r(e)g(treated)f (in)h(an)f(iden-)2042 4945 y(tical)g(sc)n(heme)g(but)i(starting)d (directly)i(at)f(step)h(2.)63 b(Since)37 b(the)2042 5040 y(linear)21 b(dep)r(endence)h(of)g(the)h(desorption)e(yield)g(on)h(the) g(laser)f(\015u-)2042 5136 y(ency)k([20)o(])g(leads)f(to)h(the)h (exclusion)e(of)h(m)n(ultiple)h(excitations)e(in)2042 5231 y(most)i(sim)n(ulations)g(only)g(steps)h(3)f(to)h(5)f(are)g (explicitly)h(treated.)2125 5330 y(T)-7 b(o)21 b(mo)r(del)h(suc)n(h)g (a)f(pro)r(cess)g(w)n(e)g(com)n(bine)h(ideas)f(from)g(T)-7 b(ully's)2042 5425 y(few)n(est)42 b(switc)n(hing)g(algorithm)g([9)o(])h (and)f(generalized)f(surface)p eop %%Page: 2 2 2 1 bop 4043 -299 a Fr(2)188 1015 y @beginspecial 0 @llx 0 @lly 635 @urx 549 @ury 1417 @rhi @setspecial %%BeginDocument: graphs/DIET_detail.eps %!PS-Adobe-2.0 EPSF-2.0 %%Title: DIET_detail.eps %%Creator: fig2dev Version 3.2 Patchlevel 3c %%CreationDate: Tue Apr 15 16:49:35 2003 %%For: cbach@berg (Christian Bach) %%BoundingBox: 0 0 635 549 %%Magnification: 1.0000 %%EndComments /$F2psDict 200 dict def $F2psDict begin $F2psDict /mtrx matrix put /col-1 {0 setgray} bind def /col0 {0.000 0.000 0.000 srgb} bind def /col1 {0.000 0.000 1.000 srgb} bind def /col2 {0.000 1.000 0.000 srgb} bind def /col3 {0.000 1.000 1.000 srgb} bind def /col4 {1.000 0.000 0.000 srgb} bind def /col5 {1.000 0.000 1.000 srgb} bind def /col6 {1.000 1.000 0.000 srgb} bind def /col7 {1.000 1.000 1.000 srgb} bind def /col8 {0.000 0.000 0.560 srgb} bind def /col9 {0.000 0.000 0.690 srgb} bind def /col10 {0.000 0.000 0.820 srgb} bind def /col11 {0.530 0.810 1.000 srgb} bind def /col12 {0.000 0.560 0.000 srgb} bind def /col13 {0.000 0.690 0.000 srgb} bind def /col14 {0.000 0.820 0.000 srgb} bind def /col15 {0.000 0.560 0.560 srgb} bind def /col16 {0.000 0.690 0.690 srgb} bind def /col17 {0.000 0.820 0.820 srgb} bind def /col18 {0.560 0.000 0.000 srgb} bind def /col19 {0.690 0.000 0.000 srgb} bind def /col20 {0.820 0.000 0.000 srgb} bind def /col21 {0.560 0.000 0.560 srgb} bind def /col22 {0.690 0.000 0.690 srgb} bind def /col23 {0.820 0.000 0.820 srgb} bind def /col24 {0.500 0.190 0.000 srgb} bind def /col25 {0.630 0.250 0.000 srgb} bind def /col26 {0.750 0.380 0.000 srgb} bind def /col27 {1.000 0.500 0.500 srgb} bind def /col28 {1.000 0.630 0.630 srgb} bind def /col29 {1.000 0.750 0.750 srgb} bind def /col30 {1.000 0.880 0.880 srgb} bind def /col31 {1.000 0.840 0.000 srgb} bind def end save newpath 0 549 moveto 0 0 lineto 635 0 lineto 635 549 lineto closepath clip newpath -8.0 565.0 translate 1 -1 scale /cp {closepath} bind def /ef {eofill} bind def /gr {grestore} bind def /gs {gsave} bind def /sa {save} bind def /rs {restore} bind def /l {lineto} bind def /m {moveto} bind def /rm {rmoveto} bind def /n {newpath} bind def /s {stroke} bind def /sh {show} bind def /slc {setlinecap} bind def /slj {setlinejoin} bind def /slw {setlinewidth} bind def /srgb {setrgbcolor} bind def /rot {rotate} bind def /sc {scale} bind def /sd {setdash} bind def /ff {findfont} bind def /sf {setfont} bind def /scf {scalefont} bind def /sw {stringwidth} bind def /tr {translate} bind def /tnt {dup dup currentrgbcolor 4 -2 roll dup 1 exch sub 3 -1 roll mul add 4 -2 roll dup 1 exch sub 3 -1 roll mul add 4 -2 roll dup 1 exch sub 3 -1 roll mul add srgb} bind def /shd {dup dup currentrgbcolor 4 -2 roll mul 4 -2 roll mul 4 -2 roll mul srgb} bind def /DrawEllipse { /endangle exch def /startangle exch def /yrad exch def /xrad exch def /y exch def /x exch def /savematrix mtrx currentmatrix def x y tr xrad yrad sc 0 0 1 startangle endangle arc closepath savematrix setmatrix } def /$F2psBegin {$F2psDict begin /$F2psEnteredState save def} def /$F2psEnd {$F2psEnteredState restore end} def $F2psBegin %%Page: 1 1 10 setmiterlimit 0.06299 0.06299 sc % % Fig objects follow % % Polyline 15.000 slw gs clippath 1410 300 m 1290 300 l 1290 587 l 1350 347 l 1410 587 l cp eoclip n 1350 8550 m 1350 315 l gs col0 s gr gr % arrowhead n 1410 587 m 1350 347 l 1290 587 l 1410 587 l cp gs 0.00 setgray ef gr col0 s % Polyline gs clippath 10185 8610 m 10185 8490 l 9898 8490 l 10138 8550 l 9898 8610 l cp eoclip n 1350 8550 m 10170 8550 l gs col0 s gr gr % arrowhead n 9898 8610 m 10138 8550 l 9898 8490 l 9898 8610 l cp gs 0.00 setgray ef gr col0 s % Polyline n 7245 2745 m 7245 8730 l gs col0 s gr % Polyline 0.000 slw n 135 270 m 1035 270 l 1035 8550 l 135 8550 l cp % adsorbate excited state % Polyline 2 slj 30.000 slw n 1800 405 m 1800 406 l 1800 410 l 1801 416 l 1802 426 l 1803 440 l 1805 459 l 1808 484 l 1811 514 l 1815 550 l 1819 592 l 1824 640 l 1829 694 l 1835 753 l 1841 817 l 1848 885 l 1856 957 l 1863 1032 l 1871 1110 l 1879 1189 l 1888 1270 l 1896 1352 l 1905 1433 l 1913 1515 l 1922 1595 l 1930 1674 l 1938 1752 l 1946 1829 l 1954 1903 l 1962 1975 l 1970 2045 l 1977 2113 l 1984 2179 l 1992 2243 l 1999 2304 l 2005 2364 l 2012 2421 l 2019 2477 l 2025 2531 l 2031 2583 l 2038 2634 l 2044 2683 l 2050 2731 l 2056 2779 l 2062 2825 l 2068 2870 l 2074 2914 l 2080 2958 l 2086 3002 l 2092 3045 l 2093 3045 l 2100 3096 l 2107 3146 l 2115 3197 l 2123 3247 l 2131 3297 l 2139 3347 l 2147 3397 l 2155 3447 l 2163 3497 l 2172 3547 l 2181 3597 l 2189 3647 l 2199 3697 l 2208 3747 l 2217 3796 l 2226 3846 l 2236 3895 l 2245 3943 l 2255 3991 l 2265 4039 l 2275 4086 l 2284 4132 l 2294 4178 l 2304 4222 l 2314 4266 l 2323 4309 l 2333 4351 l 2343 4391 l 2352 4431 l 2362 4470 l 2371 4507 l 2380 4543 l 2390 4578 l 2399 4612 l 2408 4645 l 2416 4676 l 2425 4707 l 2434 4736 l 2442 4765 l 2451 4792 l 2459 4819 l 2468 4845 l 2480 4883 l 2493 4919 l 2505 4953 l 2518 4987 l 2531 5019 l 2545 5050 l 2558 5080 l 2572 5109 l 2587 5136 l 2601 5162 l 2616 5186 l 2632 5209 l 2647 5230 l 2663 5250 l 2679 5267 l 2696 5283 l 2712 5298 l 2729 5310 l 2746 5320 l 2763 5329 l 2780 5336 l 2797 5341 l 2814 5345 l 2831 5347 l 2849 5347 l 2866 5346 l 2884 5344 l 2903 5340 l 2921 5335 l 2940 5329 l 2960 5321 l 2981 5312 l 3002 5301 l 3024 5289 l 3046 5276 l 3069 5262 l 3093 5247 l 3118 5230 l 3142 5212 l 3168 5193 l 3193 5174 l 3219 5153 l 3244 5132 l 3270 5111 l 3295 5089 l 3320 5066 l 3345 5044 l 3369 5022 l 3392 5000 l 3415 4978 l 3438 4956 l 3459 4935 l 3480 4914 l 3501 4893 l 3521 4873 l 3540 4853 l 3560 4831 l 3581 4810 l 3600 4789 l 3620 4768 l 3640 4747 l 3660 4725 l 3680 4704 l 3701 4682 l 3721 4660 l 3742 4639 l 3763 4617 l 3784 4595 l 3805 4574 l 3826 4552 l 3847 4531 l 3868 4511 l 3889 4490 l 3910 4470 l 3931 4451 l 3952 4432 l 3973 4414 l 3994 4396 l 4015 4378 l 4037 4361 l 4058 4344 l 4080 4328 l 4101 4312 l 4122 4297 l 4145 4281 l 4168 4265 l 4192 4250 l 4217 4234 l 4242 4218 l 4269 4202 l 4297 4185 l 4326 4169 l 4355 4153 l 4385 4137 l 4416 4121 l 4447 4105 l 4479 4090 l 4511 4075 l 4543 4061 l 4575 4046 l 4608 4033 l 4640 4020 l 4672 4008 l 4704 3996 l 4735 3985 l 4766 3974 l 4797 3964 l 4828 3955 l 4859 3946 l 4890 3938 l 4914 3931 l 4939 3925 l 4963 3920 l 4989 3914 l 5015 3909 l 5041 3904 l 5069 3899 l 5097 3894 l 5126 3890 l 5156 3886 l 5187 3882 l 5219 3878 l 5253 3874 l 5287 3870 l 5323 3867 l 5359 3864 l 5397 3861 l 5436 3858 l 5475 3855 l 5516 3853 l 5558 3851 l 5601 3848 l 5644 3846 l 5688 3845 l 5733 3843 l 5779 3842 l 5826 3840 l 5873 3839 l 5922 3838 l 5971 3837 l 6020 3836 l 6071 3835 l 6123 3834 l 6176 3834 l 6230 3833 l 6285 3833 l 6323 3832 l 6361 3832 l 6401 3831 l 6441 3831 l 6483 3831 l 6526 3830 l 6570 3830 l 6615 3830 l 6662 3830 l 6711 3829 l 6761 3829 l 6813 3829 l 6868 3829 l 6924 3828 l 6982 3828 l 7043 3828 l 7106 3828 l 7172 3828 l 7239 3827 l 7310 3827 l 7383 3827 l 7458 3827 l 7535 3827 l 7615 3827 l 7697 3827 l 7781 3826 l 7866 3826 l 7953 3826 l 8041 3826 l 8129 3826 l 8218 3826 l 8306 3826 l 8393 3826 l 8479 3826 l 8563 3826 l 8644 3825 l 8721 3825 l 8795 3825 l 8864 3825 l 8929 3825 l 8988 3825 l 9041 3825 l 9088 3825 l 9129 3825 l 9165 3825 l 9194 3825 l 9218 3825 l 9236 3825 l 9250 3825 l 9260 3825 l 9266 3825 l 9269 3825 l 9270 3825 l gs col4 s gr % adsobate groundstate % Polyline n 2565 3555 m 2565 3556 l 2565 3560 l 2566 3566 l 2567 3576 l 2569 3590 l 2571 3609 l 2573 3634 l 2576 3664 l 2580 3700 l 2585 3742 l 2590 3790 l 2595 3844 l 2602 3902 l 2608 3966 l 2616 4034 l 2623 4106 l 2632 4181 l 2640 4258 l 2649 4338 l 2658 4418 l 2667 4500 l 2676 4581 l 2685 4662 l 2694 4742 l 2703 4822 l 2713 4899 l 2722 4975 l 2730 5049 l 2739 5121 l 2748 5191 l 2757 5258 l 2765 5324 l 2773 5387 l 2781 5448 l 2790 5507 l 2798 5564 l 2805 5620 l 2813 5673 l 2821 5725 l 2829 5775 l 2837 5824 l 2845 5871 l 2853 5918 l 2861 5963 l 2869 6008 l 2877 6052 l 2885 6095 l 2894 6138 l 2902 6180 l 2903 6180 l 2913 6230 l 2924 6279 l 2934 6329 l 2946 6378 l 2957 6426 l 2969 6475 l 2981 6524 l 2993 6572 l 3006 6621 l 3019 6669 l 3032 6718 l 3046 6766 l 3059 6814 l 3073 6862 l 3088 6909 l 3102 6957 l 3117 7004 l 3132 7050 l 3147 7096 l 3162 7141 l 3178 7186 l 3193 7230 l 3209 7273 l 3224 7315 l 3239 7356 l 3255 7396 l 3270 7435 l 3285 7473 l 3300 7509 l 3315 7545 l 3330 7579 l 3345 7612 l 3359 7644 l 3373 7675 l 3387 7705 l 3401 7733 l 3415 7761 l 3428 7787 l 3441 7812 l 3454 7837 l 3467 7860 l 3480 7883 l 3499 7915 l 3518 7945 l 3537 7975 l 3556 8003 l 3575 8029 l 3595 8054 l 3614 8079 l 3634 8101 l 3654 8123 l 3675 8143 l 3695 8162 l 3716 8180 l 3737 8197 l 3758 8212 l 3778 8226 l 3799 8238 l 3820 8249 l 3840 8259 l 3861 8268 l 3881 8275 l 3901 8282 l 3920 8287 l 3940 8291 l 3959 8295 l 3978 8298 l 3997 8300 l 4016 8302 l 4035 8303 l 4058 8303 l 4080 8303 l 4104 8302 l 4128 8301 l 4153 8298 l 4178 8295 l 4204 8291 l 4230 8287 l 4257 8281 l 4284 8275 l 4311 8267 l 4338 8259 l 4365 8250 l 4392 8240 l 4418 8230 l 4444 8219 l 4469 8207 l 4493 8194 l 4516 8181 l 4539 8168 l 4560 8153 l 4581 8139 l 4601 8123 l 4620 8108 l 4637 8092 l 4654 8076 l 4671 8059 l 4687 8041 l 4704 8023 l 4720 8003 l 4737 7983 l 4753 7961 l 4770 7939 l 4787 7917 l 4803 7893 l 4820 7869 l 4836 7845 l 4853 7821 l 4870 7796 l 4886 7772 l 4902 7747 l 4919 7723 l 4935 7699 l 4951 7676 l 4967 7653 l 4983 7630 l 4999 7608 l 5015 7587 l 5031 7566 l 5048 7545 l 5063 7526 l 5079 7507 l 5096 7488 l 5113 7469 l 5131 7450 l 5150 7431 l 5169 7412 l 5190 7393 l 5211 7374 l 5233 7355 l 5255 7337 l 5278 7318 l 5302 7300 l 5327 7282 l 5352 7265 l 5377 7248 l 5402 7231 l 5428 7215 l 5454 7200 l 5481 7186 l 5507 7172 l 5533 7159 l 5559 7147 l 5586 7135 l 5612 7124 l 5639 7114 l 5665 7104 l 5693 7095 l 5715 7088 l 5738 7081 l 5762 7075 l 5786 7068 l 5811 7062 l 5837 7057 l 5864 7051 l 5891 7046 l 5920 7041 l 5950 7036 l 5981 7032 l 6013 7027 l 6046 7023 l 6080 7019 l 6115 7016 l 6151 7012 l 6188 7009 l 6226 7006 l 6265 7003 l 6305 7001 l 6345 6998 l 6386 6996 l 6428 6994 l 6470 6993 l 6512 6991 l 6556 6990 l 6599 6988 l 6644 6987 l 6688 6986 l 6734 6985 l 6780 6985 l 6826 6984 l 6874 6983 l 6923 6983 l 6958 6982 l 6993 6982 l 7030 6981 l 7068 6981 l 7106 6981 l 7146 6980 l 7187 6980 l 7229 6980 l 7273 6979 l 7319 6979 l 7366 6979 l 7415 6979 l 7467 6978 l 7520 6978 l 7576 6978 l 7633 6978 l 7694 6977 l 7756 6977 l 7821 6977 l 7888 6977 l 7958 6977 l 8029 6977 l 8103 6976 l 8178 6976 l 8254 6976 l 8331 6976 l 8409 6976 l 8486 6976 l 8563 6976 l 8639 6976 l 8713 6976 l 8784 6975 l 8851 6975 l 8915 6975 l 8974 6975 l 9028 6975 l 9077 6975 l 9120 6975 l 9157 6975 l 9188 6975 l 9214 6975 l 9234 6975 l 9248 6975 l 9259 6975 l 9265 6975 l 9269 6975 l 9270 6975 l gs col1 s gr % adsobate groundstate % Polyline n 2565 1260 m 2565 1261 l 2565 1265 l 2566 1271 l 2567 1281 l 2569 1295 l 2571 1314 l 2573 1339 l 2576 1369 l 2580 1405 l 2585 1447 l 2590 1495 l 2595 1549 l 2602 1607 l 2608 1671 l 2616 1739 l 2623 1811 l 2632 1886 l 2640 1963 l 2649 2043 l 2658 2123 l 2667 2205 l 2676 2286 l 2685 2367 l 2694 2447 l 2703 2527 l 2713 2604 l 2722 2680 l 2730 2754 l 2739 2826 l 2748 2896 l 2757 2963 l 2765 3029 l 2773 3092 l 2781 3153 l 2790 3212 l 2798 3269 l 2805 3325 l 2813 3378 l 2821 3430 l 2829 3480 l 2837 3529 l 2845 3576 l 2853 3623 l 2861 3668 l 2869 3713 l 2877 3757 l 2885 3800 l 2894 3843 l 2902 3885 l 2903 3885 l 2913 3935 l 2924 3984 l 2934 4034 l 2946 4083 l 2957 4131 l 2969 4180 l 2981 4229 l 2993 4277 l 3006 4326 l 3019 4374 l 3032 4423 l 3046 4471 l 3059 4519 l 3073 4567 l 3088 4614 l 3102 4662 l 3117 4709 l 3132 4755 l 3147 4801 l 3162 4846 l 3178 4891 l 3193 4935 l 3209 4978 l 3224 5020 l 3239 5061 l 3255 5101 l 3270 5140 l 3285 5178 l 3300 5214 l 3315 5250 l 3330 5284 l 3345 5317 l 3359 5349 l 3373 5380 l 3387 5410 l 3401 5438 l 3415 5466 l 3428 5492 l 3441 5517 l 3454 5542 l 3467 5565 l 3480 5588 l 3499 5620 l 3518 5650 l 3537 5680 l 3556 5708 l 3575 5734 l 3595 5759 l 3614 5784 l 3634 5806 l 3654 5828 l 3675 5848 l 3695 5867 l 3716 5885 l 3737 5902 l 3758 5917 l 3778 5931 l 3799 5943 l 3820 5954 l 3840 5964 l 3861 5973 l 3881 5980 l 3901 5987 l 3920 5992 l 3940 5996 l 3959 6000 l 3978 6003 l 3997 6005 l 4016 6007 l 4035 6008 l 4058 6008 l 4080 6008 l 4104 6007 l 4128 6006 l 4153 6003 l 4178 6000 l 4204 5996 l 4230 5992 l 4257 5986 l 4284 5980 l 4311 5972 l 4338 5964 l 4365 5955 l 4392 5945 l 4418 5935 l 4444 5924 l 4469 5912 l 4493 5899 l 4516 5886 l 4539 5873 l 4560 5858 l 4581 5844 l 4601 5828 l 4620 5813 l 4637 5797 l 4654 5781 l 4671 5764 l 4687 5746 l 4704 5728 l 4720 5708 l 4737 5688 l 4753 5666 l 4770 5644 l 4787 5622 l 4803 5598 l 4820 5574 l 4836 5550 l 4853 5526 l 4870 5501 l 4886 5477 l 4902 5452 l 4919 5428 l 4935 5404 l 4951 5381 l 4967 5358 l 4983 5335 l 4999 5313 l 5015 5292 l 5031 5271 l 5048 5250 l 5063 5231 l 5079 5212 l 5096 5193 l 5113 5174 l 5131 5155 l 5150 5136 l 5169 5117 l 5190 5098 l 5211 5079 l 5233 5060 l 5255 5042 l 5278 5023 l 5302 5005 l 5327 4987 l 5352 4970 l 5377 4953 l 5402 4936 l 5428 4920 l 5454 4905 l 5481 4891 l 5507 4877 l 5533 4864 l 5559 4852 l 5586 4840 l 5612 4829 l 5639 4819 l 5665 4809 l 5693 4800 l 5715 4793 l 5738 4786 l 5762 4780 l 5786 4773 l 5811 4767 l 5837 4762 l 5864 4756 l 5891 4751 l 5920 4746 l 5950 4741 l 5981 4737 l 6013 4732 l 6046 4728 l 6080 4724 l 6115 4721 l 6151 4717 l 6188 4714 l 6226 4711 l 6265 4708 l 6305 4706 l 6345 4703 l 6386 4701 l 6428 4699 l 6470 4698 l 6512 4696 l 6556 4695 l 6599 4693 l 6644 4692 l 6688 4691 l 6734 4690 l 6780 4690 l 6826 4689 l 6874 4688 l 6923 4688 l 6958 4687 l 6993 4687 l 7030 4686 l 7068 4686 l 7106 4686 l 7146 4685 l 7187 4685 l 7229 4685 l 7273 4684 l 7319 4684 l 7366 4684 l 7415 4684 l 7467 4683 l 7520 4683 l 7576 4683 l 7633 4683 l 7694 4682 l 7756 4682 l 7821 4682 l 7888 4682 l 7958 4682 l 8029 4682 l 8103 4681 l 8178 4681 l 8254 4681 l 8331 4681 l 8409 4681 l 8486 4681 l 8563 4681 l 8639 4681 l 8713 4681 l 8784 4680 l 8851 4680 l 8915 4680 l 8974 4680 l 9028 4680 l 9077 4680 l 9120 4680 l 9157 4680 l 9188 4680 l 9214 4680 l 9234 4680 l 9248 4680 l 9259 4680 l 9265 4680 l 9269 4680 l 9270 4680 l gs col1 s gr % adsobate groundstate % Polyline n 2655 450 m 2655 452 l 2656 455 l 2656 463 l 2657 474 l 2659 490 l 2661 512 l 2664 539 l 2668 572 l 2672 612 l 2677 656 l 2682 707 l 2688 761 l 2694 821 l 2701 883 l 2708 948 l 2716 1015 l 2724 1084 l 2732 1152 l 2740 1221 l 2748 1289 l 2756 1357 l 2764 1422 l 2772 1487 l 2780 1549 l 2788 1609 l 2796 1668 l 2803 1724 l 2811 1778 l 2819 1831 l 2827 1882 l 2834 1931 l 2842 1978 l 2850 2024 l 2858 2069 l 2866 2113 l 2874 2156 l 2882 2198 l 2891 2239 l 2899 2281 l 2908 2322 l 2918 2363 l 2927 2405 l 2938 2448 l 2948 2491 l 2959 2534 l 2970 2577 l 2982 2621 l 2994 2665 l 3006 2709 l 3019 2753 l 3032 2798 l 3046 2843 l 3059 2888 l 3074 2933 l 3088 2978 l 3103 3023 l 3118 3068 l 3133 3113 l 3148 3158 l 3164 3202 l 3180 3246 l 3196 3289 l 3212 3331 l 3228 3373 l 3244 3414 l 3259 3454 l 3275 3493 l 3291 3531 l 3307 3568 l 3322 3604 l 3338 3638 l 3353 3672 l 3368 3704 l 3382 3735 l 3397 3765 l 3411 3794 l 3425 3822 l 3439 3849 l 3453 3874 l 3467 3899 l 3480 3923 l 3499 3955 l 3518 3985 l 3537 4015 l 3556 4043 l 3575 4069 l 3595 4094 l 3614 4119 l 3634 4141 l 3654 4163 l 3675 4183 l 3695 4202 l 3716 4220 l 3737 4237 l 3758 4252 l 3778 4266 l 3799 4278 l 3820 4289 l 3840 4299 l 3861 4308 l 3881 4315 l 3901 4322 l 3920 4327 l 3940 4331 l 3959 4335 l 3978 4338 l 3997 4340 l 4016 4342 l 4035 4343 l 4058 4343 l 4080 4343 l 4104 4342 l 4128 4341 l 4153 4338 l 4178 4335 l 4204 4331 l 4230 4327 l 4257 4321 l 4284 4315 l 4311 4307 l 4338 4299 l 4365 4290 l 4392 4280 l 4418 4270 l 4444 4259 l 4469 4247 l 4493 4234 l 4516 4221 l 4539 4208 l 4560 4193 l 4581 4179 l 4601 4163 l 4620 4148 l 4637 4132 l 4654 4116 l 4671 4099 l 4687 4081 l 4704 4063 l 4720 4043 l 4737 4023 l 4753 4001 l 4770 3979 l 4787 3957 l 4803 3933 l 4820 3909 l 4836 3885 l 4853 3861 l 4870 3836 l 4886 3812 l 4902 3787 l 4919 3763 l 4935 3739 l 4951 3716 l 4967 3693 l 4983 3670 l 4999 3648 l 5015 3627 l 5031 3606 l 5048 3585 l 5063 3566 l 5079 3547 l 5096 3528 l 5113 3509 l 5131 3490 l 5150 3471 l 5169 3452 l 5190 3433 l 5211 3414 l 5233 3395 l 5255 3377 l 5278 3358 l 5302 3340 l 5327 3322 l 5352 3305 l 5377 3288 l 5402 3271 l 5428 3255 l 5454 3240 l 5481 3226 l 5507 3212 l 5533 3199 l 5559 3187 l 5586 3175 l 5612 3164 l 5639 3154 l 5665 3144 l 5693 3135 l 5715 3128 l 5738 3121 l 5762 3115 l 5786 3108 l 5811 3102 l 5837 3097 l 5864 3091 l 5891 3086 l 5920 3081 l 5950 3076 l 5981 3072 l 6013 3067 l 6046 3063 l 6080 3059 l 6115 3056 l 6151 3052 l 6188 3049 l 6226 3046 l 6265 3043 l 6305 3041 l 6345 3038 l 6386 3036 l 6428 3034 l 6470 3033 l 6512 3031 l 6556 3030 l 6599 3028 l 6644 3027 l 6688 3026 l 6734 3025 l 6780 3025 l 6826 3024 l 6874 3023 l 6923 3023 l 6958 3022 l 6993 3022 l 7030 3021 l 7068 3021 l 7106 3021 l 7146 3020 l 7187 3020 l 7229 3020 l 7273 3019 l 7319 3019 l 7366 3019 l 7415 3019 l 7467 3018 l 7520 3018 l 7576 3018 l 7633 3018 l 7694 3017 l 7756 3017 l 7821 3017 l 7888 3017 l 7958 3017 l 8029 3017 l 8103 3016 l 8178 3016 l 8254 3016 l 8331 3016 l 8409 3016 l 8486 3016 l 8563 3016 l 8639 3016 l 8713 3016 l 8784 3015 l 8851 3015 l 8915 3015 l 8974 3015 l 9028 3015 l 9077 3015 l 9120 3015 l 9157 3015 l 9188 3015 l 9214 3015 l 9234 3015 l 9248 3015 l 9259 3015 l 9265 3015 l 9269 3015 l 9270 3015 l gs col1 s gr /Helvetica-Bold ff 360.00 scf sf 9405 6975 m gs 1 -1 sc (G0) col0 sh gr /Helvetica-Bold ff 360.00 scf sf 9360 4725 m gs 1 -1 sc (G1) col0 sh gr /Helvetica-Bold ff 360.00 scf sf 9405 3150 m gs 1 -1 sc (G2) col0 sh gr /Helvetica-Bold ff 360.00 scf sf 9360 3915 m gs 1 -1 sc (A) col0 sh gr /Helvetica-Bold ff 450.00 scf sf 1125 5130 m gs 1 -1 sc 90.0 rot (Energy) col0 sh gr /Helvetica-Bold ff 450.00 scf sf 3195 8955 m gs 1 -1 sc (Reaction Path) col0 sh gr /Helvetica-Bold ff 450.00 scf sf 6975 8955 m gs 1 -1 sc (Cutoff) col0 sh gr % Polyline 0 slj 15.000 slw gs clippath 4110 4350 m 3990 4350 l 3990 4637 l 4050 4397 l 4110 4637 l cp eoclip n 4050 8325 m 4050 4365 l gs col0 s gr gr % arrowhead n 4110 4637 m 4050 4397 l 3990 4637 l 4110 4637 l cp gs 0.00 setgray ef gr col0 s /Helvetica-Bold ff 360.00 scf sf 4140 7110 m gs 1 -1 sc (1) col0 sh gr % Ellipse n 4050 4365 101 101 0 360 DrawEllipse gs 0.00 setgray ef gr gs col0 s gr % Polyline 2 slj gs clippath 3230 4875 m 3318 4956 l 3514 4746 l 3307 4881 l 3426 4664 l cp eoclip n 3915 4230 m 3285 4905 l gs col0 s gr gr % arrowhead 0 slj n 3426 4664 m 3307 4881 l 3514 4746 l 3426 4664 l cp gs 0.00 setgray ef gr col0 s /Helvetica-Bold ff 360.00 scf sf 4050 4185 m gs 1 -1 sc (2) col0 sh gr /Helvetica-Bold ff 360.00 scf sf 3450 4450 m gs 1 -1 sc (3) col0 sh gr % Ellipse n 3240 5130 101 101 0 360 DrawEllipse gs 0.00 setgray ef gr gs col0 s gr /Helvetica-Bold ff 360.00 scf sf 3015 5670 m gs 1 -1 sc (4) col0 sh gr % Polyline 2 slj gs clippath 8970 4605 m 8970 4485 l 8683 4485 l 8923 4545 l 8683 4605 l cp eoclip n 3420 5220 m 3422 5223 l 3425 5228 l 3431 5238 l 3440 5253 l 3452 5272 l 3467 5296 l 3483 5322 l 3501 5351 l 3519 5380 l 3538 5410 l 3556 5438 l 3573 5465 l 3589 5489 l 3604 5512 l 3618 5534 l 3631 5553 l 3644 5571 l 3656 5588 l 3667 5603 l 3679 5618 l 3690 5633 l 3704 5649 l 3718 5666 l 3732 5682 l 3747 5698 l 3763 5713 l 3779 5728 l 3795 5743 l 3813 5757 l 3830 5770 l 3848 5782 l 3867 5794 l 3885 5804 l 3904 5813 l 3922 5821 l 3941 5828 l 3959 5834 l 3978 5839 l 3998 5843 l 4015 5845 l 4034 5847 l 4053 5849 l 4073 5849 l 4094 5849 l 4116 5848 l 4138 5846 l 4161 5843 l 4185 5840 l 4209 5835 l 4232 5830 l 4256 5824 l 4279 5817 l 4302 5810 l 4324 5802 l 4346 5793 l 4367 5784 l 4387 5774 l 4406 5764 l 4425 5753 l 4442 5742 l 4458 5731 l 4475 5719 l 4491 5706 l 4508 5692 l 4525 5677 l 4542 5662 l 4559 5646 l 4576 5629 l 4592 5611 l 4609 5593 l 4626 5575 l 4643 5556 l 4659 5537 l 4675 5517 l 4690 5498 l 4706 5479 l 4721 5460 l 4735 5441 l 4749 5422 l 4763 5404 l 4778 5385 l 4792 5366 l 4806 5347 l 4821 5327 l 4836 5307 l 4851 5287 l 4867 5266 l 4883 5244 l 4900 5223 l 4917 5201 l 4935 5179 l 4952 5157 l 4970 5135 l 4987 5113 l 5005 5092 l 5022 5072 l 5040 5052 l 5056 5033 l 5073 5015 l 5089 4998 l 5106 4981 l 5122 4965 l 5138 4950 l 5155 4934 l 5173 4918 l 5191 4902 l 5210 4887 l 5230 4872 l 5250 4858 l 5271 4843 l 5292 4829 l 5314 4815 l 5336 4802 l 5358 4789 l 5380 4777 l 5402 4765 l 5424 4755 l 5446 4744 l 5467 4735 l 5488 4726 l 5509 4718 l 5529 4710 l 5550 4703 l 5569 4696 l 5588 4690 l 5608 4684 l 5628 4678 l 5650 4672 l 5672 4666 l 5695 4660 l 5719 4655 l 5744 4649 l 5770 4644 l 5796 4639 l 5823 4634 l 5851 4630 l 5879 4625 l 5907 4621 l 5936 4617 l 5964 4613 l 5993 4610 l 6023 4606 l 6052 4603 l 6082 4600 l 6113 4598 l 6134 4596 l 6156 4594 l 6179 4592 l 6202 4590 l 6227 4588 l 6252 4586 l 6278 4585 l 6305 4583 l 6333 4581 l 6362 4579 l 6393 4578 l 6424 4576 l 6456 4574 l 6489 4573 l 6523 4571 l 6558 4570 l 6594 4568 l 6630 4567 l 6667 4565 l 6704 4564 l 6742 4563 l 6780 4561 l 6819 4560 l 6857 4559 l 6896 4558 l 6936 4557 l 6975 4556 l 7015 4555 l 7055 4555 l 7095 4554 l 7136 4553 l 7178 4553 l 7210 4552 l 7242 4552 l 7276 4551 l 7310 4551 l 7345 4550 l 7382 4550 l 7419 4550 l 7458 4549 l 7499 4549 l 7541 4549 l 7585 4548 l 7631 4548 l 7678 4548 l 7729 4548 l 7781 4547 l 7835 4547 l 7892 4547 l 7951 4547 l 8012 4547 l 8075 4546 l 8139 4546 l 8204 4546 l 8271 4546 l 8337 4546 l 8403 4546 l 8468 4546 l 8531 4546 l 8592 4545 l 8650 4545 l 8703 4545 l 8752 4545 l 8796 4545 l 8835 4545 l 8867 4545 l 8894 4545 l 8915 4545 l 8931 4545 l 8955 4545 l gs col0 s gr gr % arrowhead 0 slj n 8683 4605 m 8923 4545 l 8683 4485 l 8683 4605 l cp gs 0.00 setgray ef gr col0 s /Helvetica-Bold ff 360.00 scf sf 4860 4905 m gs 1 -1 sc (5) col0 sh gr $F2psEnd rs %%EndDocument @endspecial -150 1185 a Fn(FIG.)31 b(1:)46 b(Sc)n(hematic)30 b(dra)n(wing)i(of)g(a)f(DIET)g(pro)r(cess.)52 b(The)31 b(p)r(oten-)-150 1272 y(tial)20 b(curv)n(es)e(lab)r(eled)h(G0{G2)i (corresp)r(ond)e(to)g(the)f(adsorbate)i(ground)-150 1360 y(state)28 b(with)f(di\013eren)n(t)f(substrate)i(excitations,)g(while)g (the)f(curv)n(e)f(la-)-150 1447 y(b)r(eled)k(A)f(corresp)r(onds)i(to)f (an)g(excitation)g(of)h(the)e(adsorbate.)48 b(The)-150 1534 y(n)n(um)n(b)r(ers)21 b(1{5)j(indicate)g(the)f(\014v)n(e)f(steps)h (of)h(the)e(desorption)i(pro)r(cess.)-150 1820 y Fr(hopping)j(metho)r (d)h([12)o(])g(with)g(those)f(of)h(Brenig)e([13)o(])i(and)f(Saal-)-150 1916 y(frank)32 b([14)o(].)51 b(First)32 b(w)n(e)g(separate)f(the)h(n)n (uclear)f(from)h(the)h(elec-)-150 2011 y(tronic)19 b(degrees)e(of)i (freedom,)i(i.e.)34 b(the)19 b(Hamilton)g(op)r(erator)f Fj(H)26 b Fr(is)-150 2107 y(split)21 b(in)n(to)g(the)g(kinetic)h (energy)e Fj(T)898 2119 y Fi(R)973 2107 y Fr(of)h(the)g(n)n(uclear)f (co)r(ordinates)-150 2202 y Fj(R)27 b Fr(and)e(an)h(electronic)f(part)g Fj(H)832 2214 y Fi(e)894 2202 y Fr(dep)r(ending)h(on)g(the)g (electronic)-150 2297 y(co)r(ordinates)31 b Fj(r)k Fr(and)d (parametrically)e(on)i(the)g(p)r(osition)g(of)g(the)-150 2393 y(n)n(uclei)c Fj(R)q Fr(.)423 2577 y Fj(H)7 b Fr(\()p Fj(r)n(;)14 b(R)q Fr(\))23 b(=)g Fj(T)859 2589 y Fi(R)931 2577 y Fr(+)18 b Fj(H)1083 2589 y Fi(e)1119 2577 y Fr(\()p Fj(r)n(;)c(R)q Fr(\))467 b(\(1\))-150 2762 y(The)29 b(electronic)e(w)n (a)n(v)n(e)g(function)i(\010)f(is)h(expanded)f(in)n(to)g(the)h(ex-)-150 2857 y(plicitly)h(treated)f(excited)h(adsorbate)e(states)i Fj(\036)1374 2869 y Fi(i)1431 2857 y Fr(and)g(a)f(collec-)-150 2953 y(tiv)n(e)38 b(state)f Fj( )k Fr(con)n(taining)c(the)h(molecular)f (ground)f(state)i(to-)-150 3048 y(gether)27 b(with)h(the)g(con)n(tin)n (uum)f(of)h(substrate)f(excitations.)155 3249 y(\010\()p Fj(r)n(;)14 b(R)q(;)g(t)p Fr(\))23 b(=)593 3170 y Fh(X)641 3347 y Fi(i)726 3249 y Fj(c)762 3261 y Fi(i)790 3249 y Fr(\()p Fj(t)p Fr(\))p Fj(\036)933 3261 y Fi(i)962 3249 y Fr(\()p Fj(r)n(;)14 b(R)q Fr(\))k(+)g Fj( )s Fr(\()p Fj(r)n(;)c(R)q(;)g(t)p Fr(\))-150 3510 y(The)28 b(in\015uence)h(of)g (the)f(collectiv)n(e)g(state)g Fj( )k Fr(can)c(b)r(e)h(tak)n(en)f(in)n (to)-150 3606 y(accoun)n(t)h(b)n(y)g(an)g(e\013ectiv)n(e)h (non-Hermitian)f(Hamiltonian)h(\(see)-150 3701 y(c)n(hapter)d(16)f(in)i ([21)o(]\))151 3885 y Fj(H)220 3897 y Fi(ef)7 b(f)333 3885 y Fr(\()p Fj(r)n(;)14 b(R)q Fr(\))24 b(=)e Fj(T)693 3897 y Fi(e)747 3885 y Fr(+)c Fj(V)878 3897 y Fi(ef)7 b(f)992 3885 y Fr(\()p Fj(r)n(;)14 b(R)q Fr(\))k(+)g Fj(i)p Fr(\001\()p Fj(r)n(;)c(R)q Fr(\))195 b(\(2\))-150 4070 y(where)25 b Fj(T)137 4082 y Fi(e)198 4070 y Fr(is)g(the)h (kinetic)g(energy)e(op)r(erator)g(for)h(the)h(electrons.)-150 4165 y(The)k(e\013ectiv)n(e)f(p)r(oten)n(tial)g Fj(V)745 4177 y Fi(ef)7 b(f)889 4165 y Fr(and)29 b(the)h(optical)f(p)r(oten)n (tial)g(\001)-150 4261 y(are)22 b(real)h(functions)g(of)h Fj(r)i Fr(and)d Fj(R)q Fr(.)35 b(In)24 b(a)e(Newns-Andersson)h(pic-) -150 4356 y(ture)d(\001)g(is)g(related)f(to)h(the)g(lifetime)h (broadening)e(of)h(a)f(resonance)-150 4452 y(state)27 b(whic)n(h)h(can)f(b)r(e)h(determined)g(via)f([22)o(])310 4657 y(\001\()p Fj(E)5 b Fr(\))52 b(=)e Fj(\031)768 4578 y Fh(X)808 4757 y Fg(k)902 4657 y Ff(j)p Fj(V)973 4669 y Fg(k)1017 4657 y Ff(j)1040 4623 y Fq(2)1077 4657 y Fj(\016)s Fr(\()p Fj(E)24 b Ff(\000)18 b Fj(")1356 4669 y Fg(k)1400 4657 y Fr(\))354 b(\(3\))-150 4925 y(With)57 b(the)g(e\013ectiv)n(e)f(Hamiltonian)g(and)f(a)h(diabatic)g(\(i.e.)-150 5020 y Ff(r)-81 5032 y Fi(R)-26 5020 y Fj(\036)23 5032 y Fi(i)85 5020 y Fr(=)33 b(0\))h(represen)n(tation)f(of)h(the)h(w)n(a)n (v)n(e)d(functions)j Fj(\036)1715 5032 y Fi(i)1777 5020 y Fr(the)-150 5116 y(electronic)27 b(Sc)n(hr\177)-42 b(odinger)26 b(equation)h(has)g(the)h(follo)n(wing)e(form)304 5340 y(_)-34 b Fj(c)329 5352 y Fi(j)387 5340 y Fr(=)22 b Ff(\000)557 5284 y Fj(i)p 549 5321 45 4 v 549 5397 a Fe(~)617 5261 y Fh(X)666 5438 y Fi(i)751 5340 y Fj(c)787 5352 y Fi(i)815 5340 y Fj(V)863 5352 y Fi(j)s(i)940 5340 y Fr(+)1035 5284 y(1)p 1033 5321 V 1033 5397 a Fe(~)1102 5261 y Fh(X)1150 5438 y Fi(i)1235 5340 y Fj(c)1271 5352 y Fi(i)1299 5340 y Fr(\001)1368 5352 y Fi(j)s(i)1427 5340 y Fj(;)336 b Fr(\(4\))2042 -83 y(where)27 b(the)h(matrix)f(elemen) n(ts)g Fj(V)3082 -71 y Fi(ij)3169 -83 y Fr(and)g(\001)3399 -71 y Fi(j)s(i)3486 -83 y Fr(are)f(de\014ned)i(as)2513 73 y Fj(V)2561 85 y Fi(j)s(i)2670 73 y Ff(\021)49 b(h)p Fj(\036)2865 85 y Fi(j)p 2915 97 4 87 v 2932 73 a Fj(T)2981 85 y Fi(e)3034 73 y Fr(+)18 b Fj(V)3165 85 y Fi(ef)7 b(f)3279 73 y Fr(\()p Fj(r)n(;)14 b(R)q Fr(\))p 3493 97 V 32 w Fj(\036)3560 85 y Fi(i)3588 73 y Ff(i)2492 194 y Fr(\001)2561 206 y Fi(j)s(i)2670 194 y Ff(\021)49 b(h)p Fj(\036)2865 206 y Fi(j)p 2915 217 V 2932 194 a Fr(\001\()p Fj(r)n(;)14 b(R)q Fr(\))p 3215 217 V 32 w Fj(\036)3282 206 y Fi(i)3309 194 y Ff(i)42 b Fj(;)572 b Fr(\(5\))2042 350 y(resp)r(ectiv)n(ely)-7 b(.)71 b(F)-7 b(or)38 b(the)i(diagonal)e(elemen)n(ts)h(of)g(the)g(densit)n(y)2042 445 y(matrix)27 b Fj(a)2356 457 y Fi(j)s(i)2437 445 y Ff(\021)c Fj(c)2561 415 y Fi(?)2561 467 y(j)2599 445 y Fj(c)2635 457 y Fi(i)2690 445 y Fr(this)28 b(leads)f(to)2506 657 y(_)-34 b Fj(a)2539 669 y Fi(j)s(j)2628 657 y Fr(=)2716 578 y Fh(X)2764 755 y Fi(i)2850 657 y Fj(b)2886 669 y Fi(j)s(i)2962 657 y Fr(+)3045 578 y Fh(X)3093 755 y Fi(i)3191 601 y Fr(2)p 3189 638 45 4 v 3189 714 a Fe(~)3244 657 y Ff(<)14 b Fr([)p Fj(a)3385 669 y Fi(j)s(i)3443 657 y Fr(\001)3512 669 y Fi(j)s(i)3571 657 y Fr(])f Fj(;)348 b Fr(\(6\))2042 902 y(with)30 b Fj(b)2269 914 y Fi(j)s(i)2354 902 y Ff(\021)2457 869 y Fq(2)p 2455 883 37 4 v 2455 931 a Fd(~)2502 902 y Ff(=)14 b Fr([)o Fj(a)2642 914 y Fi(j)s(i)2701 902 y Fj(V)2749 914 y Fi(j)s(i)2808 902 y Fr(].)43 b(Note)30 b(that)g(for)f(a)g(normalized)g(w)n(a)n(v)n(e)2042 998 y(function)h(\010)g(the)g(o)r(ccupation)f(probabilit)n(y)g Fj(a)3499 1010 y Fi(cc)3592 998 y Fr(for)g(the)i(\\rest")2042 1093 y(is)c(simply)h(giv)n(en)f(b)n(y)g Fj(a)2767 1105 y Fi(cc)2853 1093 y Ff(\021)c Fr(1)18 b Ff(\000)3084 1031 y Fh(P)3172 1118 y Fi(j)3221 1093 y Fj(a)3265 1105 y Fi(j)s(j)3358 1093 y Fr(leading)27 b(to)2416 1308 y(_)-33 b Fj(a)2450 1320 y Fi(cc)2536 1308 y Fr(=)23 b Ff(\000)2703 1229 y Fh(X)2747 1406 y Fi(j)2846 1308 y Fr(_)-33 b Fj(a)2880 1320 y Fi(j)s(j)2969 1308 y Fr(=)22 b Ff(\000)3133 1252 y Fr(2)p 3131 1289 45 4 v 3131 1365 a Fe(~)3200 1229 y Fh(X)3232 1406 y Fi(ij)3333 1308 y Ff(<)14 b Fr([)p Fj(a)3474 1320 y Fi(j)s(i)3533 1308 y Fr(\001)3602 1320 y Fi(j)s(i)3660 1308 y Fr(])g Fj(;)258 b Fr(\(7\))2042 1557 y(since)2243 1494 y Fh(P)2330 1582 y Fi(j)s(i)2403 1557 y Fj(b)2439 1569 y Fi(j)s(i)2520 1557 y Fr(=)22 b(0.)36 b(The)25 b(n)n(uclear)f(co)r(ordinates)g Fj(R)i Fr(are)e(treated)2042 1652 y(classically)i(and)h(ob)r(ey)h(the)g (Newtonian)f(equation)g(of)h(motion)2551 1837 y(\177)2533 1858 y Fj(R)c Fr(=)2717 1802 y Ff(\000)p Fr(1)p 2717 1839 107 4 v 2725 1915 a Fj(M)2833 1858 y Ff(r)2916 1741 y Fh(\024)2970 1802 y Ff(h)q Fj( )3057 1814 y Fi(occ)p 3167 1822 4 84 v 3184 1802 a Fj(H)3253 1814 y Fi(e)p 3302 1822 V 3320 1802 a Fj( )3374 1814 y Fi(occ)3470 1802 y Ff(i)p 2970 1839 532 4 v 3038 1915 a(h)p Fj( )3124 1927 y Fi(occ)p 3235 1935 4 84 v 3252 1915 a Fj( )3306 1927 y Fi(occ)3402 1915 y Ff(i)3512 1741 y Fh(\025)3570 1858 y Fj(;)385 b Fr(\(8\))2042 2063 y(where)34 b Fj( )2343 2075 y Fi(occ)2473 2063 y Fr(is)h(the)f(curren)n(tly)g(o)r(ccupied)g (state.)57 b(Using)34 b(clas-)2042 2159 y(sical)h(equations)f(of)i (motion)f(for)g(the)g(n)n(uclei)h(is)f(a)g(reasonable)2042 2254 y(appro)n(ximation)25 b(as)i(long)g(as)g(h)n(ydrogen)f(is)i(not)f (in)n(v)n(olv)n(ed.)2125 2350 y(These)60 b(equations)g(are)g(equiv)-5 b(alen)n(t)61 b(to)f(the)i(ones)e(that)2042 2445 y(ha)n(v)n(e)44 b(b)r(een)i(deriv)n(ed)e(in)i(the)g(generalized)e(surface)h(hopping) 2042 2541 y(metho)r(d)38 b([12)o(].)65 b(In)38 b(our)e(scenario,)i(ho)n (w)n(ev)n(er,)g(up)r(on)f(a)g(transi-)2042 2636 y(tion)f(to)f(the)h (con)n(tin)n(uum)g(state)g(w)n(e)f(assume)g(that)h(the)h(whole)2042 2732 y(excess)30 b(energy)h(is)g(tak)n(en)g(up)h(b)n(y)f(the)h (substrate)f(electrons,)h(as)2042 2827 y(it)21 b(is)f(usually)g(done)g (in)g(the)h(mo)r(deling)f(of)g(laser-induced)g(desorp-)2042 2922 y(tion)h([2)o(].)35 b(This)21 b(means)g(that)g(up)r(on)g(a)f (switc)n(h)h(to)g(the)g(con)n(tin)n(uum)2042 3018 y(state)32 b(w)n(e)f(just)i(mak)n(e)e(a)g(F)-7 b(ranc)n(k-Condon)30 b(transition,)j(i.e.)50 b(w)n(e)2042 3113 y(transfer)28 b(the)h(molecule)f(to)h(the)g(ground)f(state)g(p)r(oten)n(tial)h(with) 2042 3209 y(its)f(kinetic)h(energy)e(preserv)n(ed)f(and)i(p)r(erform)g (ordinary)e(Born-)2042 3304 y(Opp)r(enheimer)31 b(molecular)g(dynamics) g(un)n(til)h(the)g(\014nal)f(fate)h(of)2042 3400 y(the)c(molecule)f (has)g(b)r(een)h(determined.)2125 3495 y(If)40 b(just)f(one)g (electronically)f(excited)i(state)f(is)g(considered,)2042 3591 y(then)31 b(the)g(equations)f(b)r(ecome)g(m)n(uc)n(h)h(simpler.)46 b(According)29 b(to)2042 3686 y(Eqs.)e(6)g(and)g(7,)g(the)h (deexcitation)g(rate)e(is)i(directly)f(giv)n(en)g(b)n(y)2377 3884 y(_)-33 b Fj(a)2411 3896 y Fq(11)2531 3884 y Fr(=)51 b Ff(\000)10 b Fr(_)-33 b Fj(a)2756 3896 y Fi(cc)2869 3884 y Fr(=)62 b(_)-34 b Fj(c)3021 3896 y Fq(1)3058 3884 y Fj(c)3094 3850 y Fc(\003)3094 3905 y Fq(1)3150 3884 y Fr(+)19 b Fj(c)3270 3896 y Fq(1)3318 3884 y Fr(_)-34 b Fj(c)3343 3850 y Fc(\003)3343 3905 y Fq(1)3404 3884 y Fr(=)3501 3828 y(2)p Fj(a)3587 3840 y Fq(11)3657 3828 y Fr(\001)p 3501 3865 225 4 v 3591 3941 a Fe(~)3736 3884 y Fj(:)219 b Fr(\(9\))2042 4068 y(In)40 b(fact,)k(for)c(suc)n(h)g(a)g (situation)g(no)g(electronic)g(Sc)n(hr\177)-42 b(odinger)2042 4163 y(equation)27 b(has)g(to)g(b)r(e)h(n)n(umerically)f(in)n (tegrated.)2125 4259 y(Our)f(metho)r(d)i(could)f(in)g(principle)g(also) f(b)r(e)i(extended)f(in)g(or-)2042 4354 y(der)h(to)h(include)g(the)h (excitation)e(pro)r(cess.)40 b(F)-7 b(urthermore,)28 b(tak-)2042 4450 y(ing)20 b(explicit)h(time)g(dep)r(endence)g(in)n(to)g (accoun)n(t)f(is)g(also)g(straigh)n(t-)2042 4545 y(forw)n(ard.)66 b(This)37 b(could)h(b)r(e)g(used,)i(e.g.,)g(to)e(mo)r(del)g(the)g (pulse)2042 4641 y(shap)r(e)33 b(of)g(the)h(exciting)g(laser)e(or)g (the)i(thermalization)f(of)g(hot)2042 4736 y(electrons)26 b(in)i(the)g(case)f(of)h(an)f(indirect)g(pro)r(cess.)2776 5008 y Fl(B.)88 b(Pro)r(cedure)2125 5222 y Fr(W)-7 b(e)31 b(start)f(our)g(tra)5 b(jectories)30 b(b)n(y)g(assuming)g(that)h(they)g (ha)n(v)n(e)2042 5318 y(b)r(een)20 b(transfered)g(to)g(the)h(excited)f (state)g(p)r(oten)n(tial)g(in)h(a)f(F)-7 b(ranc)n(k-)2042 5413 y(Condon)29 b(transition.)43 b(The)30 b(initial)g(conditions)f (corresp)r(ond)f(to)p eop %%Page: 3 3 3 2 bop 4043 -299 a Fr(3)-150 -83 y(a)34 b(Gaussian)f(distribution)i (in)f(p)r(osition)g(and)h(momen)n(tum)f(ac-)-150 12 y(cording)j(to)h (the)h(curv)-5 b(ature)37 b(of)i(the)f(ground)f(state)h(p)r(oten)n (tial)-150 108 y(energy)26 b(surface)h(at)h(the)g(energy)e(minim)n(um)i (p)r(osition.)-67 209 y(Then)20 b(w)n(e)f(n)n(umerically)f(solv)n(e)h (the)h(classical)e(equation)h(of)g(mo-)-150 304 y(tion)34 b(on)f(the)h(excited)g(state)f(p)r(oten)n(tial.)55 b(After)34 b(eac)n(h)f(in)n(tegra-)-150 400 y(tion)39 b(step)f(in)h(the)g(excited) g(state)g(w)n(e)f(decide)h(b)n(y)f(comparing)-150 508 y(the)32 b(deca)n(y)f(probabilit)n(y)g Fj(p)f Fr(=)838 468 y Fq(2\001\()p Fi(R)p Fq(\))p Fi(dt)p 838 489 250 4 v 944 537 a Fd(~)1130 508 y Fr(with)i(a)g(random)f(n)n(um-)-150 604 y(b)r(er,)41 b(whether)d(to)h(con)n(tin)n(ue)e(in)i(the)g(excited)f (or)g(the)g(ground)-150 699 y(state.)e(After)26 b(the)g(F)-7 b(ranc)n(k-Condon)23 b(transition)i(to)h(the)f(ground)-150 794 y(state)i(has)f(b)r(een)h(p)r(erformed,)g(the)g(classical)e(tra)5 b(jectory)25 b(on)i(the)-150 890 y(ground)f(state)h(p)r(oten)n(tial)g (is)g(con)n(tin)n(ued)f(un)n(til)i(it)f(is)g(either)g(con-)-150 985 y(sidered)36 b(to)h(remain)f(trapp)r(ed)h(or)e(un)n(til)j(it)f (reac)n(hes)e(a)h(certain)-150 1081 y(cuto\013)d(distance)f Fj(z)455 1093 y Fq(CO)590 1081 y Fr(from)g(the)h(surface)f(in)g(whic)n (h)h(case)f(it)h(is)-150 1176 y(considered)27 b(to)h(b)r(e)h(desorb)r (ed.)37 b(Reaction)28 b(probabilities)f(are)h(\014-)-150 1272 y(nally)22 b(obtained)f(b)n(y)h(a)n(v)n(eraging)d(o)n(v)n(er)h(at) i(least)g(10)1402 1242 y Fq(6)1460 1272 y Fr(tra)5 b(jectories.)-67 1373 y(F)-7 b(or)49 b(constan)n(t)f(optical)h(p)r(oten)n(tial)h(\001)f (this)h(pro)r(cedure)f(is)-150 1468 y(equiv)-5 b(alen)n(t)34 b(to)g(the)h(Gadzuk)f(sc)n(heme)g([23)o(]\))h(as)e(used,)j(e.g.,)g(in) -150 1564 y([17)o(].)71 b(In)39 b(this)h(sc)n(heme,)h(the)f(o)n(v)n (erall)c(result)j(is)g(obtained)g(b)n(y)-150 1659 y(running)28 b(jumping)h(w)n(a)n(v)n(e-pac)n(k)n(et)c(calculations)i(with)h (di\013eren)n(t)-150 1755 y(residence)38 b(times)h(and)g(then)g (determining)g(an)f(a)n(v)n(erage)e(with)-150 1850 y(the)c(w)n(eigh)n (ting)f(function)h Fj(w)763 1862 y Fi(\034)805 1850 y Fr(\()p Fj(t)p Fr(\))e(=)1036 1817 y Fq(1)p 1033 1831 38 4 v 1033 1879 a Fi(\034)1095 1850 y Fr(exp)o(\()p Ff(\000)p Fj(t=\034)9 b Fr(\).)50 b(The)32 b(a)n(v)n(er-)-150 1946 y(age)g(residence)g(time)h Fj(\034)42 b Fr(is)33 b(an)f(adjustable)g(parameter)g(that)h(is)-150 2041 y(directly)27 b(related)g(to)h(a)f(constan)n(t)g(optical)g(p)r(oten)n(tial)g(b)n(y) 716 2273 y Fj(\034)33 b Fr(=)915 2216 y Fe(~)p 882 2254 111 4 v 882 2330 a Fr(2\001)1003 2273 y Fj(:)719 b Fr(\(10\))590 2607 y Fl(C.)88 b(P)n(oten)n(tials)-67 2826 y Fr(The)41 b(p)r(oten)n(tial)g(energy)f(surfaces)g(w)n(e)g(used)h(in)h(our)e(sim)n (u-)-150 2922 y(lation)c(are)f(based)g(on)h(t)n(w)n(o)f(t)n(w)n (o-dimensional)f(p)r(oten)n(tials)i Fj(V)1831 2934 y Fq(a)p Fi(i)-150 3017 y Fr(from)21 b(Kl)r(\177)-44 b(uner)20 b(et)i(al.)f([17)o(].)35 b(One)20 b(corresp)r(onds)g(to)h(the)g (electronic)-150 3113 y(ground)k(state)h(while)h(the)f(other)g(is)g(a)g (c)n(harge)f(transfer)g(state)h(in)-150 3208 y(whic)n(h)j(an)g (electron)f(from)g(the)i(substrate)e(is)h(transfered)f(to)h(an)-150 3304 y(adsorbate)i(state.)54 b(These)33 b(p)r(oten)n(tials)f(w)n(ere)h (obtained)f(b)n(y)h(\014t-)-150 3399 y(ting)22 b(analytical)g (expressions)e(to)j(quan)n(tum)f(c)n(hemical)g Fk(ab)j(initio)-150 3495 y Fr(calculations.)39 b(The)29 b(t)n(w)n(o)f(degrees)g(of)g (freedom)h(considered)e(are)-150 3590 y(the)i(molecule-surface)f (distance)h Fj(z)j Fr(and)d(the)h(p)r(olar)e(angle)g Fj(\022)j Fr(of)-150 3686 y(the)d(molecule)f(with)h(resp)r(ect)g(to)f (the)h(surface)f(normal.)-67 3786 y(The)k(other)e(four)h(NO)h(degrees)e (of)h(freedom)g(w)n(ere)g(addition-)-150 3882 y(ally)46 b(tak)n(en)g(in)n(to)g(accoun)n(t)f(using)h(a)g(ph)n(ysically)f (reasonable)-150 3977 y(mo)r(del)33 b(p)r(oten)n(tial.)53 b(Details)33 b(of)g(the)g(parametrization)e(will)i(b)r(e)-150 4073 y(published)28 b(elsewhere.)37 b(F)-7 b(urthermore,)27 b(in)h(order)f(to)g(mo)r(del)h(re-)-150 4168 y(coil)20 b(e\013ects)h(of)f(the)h(substrate)f(w)n(e)g(coupled)g(a)h(surface)e (oscillator)-150 4264 y(with)28 b(co)r(ordinate)f Fj(s)g Fr(to)h(the)g(molecular)e(p)r(oten)n(tials)h(via)112 4453 y Fj(V)179 4419 y Fi(i)160 4474 y Fq(N+)p Fi(osc)358 4453 y Fr(\()p Fj(s;)14 b(z)t(;)g(X)7 b Fr(\))49 b(=)h Fj(V)884 4419 y Fi(i)866 4474 y Fq(N)919 4453 y Fr(\()p Fj(z)22 b Ff(\000)c Fj(s;)c(X)7 b Fr(\))18 b(+)g Fj(V)1428 4465 y Fq(o)p Fi(sc)1527 4453 y Fr(\()p Fj(s)p Fr(\))115 b(\(11\))403 4623 y Fj(V)451 4635 y Fq(o)p Fi(sc)550 4623 y Fr(\()p Fj(s)p Fr(\))50 b(=)827 4567 y(1)p 827 4604 42 4 v 827 4680 a(2)879 4623 y Fj(m)952 4635 y Fq(o)p Fi(sc)1073 4623 y Fj(!)1128 4589 y Fq(2)1125 4644 y(o)p Fi(sc)1246 4623 y Fj(s)1285 4589 y Fq(2)1350 4623 y Fj(;)372 b Fr(\(12\))-150 4840 y(where)37 b Fj(X)44 b Fr(stands)37 b(for)g(all)g(other)g(co)r(ordinates,)i(and)e(the)h(up-)-150 4936 y(p)r(er)28 b(index)g Fj(i)g Fr(is)g(either)h Fj(g)h Fr(or)e Fj(e)p Fr(,)g(indicating)g(the)h(ground)e(or)g(the)-150 5031 y(excited)k(state,)g(resp)r(ectiv)n(ely)-7 b(.)45 b(The)30 b(mass)g(of)h(the)g(oscillator)e(is)-150 5127 y(tak)n(en)18 b(equal)h(to)g(the)g(mass)g(of)g(a)f(Ni)i(atom)e(\(58)h (am)n(u\))g(since)g(NO)g(is)-150 5222 y(adsorb)r(ed)29 b(on)h(top)h(of)f(a)g(Ni)g(atom.)45 b(The)30 b(oscillator)f(frequency) -150 5318 y(has)36 b(b)r(een)i(c)n(hosen)e(to)h(corresp)r(ond)e(to)i (the)g(a)n(v)n(erage)e(v)-5 b(alue)36 b(of)-150 5413 y(a)g(Deb)n(y)n(e)g(sp)r(ectrum,)i(as)e(it)h(is)f(usually)g(done)g(in)g (sim)n(ulations)2118 1157 y @beginspecial 50 @llx 50 @lly 410 @urx 302 @ury 2267 @rwi @setspecial %%BeginDocument: graphs/COMP2_Des.ps %!PS-Adobe-2.0 EPSF-2.0 %%Title: COMP2_Des.ps %%Creator: gnuplot 3.7 patchlevel 1 %%CreationDate: Tue Apr 15 17:29:12 2003 %%DocumentFonts: (atend) %%BoundingBox: 50 50 410 302 %%Orientation: Portrait %%EndComments /gnudict 256 dict def gnudict begin /Color false def /Solid false def /gnulinewidth 5.000 def /userlinewidth gnulinewidth def /vshift -80 def /dl {10 mul} def /hpt_ 31.5 def /vpt_ 31.5 def /hpt hpt_ def /vpt vpt_ def /reencodeISO { dup dup findfont dup length dict begin { 1 index /FID ne { def }{ pop pop } ifelse } forall currentdict /CharStrings known { CharStrings /Idieresis known { /Encoding ISOLatin1Encoding def } if } if currentdict end definefont } def /ISOLatin1Encoding [ /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /space/exclam/quotedbl/numbersign/dollar/percent/ampersand/quoteright /parenleft/parenright/asterisk/plus/comma/minus/period/slash /zero/one/two/three/four/five/six/seven/eight/nine/colon/semicolon /less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N /O/P/Q/R/S/T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright /asciicircum/underscore/quoteleft/a/b/c/d/e/f/g/h/i/j/k/l/m /n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright/asciitilde /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/dotlessi/grave/acute/circumflex/tilde/macron/breve /dotaccent/dieresis/.notdef/ring/cedilla/.notdef/hungarumlaut /ogonek/caron/space/exclamdown/cent/sterling/currency/yen/brokenbar /section/dieresis/copyright/ordfeminine/guillemotleft/logicalnot /hyphen/registered/macron/degree/plusminus/twosuperior/threesuperior /acute/mu/paragraph/periodcentered/cedilla/onesuperior/ordmasculine /guillemotright/onequarter/onehalf/threequarters/questiondown /Agrave/Aacute/Acircumflex/Atilde/Adieresis/Aring/AE/Ccedilla /Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute/Icircumflex /Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute /Thorn/germandbls/agrave/aacute/acircumflex/atilde/adieresis /aring/ae/ccedilla/egrave/eacute/ecircumflex/edieresis/igrave /iacute/icircumflex/idieresis/eth/ntilde/ograve/oacute/ocircumflex /otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex/udieresis /yacute/thorn/ydieresis ] def /M {moveto} bind def /L {lineto} bind def /R {rmoveto} bind def /V {rlineto} bind def /vpt2 vpt 2 mul def /hpt2 hpt 2 mul def /Lshow { currentpoint stroke M 0 vshift R show } def /Rshow { currentpoint stroke M dup stringwidth pop neg vshift R show } def /Cshow { currentpoint stroke M dup stringwidth pop -2 div vshift R show } def /UP { dup vpt_ mul /vpt exch def hpt_ mul /hpt exch def /hpt2 hpt 2 mul def /vpt2 vpt 2 mul def } def /DL { Color {setrgbcolor Solid {pop []} if 0 setdash } {pop pop pop Solid {pop []} if 0 setdash} ifelse } def /BL { stroke userlinewidth 2 mul setlinewidth } def /AL { stroke userlinewidth 2 div setlinewidth } def /UL { dup gnulinewidth mul /userlinewidth exch def 10 mul /udl exch def } def /PL { stroke userlinewidth setlinewidth } def /LTb { BL [] 0 0 0 DL } def /LTa { AL [1 udl mul 2 udl mul] 0 setdash 0 0 0 setrgbcolor } def /LT0 { PL [] 1 0 0 DL } def /LT1 { PL [4 dl 2 dl] 0 1 0 DL } def /LT2 { PL [2 dl 3 dl] 0 0 1 DL } def /LT3 { PL [1 dl 1.5 dl] 1 0 1 DL } def /LT4 { PL [5 dl 2 dl 1 dl 2 dl] 0 1 1 DL } def /LT5 { PL [4 dl 3 dl 1 dl 3 dl] 1 1 0 DL } def /LT6 { PL [2 dl 2 dl 2 dl 4 dl] 0 0 0 DL } def /LT7 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 1 0.3 0 DL } def /LT8 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 0.5 0.5 0.5 DL } def /Pnt { stroke [] 0 setdash gsave 1 setlinecap M 0 0 V stroke grestore } def /Dia { stroke [] 0 setdash 2 copy vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke Pnt } def /Pls { stroke [] 0 setdash vpt sub M 0 vpt2 V currentpoint stroke M hpt neg vpt neg R hpt2 0 V stroke } def /Box { stroke [] 0 setdash 2 copy exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke Pnt } def /Crs { stroke [] 0 setdash exch hpt sub exch vpt add M hpt2 vpt2 neg V currentpoint stroke M hpt2 neg 0 R hpt2 vpt2 V stroke } def /TriU { stroke [] 0 setdash 2 copy vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke Pnt } def /Star { 2 copy Pls Crs } def /BoxF { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath fill } def /TriUF { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath fill } def /TriD { stroke [] 0 setdash 2 copy vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke Pnt } def /TriDF { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath fill} def /DiaF { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath fill } def /Pent { stroke [] 0 setdash 2 copy gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore Pnt } def /PentF { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath fill grestore } def /Circle { stroke [] 0 setdash 2 copy hpt 0 360 arc stroke Pnt } def /CircleF { stroke [] 0 setdash hpt 0 360 arc fill } def /C0 { BL [] 0 setdash 2 copy moveto vpt 90 450 arc } bind def /C1 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill vpt 0 360 arc closepath } bind def /C2 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C3 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill vpt 0 360 arc closepath } bind def /C4 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc closepath } bind def /C5 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc } bind def /C6 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 270 arc closepath fill vpt 0 360 arc closepath } bind def /C7 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 270 arc closepath fill vpt 0 360 arc closepath } bind def /C8 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C9 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 450 arc closepath fill vpt 0 360 arc closepath } bind def /C10 { BL [] 0 setdash 2 copy 2 copy moveto vpt 270 360 arc closepath fill 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C11 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C12 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C13 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C14 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 360 arc closepath fill vpt 0 360 arc } bind def /C15 { BL [] 0 setdash 2 copy vpt 0 360 arc closepath fill vpt 0 360 arc closepath } bind def /Rec { newpath 4 2 roll moveto 1 index 0 rlineto 0 exch rlineto neg 0 rlineto closepath } bind def /Square { dup Rec } bind def /Bsquare { vpt sub exch vpt sub exch vpt2 Square } bind def /S0 { BL [] 0 setdash 2 copy moveto 0 vpt rlineto BL Bsquare } bind def /S1 { BL [] 0 setdash 2 copy vpt Square fill Bsquare } bind def /S2 { BL [] 0 setdash 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S3 { BL [] 0 setdash 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S4 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S5 { BL [] 0 setdash 2 copy 2 copy vpt Square fill exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S6 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill Bsquare } bind def /S7 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill 2 copy vpt Square fill Bsquare } bind def /S8 { BL [] 0 setdash 2 copy vpt sub vpt Square fill Bsquare } bind def /S9 { BL [] 0 setdash 2 copy vpt sub vpt vpt2 Rec fill Bsquare } bind def /S10 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S11 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S12 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill Bsquare } bind def /S13 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy vpt Square fill Bsquare } bind def /S14 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S15 { BL [] 0 setdash 2 copy Bsquare fill Bsquare } bind def /D0 { gsave translate 45 rotate 0 0 S0 stroke grestore } bind def /D1 { gsave translate 45 rotate 0 0 S1 stroke grestore } bind def /D2 { gsave translate 45 rotate 0 0 S2 stroke grestore } bind def /D3 { gsave translate 45 rotate 0 0 S3 stroke grestore } bind def /D4 { gsave translate 45 rotate 0 0 S4 stroke grestore } bind def /D5 { gsave translate 45 rotate 0 0 S5 stroke grestore } bind def /D6 { gsave translate 45 rotate 0 0 S6 stroke grestore } bind def /D7 { gsave translate 45 rotate 0 0 S7 stroke grestore } bind def /D8 { gsave translate 45 rotate 0 0 S8 stroke grestore } bind def /D9 { gsave translate 45 rotate 0 0 S9 stroke grestore } bind def /D10 { gsave translate 45 rotate 0 0 S10 stroke grestore } bind def /D11 { gsave translate 45 rotate 0 0 S11 stroke grestore } bind def /D12 { gsave translate 45 rotate 0 0 S12 stroke grestore } bind def /D13 { gsave translate 45 rotate 0 0 S13 stroke grestore } bind def /D14 { gsave translate 45 rotate 0 0 S14 stroke grestore } bind def /D15 { gsave translate 45 rotate 0 0 S15 stroke grestore } bind def /DiaE { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke } def /BoxE { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke } def /TriUE { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke } def /TriDE { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke } def /PentE { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore } def /CircE { stroke [] 0 setdash hpt 0 360 arc stroke } def /Opaque { gsave closepath 1 setgray fill grestore 0 setgray closepath } def /DiaW { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V Opaque stroke } def /BoxW { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V Opaque stroke } def /TriUW { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V Opaque stroke } def /TriDW { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V Opaque stroke } def /PentW { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat Opaque stroke grestore } def /CircW { stroke [] 0 setdash hpt 0 360 arc Opaque stroke } def /BoxFill { gsave Rec 1 setgray fill grestore } def /Symbol-Oblique /Symbol findfont [1 0 .167 1 0 0] makefont dup length dict begin {1 index /FID eq {pop pop} {def} ifelse} forall currentdict end definefont /Helvetica reencodeISO def /MFshow {{dup dup 0 get findfont exch 1 get scalefont setfont [ currentpoint ] exch dup 2 get 0 exch rmoveto dup dup 5 get exch 4 get {show} {stringwidth pop 0 rmoveto}ifelse dup 3 get {2 get neg 0 exch rmoveto pop} {pop aload pop moveto}ifelse} forall} bind def /MFwidth {0 exch {dup 3 get{dup dup 0 get findfont exch 1 get scalefont setfont 5 get stringwidth pop add} {pop} ifelse} forall} bind def /MLshow { currentpoint stroke M 0 exch R MFshow } bind def /MRshow { currentpoint stroke M exch dup MFwidth neg 3 -1 roll R MFshow } def /MCshow { currentpoint stroke M exch dup MFwidth -2 div 3 -1 roll R MFshow } def end %%EndProlog gnudict begin gsave 50 50 translate 0.050 0.050 scale 0 setgray newpath (Helvetica) findfont 240 scalefont setfont 1.000 UL LTb 1416 3975 M 63 0 V 5313 0 R -63 0 V stroke 1272 3975 M [ [(Helvetica) 240.0 0.0 true true (10)] [(Helvetica) 192.0 120.0 true true (-6)] ] -104.0 MRshow 1416 2348 M 63 0 V 5313 0 R -63 0 V stroke 1272 2348 M [ [(Helvetica) 240.0 0.0 true true (10)] [(Helvetica) 192.0 120.0 true true (-7)] ] -104.0 MRshow 1416 720 M 63 0 V 5313 0 R -63 0 V stroke 1272 720 M [ [(Helvetica) 240.0 0.0 true true (10)] [(Helvetica) 192.0 120.0 true true (-8)] ] -104.0 MRshow 1416 720 M 0 63 V 0 3969 R 0 -63 V stroke 1416 480 M [ [(Helvetica) 240.0 0.0 true true (0)] ] -80.0 MCshow 2312 720 M 0 63 V 0 3969 R 0 -63 V stroke 2312 480 M [ [(Helvetica) 240.0 0.0 true true (2)] ] -80.0 MCshow 3208 720 M 0 63 V 0 3969 R 0 -63 V stroke 3208 480 M [ [(Helvetica) 240.0 0.0 true true (4)] ] -80.0 MCshow 4104 720 M 0 63 V 0 3969 R 0 -63 V stroke 4104 480 M [ [(Helvetica) 240.0 0.0 true true (6)] ] -80.0 MCshow 5000 720 M 0 63 V 0 3969 R 0 -63 V stroke 5000 480 M [ [(Helvetica) 240.0 0.0 true true (8)] ] -80.0 MCshow 5896 720 M 0 63 V 0 3969 R 0 -63 V stroke 5896 480 M [ [(Helvetica) 240.0 0.0 true true (10)] ] -80.0 MCshow 6792 720 M 0 63 V 0 3969 R 0 -63 V stroke 6792 480 M [ [(Helvetica) 240.0 0.0 true true (12)] ] -80.0 MCshow 1.000 UL LTb 1416 720 M 5376 0 V 0 4032 V -5376 0 V 0 -4032 V stroke 480 2736 M currentpoint gsave translate 90 rotate 0 0 moveto [ [(Helvetica) 240.0 0.0 true true (Rate \(1/fs\))] ] -80.0 MCshow grestore 4104 120 M [ [(Helvetica) 240.0 0.0 true true (Runtime \(ps\))] ] -80.0 MCshow 4.000 UL LT0 5752 4391 M [ [(Helvetica) 240.0 0.0 true true (2D)] ] -80.0 MRshow 5896 4391 M 351 0 V 1552 720 M 16 1350 V 21 1447 V 22 832 V 22 283 V 21 5 V 22 -128 V 22 -170 V 21 -192 V 22 -196 V 22 -215 V 21 -456 V 22 -1299 V 22 -865 V 21 -211 V 14 -185 V 85 0 R 10 619 V 22 540 V 21 507 V 22 227 V 22 74 V 21 42 V 22 -49 V 22 -107 V 21 -111 V 22 74 V 22 62 V 21 -87 V 22 171 V 22 -146 V 21 -36 V 22 -152 V 22 17 V 21 -17 V 22 54 V 22 101 V 21 -32 V 22 -156 V 22 57 V 21 -53 V 22 -133 V 22 67 V 21 16 V 22 -4 V 22 24 V 21 -99 V 22 106 V 22 -142 V 21 58 V 22 -44 V 22 -10 V 21 41 V 22 21 V 22 -100 V 21 133 V 22 -20 V 22 -34 V 21 -59 V 22 -60 V 22 144 V 22 -128 V 21 72 V 22 -5 V 22 -28 V 21 -178 V 22 139 V 22 -21 V 21 -65 V 22 -125 V 22 147 V 21 -63 V 22 -25 V 22 -19 V 21 186 V 22 -161 V 22 -159 V 21 60 V 22 141 V 22 -54 V 21 -53 V 22 -49 V 22 0 V 21 -77 V 22 -68 V 22 18 V 21 74 V 22 -83 V 22 99 V 21 -56 V 22 -9 V 22 247 V 21 -152 V 22 -213 V 22 213 V 21 -95 V 22 41 V 22 -66 V 21 -27 V 22 35 V 22 -72 V 21 72 V 22 -44 V 22 -88 V 22 21 V 21 -21 V 22 -21 V 22 71 V 21 0 V 22 156 V 22 -137 V 21 -48 V 22 153 V 22 -206 V 21 -11 V 22 83 V 22 -72 V 21 138 V 22 -183 V 22 45 V 21 -45 V 22 -23 V 22 35 V 21 11 V 22 -58 V 22 -120 V 21 -60 V 22 129 V 22 120 V 21 -203 V 22 296 V 22 -40 V 21 -53 V 22 -82 V 22 48 V 21 -86 V 22 -178 V 22 298 V 21 -120 V 22 184 V 22 -362 V 21 138 V 22 -73 V 22 -82 V 21 -175 V 22 301 V 22 56 V 22 -314 V 21 469 V 22 -390 V 22 103 V 21 0 V 22 -103 V 22 119 V 21 155 V 22 -171 V 22 -103 V 21 -167 V 22 361 V 22 -75 V 21 16 V 22 -235 V 22 187 V 21 174 V 22 -142 V 22 -49 V 21 -34 V 22 67 V 22 -122 V 21 72 V 22 -72 V 22 106 V 21 -69 V 22 18 V 22 34 V 21 33 V 22 -270 V 22 203 V 21 -74 V 22 -41 V 22 149 V 21 -490 V 22 401 V 22 19 V 21 0 V 22 -38 V 22 -106 V 21 144 V 22 -191 V 22 112 V 21 97 V 22 -97 V 22 115 V 22 -136 V 21 -196 V 22 80 V 22 -139 V 21 233 V 22 -69 V 22 -263 V 21 263 V 22 -134 V 22 306 V 21 -39 V 20 -396 V 4 0 R 20 435 V 21 -368 V 22 171 V 22 -204 V 21 0 V 22 341 V 14 -375 V 18 0 R 11 238 V 22 -109 V 22 109 V 21 49 V 22 -102 V 18 -185 V 10 0 R 15 99 V 22 0 V 22 139 V 21 137 V 22 -276 V 22 86 V 21 102 V 22 45 V 20 -332 V 5 0 R 18 238 V 19 -238 V 6 0 R 19 212 V 21 26 V 22 0 V 13 -238 V 22 0 R 8 99 V 22 0 V 22 -32 V 22 145 V 21 -83 V 22 -62 V 14 -67 V 5.000 UL LT6 5752 4151 M [ [(Helvetica) 240.0 0.0 true true (7D)] ] -80.0 MRshow 5896 4151 M 351 0 V 1619 720 M 14 416 V 27 226 V 27 -226 V 27 -33 V 27 -33 V 27 -54 V 27 368 V 27 323 V 27 251 V 28 409 V 27 515 V 27 279 V 27 45 V 27 -43 V 27 -65 V 27 -36 V 27 -41 V 27 -75 V 27 -13 V 28 -10 V 27 -3 V 27 -75 V 27 43 V 27 -8 V 27 -39 V 27 -46 V 27 -38 V 27 -24 V 27 68 V 27 -118 V 28 23 V 27 -31 V 27 8 V 27 -32 V 27 29 V 27 -44 V 27 -123 V 27 114 V 27 -14 V 27 -8 V 27 -55 V 28 -55 V 27 32 V 27 32 V 27 -102 V 27 -9 V 27 36 V 27 -10 V 27 -31 V 27 -76 V 27 3 V 27 -109 V 28 120 V 27 -59 V 27 -88 V 27 108 V 27 20 V 27 -92 V 27 -13 V 27 -16 V 27 -23 V 27 -21 V 27 44 V 28 -118 V 27 101 V 27 -10 V 27 -110 V 27 79 V 27 -41 V 27 69 V 27 -140 V 27 21 V 27 23 V 28 42 V 27 -61 V 27 -29 V 27 -62 V 27 57 V 27 57 V 27 -27 V 27 -78 V 27 -23 V 27 -9 V 27 -39 V 28 71 V 27 -13 V 27 9 V 27 -147 V 27 114 V 27 -44 V 27 25 V 27 -89 V 27 -102 V 27 102 V 27 59 V 28 -5 V 27 -112 V 27 35 V 27 -35 V 27 -50 V 27 135 V 27 -50 V 27 -5 V 27 -120 V 27 142 V 27 -109 V 28 -6 V 27 32 V 27 -32 V 27 -34 V 27 53 V 27 -39 V 27 71 V 27 -99 V 27 48 V 27 -77 V 28 -38 V 27 108 V 27 -148 V 27 40 V 27 108 V 27 33 V 27 -149 V 27 116 V 27 -173 V 27 25 V 27 -33 V 28 -45 V 27 9 V 27 -27 V 27 80 V 27 -35 V 27 0 V 27 -158 V 27 209 V 27 -135 V 27 29 V 27 -125 V 28 180 V 27 -55 V 27 -9 V 27 -83 V 27 147 V 27 -239 V 27 114 V 27 -11 V 27 -33 V 27 33 V 27 0 V 28 -168 V 27 52 V 27 148 V 27 -76 V 27 153 V 27 -176 V 27 158 V 27 -146 V 27 11 V 27 -124 V 27 146 V 28 -33 V 27 -87 V 27 -13 V 27 52 V 27 -13 V 27 83 V 27 -122 V 27 52 V 27 -152 V 27 126 V 28 -81 V 27 42 V 27 -28 V 27 -107 V 27 200 V 27 -233 V 27 194 V 27 -161 V 27 121 V 27 53 V 27 -280 V 28 154 V 27 59 V 27 -158 V 27 144 V 27 -144 V 27 129 V 27 -147 V 27 86 V 27 -104 V 27 36 V 12 22 V stroke grestore end showpage %%Trailer %%DocumentFonts: Helvetica %%EndDocument @endspecial 2042 1327 a Fn(FIG.)29 b(2:)42 b(Desorption)29 b(rate)h(as)g(a)f(function)g(of)h(time)e(\(excitation)i(at)2042 1414 y(time)23 b Fb(t)e Fn(=)g(0\))j(in)f(the)h(t)n(w)n(o-dimensional)g (\(solid)g(line\))g(and)g(the)f(sev)n(en-)2042 1501 y(dimensional)33 b(sim)n(ulations)g(\(dash-dotted)f(line\).)57 b(The)33 b(2D)g(results)2042 1589 y(ha)n(v)n(e)26 b(b)r(een)g(obtained)g(with)h (a)g(cuto\013)f(distance)h(of)g Fb(z)3599 1597 y Fp(CO)3715 1589 y Fn(=)c(12)p Fb(:)p Fn(5)k(a.u.)2042 1676 y(while)22 b(in)g(the)f(7D)h(calculations)h Fb(z)3021 1684 y Fp(CO)3137 1676 y Fn(=)e(16)p Fb(:)p Fn(0)i(a.u.)33 b(has)22 b(b)r(een)g(c)n (hosen.)2042 1953 y Fr(using)29 b(the)i(surface)e(oscillator)f(mo)r (del)i([24)o(].)44 b(The)30 b(Deb)n(y)n(e)g(tem-)2042 2048 y(p)r(erature)j(of)g(NiO)g(has)g(b)r(een)h(estimated)g(to)f(b)r(e) h(b)r(et)n(w)n(een)g(500)2042 2144 y(and)e(600)f(K)h([25].)51 b(Accordingly)-7 b(,)33 b(w)n(e)f(ha)n(v)n(e)g(set)g(the)h(oscillator) 2042 2239 y(frequency)k(to)h Fe(~)p Fj(!)k Fr(=)e(27)d(meV.)h(An)n(yw)n (a)n(y)-7 b(,)40 b(the)e(e\013ect)g(of)g(the)2042 2335 y(surface)25 b(oscillator)g(on)h(the)g(desorption)f(dynamics)h(is)g (not)g(v)n(ery)2042 2430 y(sensitiv)n(e)e(to)h(the)g(particular)e(c)n (hoice)h(of)h(the)g(frequency)-7 b(.)36 b(In)25 b(the)2042 2526 y(follo)n(wing)e(w)n(e)g(will)h(rep)r(ort)f(results)h(of)g(2D)f (and)h(6D)g(sim)n(ulations)2042 2621 y(without)31 b(and)f(with)h(the)g (surface)f(oscillator,)f(denoted)i(b)n(y)f(2D,)2042 2716 y(3D,)d(6D,)h(or)f(7D)g(calculations,)g(resp)r(ectiv)n(ely)-7 b(.)2349 3001 y Fl(I)r(I)r(I.)90 b(RESUL)-7 b(TS)29 b(AND)g(DISCUSSION) 2125 3216 y Fr(In)22 b(order)e(to)h(v)-5 b(alidate)22 b(our)f(metho)r(d,)i(w)n(e)e(\014rst)h(tried)f(to)h(repro-)2042 3311 y(duce)30 b(the)h(t)n(w)n(o-dimensional)e(w)n(a)n(v)n(e)g(pac)n(k) n(et)g(results)h(of)h(Kl)r(\177)-44 b(uner)2042 3407 y(et)38 b(al.)69 b([17)o(])38 b(using)g(exactly)g(the)g(same)g(p)r (oten)n(tial.)69 b(W)-7 b(e)39 b(p)r(er-)2042 3502 y(formed)44 b(b)r(oth)h(classical)f(sim)n(ulations)f(within)j(the)f(Gadzuk-)2042 3598 y(Sc)n(heme)30 b(with)g(the)h(same)f(a)n(v)n(erage)d(residence)i (time)i(of)f(24)p Fj(:)p Fr(19fs)2042 3693 y(\(=)39 b(1000)d(a.u.\))67 b(as)37 b(used)g(in)h(the)g(w)n(a)n(v)n(e-pac)n(k)n(et)c(calculations) 2042 3788 y(as)26 b(w)n(ell)h(as)f(our)g(prop)r(osed)g(mixed)i(quan)n (tum-classical)d(sc)n(heme)2042 3884 y(with)k(the)g(corresp)r(onding)e (constan)n(t)g(optical)i(p)r(oten)n(tial.)39 b(Both)2042 3979 y(t)n(yp)r(es)26 b(of)h(sim)n(ulations)f(treat)g(the)i(n)n(uclear) d(motion)i(classically;)2042 4075 y(in)47 b(fact,)k(they)c(yielded)f (iden)n(tical)h(results)f(for)g(the)h(desorp-)2042 4170 y(tion)26 b(probabilities)g(within)h(the)g(n)n(umerical)f(accuracy)-7 b(,)25 b(as)h(they)2042 4266 y(should.)67 b(Ho)n(w)n(ev)n(er,)38 b(the)g(mixed)g(quan)n(tum-classical)e(sc)n(heme)2042 4361 y(with)22 b(the)h(optical)f(p)r(oten)n(tial)g(is)g(conceptual)f (simpler)h(and)g(more)2042 4457 y(\015exible)h(than)g(the)g(Gadzuk)g (sc)n(heme)f(since)h(it)g(do)r(es)f(not)h(require)2042 4552 y(a)n(v)n(eraging)42 b(o)n(v)n(er)h(di\013eren)n(t)j(residence)e (times)i(and)f(it)h(allo)n(ws)2042 4648 y(mo)r(deling)27 b(of)h(spatially)f(non-constan)n(t)f(deexcitation)h(rates.)2125 4745 y(As)32 b(for)g(the)h(comparison)e(with)i(the)g(jumping)g(w)n(a)n (v)n(e-pac)n(k)n(et)2042 4840 y(calculations,)48 b(w)n(e)c(obtained)h (a)f(larger)f(desorption)g(yield)i(of)2042 4936 y(4)p Fj(:)p Fr(8\045)52 b(compared)g(to)g(3)p Fj(:)p Fr(3\045)g(in)h(the)h (w)n(a)n(v)n(e-pac)n(k)n(et)49 b(calcula-)2042 5031 y(tions)32 b([17)o(].)53 b(This)33 b(w)n(as)f(puzzling)g(as)g(w)n(e)h(exp)r(ected) g(the)g(w)n(a)n(v)n(e-)2042 5127 y(pac)n(k)n(et)41 b(calculations)g(to) h(giv)n(e)g(a)f(higher)h(yield)g(due)h(to)f(des-)2042 5222 y(orption)34 b(from)h(the)h(classically)e(forbidden)h(tails)g(of)g (the)h(w)n(a)n(v)n(e)2042 5318 y(function.)60 b(Closer)34 b(examination)g(of)i(the)f(desorption)f(rate)h(as)2042 5413 y(a)28 b(function)h(of)g(time)g(help)r(ed)g(to)g(resolv)n(e)d (this)j(discrepancy)-7 b(.)39 b(In)p eop %%Page: 4 4 4 3 bop 4043 -299 a Fr(4)-127 1487 y @beginspecial 50 @llx 50 @lly 230 @urx 352 @ury 1984 @rhi @setspecial %%BeginDocument: graphs/2D_CO125_VDist_early.eps %!PS-Adobe-2.0 EPSF-2.0 %%Title: EPS/2D_CO125_VDist_early.eps %%Creator: gnuplot 3.7 patchlevel 1 %%CreationDate: Tue Apr 15 17:03:30 2003 %%DocumentFonts: (atend) %%BoundingBox: 50 50 230 352 %%Orientation: Portrait %%EndComments /gnudict 256 dict def gnudict begin /Color false def /Solid false def /gnulinewidth 5.000 def /userlinewidth gnulinewidth def /vshift -80 def /dl {10 mul} def /hpt_ 31.5 def /vpt_ 31.5 def /hpt hpt_ def /vpt vpt_ def /reencodeISO { dup dup findfont dup length dict begin { 1 index /FID ne { def }{ pop pop } ifelse } forall currentdict /CharStrings known { CharStrings /Idieresis known { /Encoding ISOLatin1Encoding def } if } if currentdict end definefont } def /ISOLatin1Encoding [ /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /space/exclam/quotedbl/numbersign/dollar/percent/ampersand/quoteright /parenleft/parenright/asterisk/plus/comma/minus/period/slash /zero/one/two/three/four/five/six/seven/eight/nine/colon/semicolon /less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N /O/P/Q/R/S/T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright /asciicircum/underscore/quoteleft/a/b/c/d/e/f/g/h/i/j/k/l/m /n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright/asciitilde /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/dotlessi/grave/acute/circumflex/tilde/macron/breve /dotaccent/dieresis/.notdef/ring/cedilla/.notdef/hungarumlaut /ogonek/caron/space/exclamdown/cent/sterling/currency/yen/brokenbar /section/dieresis/copyright/ordfeminine/guillemotleft/logicalnot /hyphen/registered/macron/degree/plusminus/twosuperior/threesuperior /acute/mu/paragraph/periodcentered/cedilla/onesuperior/ordmasculine /guillemotright/onequarter/onehalf/threequarters/questiondown /Agrave/Aacute/Acircumflex/Atilde/Adieresis/Aring/AE/Ccedilla /Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute/Icircumflex /Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute /Thorn/germandbls/agrave/aacute/acircumflex/atilde/adieresis /aring/ae/ccedilla/egrave/eacute/ecircumflex/edieresis/igrave /iacute/icircumflex/idieresis/eth/ntilde/ograve/oacute/ocircumflex /otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex/udieresis /yacute/thorn/ydieresis ] def /M {moveto} bind def /L {lineto} bind def /R {rmoveto} bind def /V {rlineto} bind def /vpt2 vpt 2 mul def /hpt2 hpt 2 mul def /Lshow { currentpoint stroke M 0 vshift R show } def /Rshow { currentpoint stroke M dup stringwidth pop neg vshift R show } def /Cshow { currentpoint stroke M dup stringwidth pop -2 div vshift R show } def /UP { dup vpt_ mul /vpt exch def hpt_ mul /hpt exch def /hpt2 hpt 2 mul def /vpt2 vpt 2 mul def } def /DL { Color {setrgbcolor Solid {pop []} if 0 setdash } {pop pop pop Solid {pop []} if 0 setdash} ifelse } def /BL { stroke userlinewidth 2 mul setlinewidth } def /AL { stroke userlinewidth 2 div setlinewidth } def /UL { dup gnulinewidth mul /userlinewidth exch def 10 mul /udl exch def } def /PL { stroke userlinewidth setlinewidth } def /LTb { BL [] 0 0 0 DL } def /LTa { AL [1 udl mul 2 udl mul] 0 setdash 0 0 0 setrgbcolor } def /LT0 { PL [] 1 0 0 DL } def /LT1 { PL [4 dl 2 dl] 0 1 0 DL } def /LT2 { PL [2 dl 3 dl] 0 0 1 DL } def /LT3 { PL [1 dl 1.5 dl] 1 0 1 DL } def /LT4 { PL [5 dl 2 dl 1 dl 2 dl] 0 1 1 DL } def /LT5 { PL [4 dl 3 dl 1 dl 3 dl] 1 1 0 DL } def /LT6 { PL [2 dl 2 dl 2 dl 4 dl] 0 0 0 DL } def /LT7 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 1 0.3 0 DL } def /LT8 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 0.5 0.5 0.5 DL } def /Pnt { stroke [] 0 setdash gsave 1 setlinecap M 0 0 V stroke grestore } def /Dia { stroke [] 0 setdash 2 copy vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke Pnt } def /Pls { stroke [] 0 setdash vpt sub M 0 vpt2 V currentpoint stroke M hpt neg vpt neg R hpt2 0 V stroke } def /Box { stroke [] 0 setdash 2 copy exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke Pnt } def /Crs { stroke [] 0 setdash exch hpt sub exch vpt add M hpt2 vpt2 neg V currentpoint stroke M hpt2 neg 0 R hpt2 vpt2 V stroke } def /TriU { stroke [] 0 setdash 2 copy vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke Pnt } def /Star { 2 copy Pls Crs } def /BoxF { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath fill } def /TriUF { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath fill } def /TriD { stroke [] 0 setdash 2 copy vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke Pnt } def /TriDF { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath fill} def /DiaF { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath fill } def /Pent { stroke [] 0 setdash 2 copy gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore Pnt } def /PentF { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath fill grestore } def /Circle { stroke [] 0 setdash 2 copy hpt 0 360 arc stroke Pnt } def /CircleF { stroke [] 0 setdash hpt 0 360 arc fill } def /C0 { BL [] 0 setdash 2 copy moveto vpt 90 450 arc } bind def /C1 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill vpt 0 360 arc closepath } bind def /C2 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C3 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill vpt 0 360 arc closepath } bind def /C4 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc closepath } bind def /C5 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc } bind def /C6 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 270 arc closepath fill vpt 0 360 arc closepath } bind def /C7 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 270 arc closepath fill vpt 0 360 arc closepath } bind def /C8 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C9 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 450 arc closepath fill vpt 0 360 arc closepath } bind def /C10 { BL [] 0 setdash 2 copy 2 copy moveto vpt 270 360 arc closepath fill 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C11 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C12 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C13 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C14 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 360 arc closepath fill vpt 0 360 arc } bind def /C15 { BL [] 0 setdash 2 copy vpt 0 360 arc closepath fill vpt 0 360 arc closepath } bind def /Rec { newpath 4 2 roll moveto 1 index 0 rlineto 0 exch rlineto neg 0 rlineto closepath } bind def /Square { dup Rec } bind def /Bsquare { vpt sub exch vpt sub exch vpt2 Square } bind def /S0 { BL [] 0 setdash 2 copy moveto 0 vpt rlineto BL Bsquare } bind def /S1 { BL [] 0 setdash 2 copy vpt Square fill Bsquare } bind def /S2 { BL [] 0 setdash 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S3 { BL [] 0 setdash 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S4 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S5 { BL [] 0 setdash 2 copy 2 copy vpt Square fill exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S6 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill Bsquare } bind def /S7 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill 2 copy vpt Square fill Bsquare } bind def /S8 { BL [] 0 setdash 2 copy vpt sub vpt Square fill Bsquare } bind def /S9 { BL [] 0 setdash 2 copy vpt sub vpt vpt2 Rec fill Bsquare } bind def /S10 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S11 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S12 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill Bsquare } bind def /S13 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy vpt Square fill Bsquare } bind def /S14 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S15 { BL [] 0 setdash 2 copy Bsquare fill Bsquare } bind def /D0 { gsave translate 45 rotate 0 0 S0 stroke grestore } bind def /D1 { gsave translate 45 rotate 0 0 S1 stroke grestore } bind def /D2 { gsave translate 45 rotate 0 0 S2 stroke grestore } bind def /D3 { gsave translate 45 rotate 0 0 S3 stroke grestore } bind def /D4 { gsave translate 45 rotate 0 0 S4 stroke grestore } bind def /D5 { gsave translate 45 rotate 0 0 S5 stroke grestore } bind def /D6 { gsave translate 45 rotate 0 0 S6 stroke grestore } bind def /D7 { gsave translate 45 rotate 0 0 S7 stroke grestore } bind def /D8 { gsave translate 45 rotate 0 0 S8 stroke grestore } bind def /D9 { gsave translate 45 rotate 0 0 S9 stroke grestore } bind def /D10 { gsave translate 45 rotate 0 0 S10 stroke grestore } bind def /D11 { gsave translate 45 rotate 0 0 S11 stroke grestore } bind def /D12 { gsave translate 45 rotate 0 0 S12 stroke grestore } bind def /D13 { gsave translate 45 rotate 0 0 S13 stroke grestore } bind def /D14 { gsave translate 45 rotate 0 0 S14 stroke grestore } bind def /D15 { gsave translate 45 rotate 0 0 S15 stroke grestore } bind def /DiaE { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke } def /BoxE { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke } def /TriUE { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke } def /TriDE { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke } def /PentE { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore } def /CircE { stroke [] 0 setdash hpt 0 360 arc stroke } def /Opaque { gsave closepath 1 setgray fill grestore 0 setgray closepath } def /DiaW { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V Opaque stroke } def /BoxW { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V Opaque stroke } def /TriUW { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V Opaque stroke } def /TriDW { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V Opaque stroke } def /PentW { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat Opaque stroke grestore } def /CircW { stroke [] 0 setdash hpt 0 360 arc Opaque stroke } def /BoxFill { gsave Rec 1 setgray fill grestore } def /Symbol-Oblique /Symbol findfont [1 0 .167 1 0 0] makefont dup length dict begin {1 index /FID eq {pop pop} {def} ifelse} forall currentdict end definefont /Helvetica reencodeISO def /MFshow {{dup dup 0 get findfont exch 1 get scalefont setfont [ currentpoint ] exch dup 2 get 0 exch rmoveto dup dup 5 get exch 4 get {show} {stringwidth pop 0 rmoveto}ifelse dup 3 get {2 get neg 0 exch rmoveto pop} {pop aload pop moveto}ifelse} forall} bind def /MFwidth {0 exch {dup 3 get{dup dup 0 get findfont exch 1 get scalefont setfont 5 get stringwidth pop add} {pop} ifelse} forall} bind def /MLshow { currentpoint stroke M 0 exch R MFshow } bind def /MRshow { currentpoint stroke M exch dup MFwidth neg 3 -1 roll R MFshow } def /MCshow { currentpoint stroke M exch dup MFwidth -2 div 3 -1 roll R MFshow } def end %%EndProlog gnudict begin gsave 50 50 translate 0.050 0.050 scale 0 setgray newpath (Helvetica) findfont 240 scalefont setfont 1.000 UL LTb 480 720 M 0 31 V 0 5009 R 0 -31 V 623 720 M 0 31 V 0 5009 R 0 -31 V 765 720 M 0 31 V 0 5009 R 0 -31 V 908 720 M 0 31 V 0 5009 R 0 -31 V 1051 720 M 0 63 V 0 4977 R 0 -63 V stroke 1051 480 M [ [(Helvetica) 240.0 0.0 true true (500)] ] -80.0 MCshow 1194 720 M 0 31 V 0 5009 R 0 -31 V 1336 720 M 0 31 V 0 5009 R 0 -31 V 1479 720 M 0 31 V 0 5009 R 0 -31 V 1622 720 M 0 31 V 0 5009 R 0 -31 V 1765 720 M 0 63 V 0 4977 R 0 -63 V stroke 1765 480 M [ [(Helvetica) 240.0 0.0 true true (1000)] ] -80.0 MCshow 1907 720 M 0 31 V 0 5009 R 0 -31 V 2050 720 M 0 31 V 0 5009 R 0 -31 V 2193 720 M 0 31 V 0 5009 R 0 -31 V 2336 720 M 0 31 V 0 5009 R 0 -31 V 2478 720 M 0 63 V 0 4977 R 0 -63 V stroke 2478 480 M [ [(Helvetica) 240.0 0.0 true true (1500)] ] -80.0 MCshow 2621 720 M 0 31 V 0 5009 R 0 -31 V 2764 720 M 0 31 V 0 5009 R 0 -31 V 2907 720 M 0 31 V 0 5009 R 0 -31 V 3049 720 M 0 31 V 0 5009 R 0 -31 V 3192 720 M 0 63 V 0 4977 R 0 -63 V stroke 3192 480 M [ [(Helvetica) 240.0 0.0 true true (2000)] ] -80.0 MCshow 1.000 UL LTb 480 720 M 2712 0 V 0 5040 V -2712 0 V 480 720 L stroke 240 3240 M currentpoint gsave translate 90 rotate 0 0 moveto [ [(Helvetica) 240.0 0.0 true true (Intensity)] ] -80.0 MCshow grestore 1836 120 M [ [(Helvetica) 240.0 0.0 true true (Velocity \(m/s\))] ] -80.0 MCshow 2621 893 M [ [(Helvetica) 240.0 0.0 true true (J=4)] ] -80.0 MLshow 2621 1760 M [ [(Helvetica) 240.0 0.0 true true (J=7)] ] -80.0 MLshow 2621 2628 M [ [(Helvetica) 240.0 0.0 true true (J=9)] ] -80.0 MLshow 2621 3495 M [ [(Helvetica) 240.0 0.0 true true (J=19)] ] -80.0 MLshow 2621 4362 M [ [(Helvetica) 240.0 0.0 true true (J=32)] ] -80.0 MLshow 2621 5229 M [ [(Helvetica) 240.0 0.0 true true (J=34)] ] -80.0 MLshow 3.000 UL LT0 480 720 M 143 2 V 765 876 L 908 995 L 143 49 V 143 -5 V 142 5 V 143 -13 V 143 -48 V 143 -53 V 142 -66 V 143 -35 V 143 -36 V 142 -37 V 143 -5 V 143 -17 V 143 -5 V 142 -3 V 143 0 V 143 2 V 3.000 UL LT0 480 1587 M 143 7 V 142 193 V 143 315 V 143 110 V 143 -5 V 142 -92 V 143 -80 V 143 -104 V 143 -58 V 142 -86 V 143 -71 V 143 -52 V 142 -22 V 143 -24 V 143 -14 V 143 -7 V 142 -4 V 143 -3 V 143 5 V 3.000 UL LT0 480 2454 M 143 0 V 142 274 V 143 263 V 143 90 V 143 98 V 142 -59 V 143 -38 V 143 -121 V 143 -133 V 142 -104 V 143 -108 V 143 -54 V 142 -55 V 143 -20 V 143 -9 V 143 -13 V 142 -8 V 143 -2 V 143 3 V 3.000 UL LT0 480 3321 M 143 0 V 142 656 V 143 488 V 143 93 V 143 32 V 142 81 V 143 -83 V 143 -221 V 143 -240 V 142 -288 V 143 -205 V 143 -166 V 142 -88 V 143 -38 V 143 -12 V 143 -5 V 142 -2 V 143 -1 V 143 3 V 3.000 UL LT0 480 4188 M 143 0 V 142 43 V 143 9 V 143 120 V 143 70 V 142 279 V 143 33 V 143 401 V 143 253 V 142 364 V 143 -75 V 143 -384 V 142 -524 V 143 -354 V 143 -169 V 143 -61 V 142 -4 V 143 0 V 143 1 V 3.000 UL LT0 480 5055 M 143 0 V 142 0 V 143 74 V 143 -74 V 143 42 V 142 10 V 143 20 V 143 43 V 143 236 V 142 156 V 143 -13 V 143 37 V 142 -92 V 143 -232 V 143 -142 V 143 -52 V 142 -12 V 143 0 V 143 -1 V stroke grestore end showpage %%Trailer %%DocumentFonts: Helvetica %%EndDocument @endspecial 1011 w @beginspecial 50 @llx 50 @lly 230 @urx 352 @ury 1984 @rhi @setspecial %%BeginDocument: graphs/2D_CO125_VDist_comp.eps %!PS-Adobe-2.0 EPSF-2.0 %%Title: EPS/2D_CO125_VDist_comp.eps %%Creator: gnuplot 3.7 patchlevel 1 %%CreationDate: Tue Apr 15 17:03:30 2003 %%DocumentFonts: (atend) %%BoundingBox: 50 50 230 352 %%Orientation: Portrait %%EndComments /gnudict 256 dict def gnudict begin /Color false def /Solid false def /gnulinewidth 5.000 def /userlinewidth gnulinewidth def /vshift -80 def /dl {10 mul} def /hpt_ 31.5 def /vpt_ 31.5 def /hpt hpt_ def /vpt vpt_ def /reencodeISO { dup dup findfont dup length dict begin { 1 index /FID ne { def }{ pop pop } ifelse } forall currentdict /CharStrings known { CharStrings /Idieresis known { /Encoding ISOLatin1Encoding def } if } if currentdict end definefont } def /ISOLatin1Encoding [ /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /space/exclam/quotedbl/numbersign/dollar/percent/ampersand/quoteright /parenleft/parenright/asterisk/plus/comma/minus/period/slash /zero/one/two/three/four/five/six/seven/eight/nine/colon/semicolon /less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N /O/P/Q/R/S/T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright /asciicircum/underscore/quoteleft/a/b/c/d/e/f/g/h/i/j/k/l/m /n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright/asciitilde /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/dotlessi/grave/acute/circumflex/tilde/macron/breve /dotaccent/dieresis/.notdef/ring/cedilla/.notdef/hungarumlaut /ogonek/caron/space/exclamdown/cent/sterling/currency/yen/brokenbar /section/dieresis/copyright/ordfeminine/guillemotleft/logicalnot /hyphen/registered/macron/degree/plusminus/twosuperior/threesuperior /acute/mu/paragraph/periodcentered/cedilla/onesuperior/ordmasculine /guillemotright/onequarter/onehalf/threequarters/questiondown /Agrave/Aacute/Acircumflex/Atilde/Adieresis/Aring/AE/Ccedilla /Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute/Icircumflex /Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute /Thorn/germandbls/agrave/aacute/acircumflex/atilde/adieresis /aring/ae/ccedilla/egrave/eacute/ecircumflex/edieresis/igrave /iacute/icircumflex/idieresis/eth/ntilde/ograve/oacute/ocircumflex /otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex/udieresis /yacute/thorn/ydieresis ] def /M {moveto} bind def /L {lineto} bind def /R {rmoveto} bind def /V {rlineto} bind def /vpt2 vpt 2 mul def /hpt2 hpt 2 mul def /Lshow { currentpoint stroke M 0 vshift R show } def /Rshow { currentpoint stroke M dup stringwidth pop neg vshift R show } def /Cshow { currentpoint stroke M dup stringwidth pop -2 div vshift R show } def /UP { dup vpt_ mul /vpt exch def hpt_ mul /hpt exch def /hpt2 hpt 2 mul def /vpt2 vpt 2 mul def } def /DL { Color {setrgbcolor Solid {pop []} if 0 setdash } {pop pop pop Solid {pop []} if 0 setdash} ifelse } def /BL { stroke userlinewidth 2 mul setlinewidth } def /AL { stroke userlinewidth 2 div setlinewidth } def /UL { dup gnulinewidth mul /userlinewidth exch def 10 mul /udl exch def } def /PL { stroke userlinewidth setlinewidth } def /LTb { BL [] 0 0 0 DL } def /LTa { AL [1 udl mul 2 udl mul] 0 setdash 0 0 0 setrgbcolor } def /LT0 { PL [] 1 0 0 DL } def /LT1 { PL [4 dl 2 dl] 0 1 0 DL } def /LT2 { PL [2 dl 3 dl] 0 0 1 DL } def /LT3 { PL [1 dl 1.5 dl] 1 0 1 DL } def /LT4 { PL [5 dl 2 dl 1 dl 2 dl] 0 1 1 DL } def /LT5 { PL [4 dl 3 dl 1 dl 3 dl] 1 1 0 DL } def /LT6 { PL [2 dl 2 dl 2 dl 4 dl] 0 0 0 DL } def /LT7 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 1 0.3 0 DL } def /LT8 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 0.5 0.5 0.5 DL } def /Pnt { stroke [] 0 setdash gsave 1 setlinecap M 0 0 V stroke grestore } def /Dia { stroke [] 0 setdash 2 copy vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke Pnt } def /Pls { stroke [] 0 setdash vpt sub M 0 vpt2 V currentpoint stroke M hpt neg vpt neg R hpt2 0 V stroke } def /Box { stroke [] 0 setdash 2 copy exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke Pnt } def /Crs { stroke [] 0 setdash exch hpt sub exch vpt add M hpt2 vpt2 neg V currentpoint stroke M hpt2 neg 0 R hpt2 vpt2 V stroke } def /TriU { stroke [] 0 setdash 2 copy vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke Pnt } def /Star { 2 copy Pls Crs } def /BoxF { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath fill } def /TriUF { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath fill } def /TriD { stroke [] 0 setdash 2 copy vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke Pnt } def /TriDF { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath fill} def /DiaF { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath fill } def /Pent { stroke [] 0 setdash 2 copy gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore Pnt } def /PentF { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath fill grestore } def /Circle { stroke [] 0 setdash 2 copy hpt 0 360 arc stroke Pnt } def /CircleF { stroke [] 0 setdash hpt 0 360 arc fill } def /C0 { BL [] 0 setdash 2 copy moveto vpt 90 450 arc } bind def /C1 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill vpt 0 360 arc closepath } bind def /C2 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C3 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill vpt 0 360 arc closepath } bind def /C4 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc closepath } bind def /C5 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc } bind def /C6 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 270 arc closepath fill vpt 0 360 arc closepath } bind def /C7 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 270 arc closepath fill vpt 0 360 arc closepath } bind def /C8 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C9 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 450 arc closepath fill vpt 0 360 arc closepath } bind def /C10 { BL [] 0 setdash 2 copy 2 copy moveto vpt 270 360 arc closepath fill 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C11 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C12 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C13 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C14 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 360 arc closepath fill vpt 0 360 arc } bind def /C15 { BL [] 0 setdash 2 copy vpt 0 360 arc closepath fill vpt 0 360 arc closepath } bind def /Rec { newpath 4 2 roll moveto 1 index 0 rlineto 0 exch rlineto neg 0 rlineto closepath } bind def /Square { dup Rec } bind def /Bsquare { vpt sub exch vpt sub exch vpt2 Square } bind def /S0 { BL [] 0 setdash 2 copy moveto 0 vpt rlineto BL Bsquare } bind def /S1 { BL [] 0 setdash 2 copy vpt Square fill Bsquare } bind def /S2 { BL [] 0 setdash 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S3 { BL [] 0 setdash 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S4 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S5 { BL [] 0 setdash 2 copy 2 copy vpt Square fill exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S6 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill Bsquare } bind def /S7 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill 2 copy vpt Square fill Bsquare } bind def /S8 { BL [] 0 setdash 2 copy vpt sub vpt Square fill Bsquare } bind def /S9 { BL [] 0 setdash 2 copy vpt sub vpt vpt2 Rec fill Bsquare } bind def /S10 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S11 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S12 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill Bsquare } bind def /S13 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy vpt Square fill Bsquare } bind def /S14 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S15 { BL [] 0 setdash 2 copy Bsquare fill Bsquare } bind def /D0 { gsave translate 45 rotate 0 0 S0 stroke grestore } bind def /D1 { gsave translate 45 rotate 0 0 S1 stroke grestore } bind def /D2 { gsave translate 45 rotate 0 0 S2 stroke grestore } bind def /D3 { gsave translate 45 rotate 0 0 S3 stroke grestore } bind def /D4 { gsave translate 45 rotate 0 0 S4 stroke grestore } bind def /D5 { gsave translate 45 rotate 0 0 S5 stroke grestore } bind def /D6 { gsave translate 45 rotate 0 0 S6 stroke grestore } bind def /D7 { gsave translate 45 rotate 0 0 S7 stroke grestore } bind def /D8 { gsave translate 45 rotate 0 0 S8 stroke grestore } bind def /D9 { gsave translate 45 rotate 0 0 S9 stroke grestore } bind def /D10 { gsave translate 45 rotate 0 0 S10 stroke grestore } bind def /D11 { gsave translate 45 rotate 0 0 S11 stroke grestore } bind def /D12 { gsave translate 45 rotate 0 0 S12 stroke grestore } bind def /D13 { gsave translate 45 rotate 0 0 S13 stroke grestore } bind def /D14 { gsave translate 45 rotate 0 0 S14 stroke grestore } bind def /D15 { gsave translate 45 rotate 0 0 S15 stroke grestore } bind def /DiaE { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke } def /BoxE { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke } def /TriUE { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke } def /TriDE { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke } def /PentE { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore } def /CircE { stroke [] 0 setdash hpt 0 360 arc stroke } def /Opaque { gsave closepath 1 setgray fill grestore 0 setgray closepath } def /DiaW { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V Opaque stroke } def /BoxW { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V Opaque stroke } def /TriUW { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V Opaque stroke } def /TriDW { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V Opaque stroke } def /PentW { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat Opaque stroke grestore } def /CircW { stroke [] 0 setdash hpt 0 360 arc Opaque stroke } def /BoxFill { gsave Rec 1 setgray fill grestore } def /Symbol-Oblique /Symbol findfont [1 0 .167 1 0 0] makefont dup length dict begin {1 index /FID eq {pop pop} {def} ifelse} forall currentdict end definefont /Helvetica reencodeISO def /MFshow {{dup dup 0 get findfont exch 1 get scalefont setfont [ currentpoint ] exch dup 2 get 0 exch rmoveto dup dup 5 get exch 4 get {show} {stringwidth pop 0 rmoveto}ifelse dup 3 get {2 get neg 0 exch rmoveto pop} {pop aload pop moveto}ifelse} forall} bind def /MFwidth {0 exch {dup 3 get{dup dup 0 get findfont exch 1 get scalefont setfont 5 get stringwidth pop add} {pop} ifelse} forall} bind def /MLshow { currentpoint stroke M 0 exch R MFshow } bind def /MRshow { currentpoint stroke M exch dup MFwidth neg 3 -1 roll R MFshow } def /MCshow { currentpoint stroke M exch dup MFwidth -2 div 3 -1 roll R MFshow } def end %%EndProlog gnudict begin gsave 50 50 translate 0.050 0.050 scale 0 setgray newpath (Helvetica) findfont 240 scalefont setfont 1.000 UL LTb 480 720 M 0 31 V 0 5009 R 0 -31 V 623 720 M 0 31 V 0 5009 R 0 -31 V 765 720 M 0 31 V 0 5009 R 0 -31 V 908 720 M 0 31 V 0 5009 R 0 -31 V 1051 720 M 0 63 V 0 4977 R 0 -63 V stroke 1051 480 M [ [(Helvetica) 240.0 0.0 true true (500)] ] -80.0 MCshow 1194 720 M 0 31 V 0 5009 R 0 -31 V 1336 720 M 0 31 V 0 5009 R 0 -31 V 1479 720 M 0 31 V 0 5009 R 0 -31 V 1622 720 M 0 31 V 0 5009 R 0 -31 V 1765 720 M 0 63 V 0 4977 R 0 -63 V stroke 1765 480 M [ [(Helvetica) 240.0 0.0 true true (1000)] ] -80.0 MCshow 1907 720 M 0 31 V 0 5009 R 0 -31 V 2050 720 M 0 31 V 0 5009 R 0 -31 V 2193 720 M 0 31 V 0 5009 R 0 -31 V 2336 720 M 0 31 V 0 5009 R 0 -31 V 2478 720 M 0 63 V 0 4977 R 0 -63 V stroke 2478 480 M [ [(Helvetica) 240.0 0.0 true true (1500)] ] -80.0 MCshow 2621 720 M 0 31 V 0 5009 R 0 -31 V 2764 720 M 0 31 V 0 5009 R 0 -31 V 2907 720 M 0 31 V 0 5009 R 0 -31 V 3049 720 M 0 31 V 0 5009 R 0 -31 V 3192 720 M 0 63 V 0 4977 R 0 -63 V stroke 3192 480 M [ [(Helvetica) 240.0 0.0 true true (2000)] ] -80.0 MCshow 1.000 UL LTb 480 720 M 2712 0 V 0 5040 V -2712 0 V 480 720 L stroke 240 3240 M currentpoint gsave translate 90 rotate 0 0 moveto [ [(Helvetica) 240.0 0.0 true true (Intensity)] ] -80.0 MCshow grestore 1836 120 M [ [(Helvetica) 240.0 0.0 true true (Velocity \(m/s\))] ] -80.0 MCshow 2621 893 M [ [(Helvetica) 240.0 0.0 true true (J=4)] ] -80.0 MLshow 2621 1760 M [ [(Helvetica) 240.0 0.0 true true (J=7)] ] -80.0 MLshow 2621 2628 M [ [(Helvetica) 240.0 0.0 true true (J=9)] ] -80.0 MLshow 2621 3495 M [ [(Helvetica) 240.0 0.0 true true (J=19)] ] -80.0 MLshow 2621 4362 M [ [(Helvetica) 240.0 0.0 true true (J=32)] ] -80.0 MLshow 2621 5229 M [ [(Helvetica) 240.0 0.0 true true (J=34)] ] -80.0 MLshow 3.000 UL LT0 480 720 M 143 11 V 765 1928 L 143 655 V 143 356 V 143 -81 V 142 -266 V 143 -463 V 143 -583 V 143 -442 V 1907 897 L 143 -68 V 143 -36 V 142 -37 V 143 -5 V 143 -17 V 143 -5 V 142 -3 V 143 0 V 143 2 V 3.000 UL LT0 480 1587 M 143 24 V 765 2713 L 143 985 V 143 249 V 143 -94 V 142 -336 V 143 -689 V 143 -489 V 143 -356 V 142 -182 V 143 -83 V 143 -54 V 142 -22 V 143 -24 V 143 -14 V 143 -7 V 142 -4 V 143 -3 V 143 5 V 3.000 UL LT0 480 2454 M 143 23 V 765 3676 L 908 4814 L 143 76 V 143 -37 V 142 -322 V 143 -644 V 143 -554 V 143 -419 V 142 -182 V 143 -116 V 143 -54 V 142 -55 V 143 -20 V 143 -9 V 143 -13 V 142 -8 V 143 -2 V 143 3 V 3.000 UL LT0 480 3321 M 143 8 V 765 4797 L 143 962 V 143 -94 V 143 -271 V 142 -406 V 143 -322 V 143 -282 V 143 -255 V 142 -290 V 143 -205 V 143 -166 V 142 -88 V 143 -38 V 143 -12 V 143 -5 V 142 -2 V 143 -1 V 143 3 V 3.000 UL LT0 480 4188 M 143 0 V 142 43 V 143 9 V 143 120 V 143 70 V 142 279 V 143 33 V 143 401 V 143 253 V 142 364 V 143 -75 V 143 -384 V 142 -524 V 143 -354 V 143 -169 V 143 -61 V 142 -4 V 143 0 V 143 1 V 3.000 UL LT0 480 5055 M 143 0 V 142 0 V 143 74 V 143 -74 V 143 42 V 142 10 V 143 20 V 143 43 V 143 236 V 142 156 V 143 -13 V 143 37 V 142 -92 V 143 -232 V 143 -142 V 143 -52 V 142 -12 V 143 0 V 143 -1 V stroke grestore end showpage %%Trailer %%DocumentFonts: Helvetica %%EndDocument @endspecial -150 1658 a Fn(FIG.)28 b(3:)40 b(V)-6 b(elo)r(cit)n(y)28 b(distribution)g(of)g(desorbing)h(molecules)f(for)h(v)l(ar-)-150 1745 y(ious)f(rotational)i(quan)n(tum)25 b(states.)42 b(Left)28 b(panel:)39 b(early)28 b(desorption)-150 1832 y(c)n(hannel;)e(righ)n(t)g(panel:)34 b(considering)27 b(all)g(desorbing)f(molecules.)-150 2140 y Fr(Fig.)h(2,)f(w)n(e)h(ha)n (v)n(e)e(plotted)i(the)h(desorption)d(rate)h(as)g(a)h(function)-150 2235 y(of)37 b(time)h(for)e(the)i(t)n(w)n(o-dimensional)d(\(solid)i (line\))h(and)e(sev)n(en-)-150 2331 y(dimensional)h(sim)n(ulations)g (\(dash-dotted)g(line\).)68 b(In)38 b(t)n(w)n(o)e(di-)-150 2426 y(mensions,)44 b(there)d(are)f(t)n(w)n(o)g(t)n(yp)r(es)h(of)g (desorbing)f(molecules.)-150 2521 y(\\Early")f(molecules)j(that)g (desorb)e(within)j(the)f(\014rst)g(1)p Fj(:)p Fr(2)e(pi-)-150 2617 y(coseconds)c(and)i(\\late")e(ones.)67 b(The)38 b(initial)g(fast)f(desorption)-150 2712 y(p)r(eak)i(corresp)r(onds)e (to)h(molecules)h(directly)f(desorbing)g(after)-150 2808 y(b)r(eing)h(scattered)g(o\013)g(the)g(repulsiv)n(e)f(part)h(of)g(the)g (p)r(oten)n(tial.)-150 2903 y(The)26 b(slo)n(w)e(trail)h(of)h(nearly)e (exp)r(onen)n(tially)h(decreasing)f(desorp-)-150 2999 y(tion)g(rate)f(can)g(b)r(e)i(assigned)d(to)i(molecules)f(b)r(eing)h (dynamically)-150 3094 y(trapp)r(ed)30 b([26)o(,)h(27)o(])f(close)f(to) h(the)g(surface)g(for)f(a)h(while)g(prior)f(to)-150 3190 y(desorption.)-67 3299 y(It)41 b(is)g(apparen)n(t)f(in)h(Fig.)f(2)h (that)g(the)g(desorption)f(rate)g(in)-150 3394 y(the)45 b(2D)f(sim)n(ulations)f(drops)g(to)i(almost)e(zero)g(after)h(1)p Fj(:)p Fr(2)f(ps)-150 3490 y(whic)n(h)d(means)f(that)i(the)f (desorption)f(probabilit)n(y)g(seems)h(to)-150 3585 y(saturate)d(after) g(this)h(time.)67 b(The)38 b(w)n(a)n(v)n(e-pac)n(k)n(et)d(calculations) -150 3681 y(w)n(ere)h(stopp)r(ed)h(after)f(this)h(time)h(due)f(to)f (their)h(high)g(compu-)-150 3776 y(tational)32 b(cost.)53 b(Hence)33 b(the)g(late)g(comp)r(onen)n(t)g(of)f(the)i(desorb-)-150 3872 y(ing)f(molecules)h(w)n(ere)e(not)i(tak)n(en)f(in)n(to)g(accoun)n (t.)54 b(Due)35 b(to)e(the)-150 3967 y(computational)c(e\016ciency)g (of)h(the)g(mixed)f(quan)n(tum-classical)-150 4063 y(sc)n(heme)i(there) h(w)n(ere)e(no)h(constrain)n(ts)g(on)g(the)h(run)n(time)f(of)h(the)-150 4158 y(tra)5 b(jectories.)74 b(When)41 b(considering)e(only)h(the)g (early)g(desorb-)-150 4254 y(ing)g(molecules)g(the)h(desorption)e (probabilit)n(y)g(is)i(reduced)f(to)-150 4349 y(2)p Fj(:)p Fr(93\045)19 b(in)h(m)n(uc)n(h)g(b)r(etter)h(agreemen)n(t)e(with)i(the) f(w)n(a)n(v)n(e-pac)n(k)n(et)d(re-)-150 4445 y(sults.)46 b(Subsequen)n(t)31 b(w)n(a)n(v)n(e-pac)n(k)n(et)d(calculations)h(using) i(longer)-150 4540 y(run)n(times)k(con\014rmed)g(this)g(conclusion;)k (they)c(yielded)g(larger)-150 4636 y(desorption)h(yields)i(due)f(to)h (the)f(additional)g(c)n(hannel)g(of)h(late)-150 4731 y(molecules.)-67 4840 y(The)21 b(late)g(desorption)g(c)n(hannel)f(also) g(sho)n(ws)g(up)i(prominen)n(tly)-150 4936 y(in)d(the)h(v)n(elo)r(cit)n (y)e(distribution)h(of)g(desorbing)f(molecules)h(for)f(v)-5 b(ar-)-150 5031 y(ious)40 b(rotational)g(quan)n(tum)g(n)n(um)n(b)r(ers) g(\(Fig.)h(3\).)77 b(The)41 b(early)-150 5127 y(desorbing)f(molecules)h (sho)n(w)g(a)g(rather)g(broad)f(v)n(elo)r(cit)n(y)h(dis-)-150 5222 y(tribution.)81 b(These)42 b(distributions)g(are)f(in)i(fact)f(in) h(a)e(rather)-150 5318 y(go)r(o)r(d)29 b(agreemen)n(t)g(with)h(the)g (corresp)r(onding)e(w)n(a)n(v)n(e-pac)n(k)n(et)f(re-)-150 5413 y(sults)45 b([17)o(].)89 b(T)-7 b(aking)44 b(in)n(to)g(accoun)n(t) g(also)g(the)h(late)g(desorp-)2118 1157 y @beginspecial 50 @llx 50 @lly 410 @urx 302 @ury 2267 @rwi @setspecial %%BeginDocument: graphs/COMP2_Rot.ps %!PS-Adobe-2.0 EPSF-2.0 %%Title: COMP2_Rot.ps %%Creator: gnuplot 3.7 patchlevel 1 %%CreationDate: Tue Apr 15 17:29:12 2003 %%DocumentFonts: (atend) %%BoundingBox: 50 50 410 302 %%Orientation: Portrait %%EndComments /gnudict 256 dict def gnudict begin /Color false def /Solid false def /gnulinewidth 5.000 def /userlinewidth gnulinewidth def /vshift -80 def /dl {10 mul} def /hpt_ 31.5 def /vpt_ 31.5 def /hpt hpt_ def /vpt vpt_ def /reencodeISO { dup dup findfont dup length dict begin { 1 index /FID ne { def }{ pop pop } ifelse } forall currentdict /CharStrings known { CharStrings /Idieresis known { /Encoding ISOLatin1Encoding def } if } if currentdict end definefont } def /ISOLatin1Encoding [ /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /space/exclam/quotedbl/numbersign/dollar/percent/ampersand/quoteright /parenleft/parenright/asterisk/plus/comma/minus/period/slash /zero/one/two/three/four/five/six/seven/eight/nine/colon/semicolon /less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N /O/P/Q/R/S/T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright /asciicircum/underscore/quoteleft/a/b/c/d/e/f/g/h/i/j/k/l/m /n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright/asciitilde /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/dotlessi/grave/acute/circumflex/tilde/macron/breve /dotaccent/dieresis/.notdef/ring/cedilla/.notdef/hungarumlaut /ogonek/caron/space/exclamdown/cent/sterling/currency/yen/brokenbar /section/dieresis/copyright/ordfeminine/guillemotleft/logicalnot /hyphen/registered/macron/degree/plusminus/twosuperior/threesuperior /acute/mu/paragraph/periodcentered/cedilla/onesuperior/ordmasculine /guillemotright/onequarter/onehalf/threequarters/questiondown /Agrave/Aacute/Acircumflex/Atilde/Adieresis/Aring/AE/Ccedilla /Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute/Icircumflex /Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute /Thorn/germandbls/agrave/aacute/acircumflex/atilde/adieresis /aring/ae/ccedilla/egrave/eacute/ecircumflex/edieresis/igrave /iacute/icircumflex/idieresis/eth/ntilde/ograve/oacute/ocircumflex /otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex/udieresis /yacute/thorn/ydieresis ] def /M {moveto} bind def /L {lineto} bind def /R {rmoveto} bind def /V {rlineto} bind def /vpt2 vpt 2 mul def /hpt2 hpt 2 mul def /Lshow { currentpoint stroke M 0 vshift R show } def /Rshow { currentpoint stroke M dup stringwidth pop neg vshift R show } def /Cshow { currentpoint stroke M dup stringwidth pop -2 div vshift R show } def /UP { dup vpt_ mul /vpt exch def hpt_ mul /hpt exch def /hpt2 hpt 2 mul def /vpt2 vpt 2 mul def } def /DL { Color {setrgbcolor Solid {pop []} if 0 setdash } {pop pop pop Solid {pop []} if 0 setdash} ifelse } def /BL { stroke userlinewidth 2 mul setlinewidth } def /AL { stroke userlinewidth 2 div setlinewidth } def /UL { dup gnulinewidth mul /userlinewidth exch def 10 mul /udl exch def } def /PL { stroke userlinewidth setlinewidth } def /LTb { BL [] 0 0 0 DL } def /LTa { AL [1 udl mul 2 udl mul] 0 setdash 0 0 0 setrgbcolor } def /LT0 { PL [] 1 0 0 DL } def /LT1 { PL [4 dl 2 dl] 0 1 0 DL } def /LT2 { PL [2 dl 3 dl] 0 0 1 DL } def /LT3 { PL [1 dl 1.5 dl] 1 0 1 DL } def /LT4 { PL [5 dl 2 dl 1 dl 2 dl] 0 1 1 DL } def /LT5 { PL [4 dl 3 dl 1 dl 3 dl] 1 1 0 DL } def /LT6 { PL [2 dl 2 dl 2 dl 4 dl] 0 0 0 DL } def /LT7 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 1 0.3 0 DL } def /LT8 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 0.5 0.5 0.5 DL } def /Pnt { stroke [] 0 setdash gsave 1 setlinecap M 0 0 V stroke grestore } def /Dia { stroke [] 0 setdash 2 copy vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke Pnt } def /Pls { stroke [] 0 setdash vpt sub M 0 vpt2 V currentpoint stroke M hpt neg vpt neg R hpt2 0 V stroke } def /Box { stroke [] 0 setdash 2 copy exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke Pnt } def /Crs { stroke [] 0 setdash exch hpt sub exch vpt add M hpt2 vpt2 neg V currentpoint stroke M hpt2 neg 0 R hpt2 vpt2 V stroke } def /TriU { stroke [] 0 setdash 2 copy vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke Pnt } def /Star { 2 copy Pls Crs } def /BoxF { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath fill } def /TriUF { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath fill } def /TriD { stroke [] 0 setdash 2 copy vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke Pnt } def /TriDF { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath fill} def /DiaF { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath fill } def /Pent { stroke [] 0 setdash 2 copy gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore Pnt } def /PentF { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath fill grestore } def /Circle { stroke [] 0 setdash 2 copy hpt 0 360 arc stroke Pnt } def /CircleF { stroke [] 0 setdash hpt 0 360 arc fill } def /C0 { BL [] 0 setdash 2 copy moveto vpt 90 450 arc } bind def /C1 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill vpt 0 360 arc closepath } bind def /C2 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C3 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill vpt 0 360 arc closepath } bind def /C4 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc closepath } bind def /C5 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc } bind def /C6 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 270 arc closepath fill vpt 0 360 arc closepath } bind def /C7 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 270 arc closepath fill vpt 0 360 arc closepath } bind def /C8 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C9 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 450 arc closepath fill vpt 0 360 arc closepath } bind def /C10 { BL [] 0 setdash 2 copy 2 copy moveto vpt 270 360 arc closepath fill 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C11 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C12 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C13 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C14 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 360 arc closepath fill vpt 0 360 arc } bind def /C15 { BL [] 0 setdash 2 copy vpt 0 360 arc closepath fill vpt 0 360 arc closepath } bind def /Rec { newpath 4 2 roll moveto 1 index 0 rlineto 0 exch rlineto neg 0 rlineto closepath } bind def /Square { dup Rec } bind def /Bsquare { vpt sub exch vpt sub exch vpt2 Square } bind def /S0 { BL [] 0 setdash 2 copy moveto 0 vpt rlineto BL Bsquare } bind def /S1 { BL [] 0 setdash 2 copy vpt Square fill Bsquare } bind def /S2 { BL [] 0 setdash 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S3 { BL [] 0 setdash 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S4 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S5 { BL [] 0 setdash 2 copy 2 copy vpt Square fill exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S6 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill Bsquare } bind def /S7 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill 2 copy vpt Square fill Bsquare } bind def /S8 { BL [] 0 setdash 2 copy vpt sub vpt Square fill Bsquare } bind def /S9 { BL [] 0 setdash 2 copy vpt sub vpt vpt2 Rec fill Bsquare } bind def /S10 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S11 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S12 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill Bsquare } bind def /S13 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy vpt Square fill Bsquare } bind def /S14 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S15 { BL [] 0 setdash 2 copy Bsquare fill Bsquare } bind def /D0 { gsave translate 45 rotate 0 0 S0 stroke grestore } bind def /D1 { gsave translate 45 rotate 0 0 S1 stroke grestore } bind def /D2 { gsave translate 45 rotate 0 0 S2 stroke grestore } bind def /D3 { gsave translate 45 rotate 0 0 S3 stroke grestore } bind def /D4 { gsave translate 45 rotate 0 0 S4 stroke grestore } bind def /D5 { gsave translate 45 rotate 0 0 S5 stroke grestore } bind def /D6 { gsave translate 45 rotate 0 0 S6 stroke grestore } bind def /D7 { gsave translate 45 rotate 0 0 S7 stroke grestore } bind def /D8 { gsave translate 45 rotate 0 0 S8 stroke grestore } bind def /D9 { gsave translate 45 rotate 0 0 S9 stroke grestore } bind def /D10 { gsave translate 45 rotate 0 0 S10 stroke grestore } bind def /D11 { gsave translate 45 rotate 0 0 S11 stroke grestore } bind def /D12 { gsave translate 45 rotate 0 0 S12 stroke grestore } bind def /D13 { gsave translate 45 rotate 0 0 S13 stroke grestore } bind def /D14 { gsave translate 45 rotate 0 0 S14 stroke grestore } bind def /D15 { gsave translate 45 rotate 0 0 S15 stroke grestore } bind def /DiaE { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke } def /BoxE { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke } def /TriUE { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke } def /TriDE { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke } def /PentE { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore } def /CircE { stroke [] 0 setdash hpt 0 360 arc stroke } def /Opaque { gsave closepath 1 setgray fill grestore 0 setgray closepath } def /DiaW { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V Opaque stroke } def /BoxW { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V Opaque stroke } def /TriUW { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V Opaque stroke } def /TriDW { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V Opaque stroke } def /PentW { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat Opaque stroke grestore } def /CircW { stroke [] 0 setdash hpt 0 360 arc Opaque stroke } def /BoxFill { gsave Rec 1 setgray fill grestore } def /Symbol-Oblique /Symbol findfont [1 0 .167 1 0 0] makefont dup length dict begin {1 index /FID eq {pop pop} {def} ifelse} forall currentdict end definefont /Helvetica reencodeISO def /MFshow {{dup dup 0 get findfont exch 1 get scalefont setfont [ currentpoint ] exch dup 2 get 0 exch rmoveto dup dup 5 get exch 4 get {show} {stringwidth pop 0 rmoveto}ifelse dup 3 get {2 get neg 0 exch rmoveto pop} {pop aload pop moveto}ifelse} forall} bind def /MFwidth {0 exch {dup 3 get{dup dup 0 get findfont exch 1 get scalefont setfont 5 get stringwidth pop add} {pop} ifelse} forall} bind def /MLshow { currentpoint stroke M 0 exch R MFshow } bind def /MRshow { currentpoint stroke M exch dup MFwidth neg 3 -1 roll R MFshow } def /MCshow { currentpoint stroke M exch dup MFwidth -2 div 3 -1 roll R MFshow } def end %%EndProlog gnudict begin gsave 50 50 translate 0.050 0.050 scale 0 setgray newpath (Helvetica) findfont 240 scalefont setfont 1.000 UL LTb 1512 720 M 63 0 V 5217 0 R -63 0 V stroke 1368 720 M [ [(Helvetica) 240.0 0.0 true true (0)] ] -80.0 MRshow 1512 1392 M 63 0 V 5217 0 R -63 0 V stroke 1368 1392 M [ [(Helvetica) 240.0 0.0 true true (0.0005)] ] -80.0 MRshow 1512 2064 M 63 0 V 5217 0 R -63 0 V stroke 1368 2064 M [ [(Helvetica) 240.0 0.0 true true (0.001)] ] -80.0 MRshow 1512 2736 M 63 0 V 5217 0 R -63 0 V stroke 1368 2736 M [ [(Helvetica) 240.0 0.0 true true (0.0015)] ] -80.0 MRshow 1512 3408 M 63 0 V 5217 0 R -63 0 V stroke 1368 3408 M [ [(Helvetica) 240.0 0.0 true true (0.002)] ] -80.0 MRshow 1512 4080 M 63 0 V 5217 0 R -63 0 V stroke 1368 4080 M [ [(Helvetica) 240.0 0.0 true true (0.0025)] ] -80.0 MRshow 1512 4752 M 63 0 V 5217 0 R -63 0 V stroke 1368 4752 M [ [(Helvetica) 240.0 0.0 true true (0.003)] ] -80.0 MRshow 1512 720 M 0 63 V 0 3969 R 0 -63 V stroke 1512 480 M [ [(Helvetica) 240.0 0.0 true true (0)] ] -80.0 MCshow 2266 720 M 0 63 V 0 3969 R 0 -63 V stroke 2266 480 M [ [(Helvetica) 240.0 0.0 true true (5)] ] -80.0 MCshow 3021 720 M 0 63 V 0 3969 R 0 -63 V stroke 3021 480 M [ [(Helvetica) 240.0 0.0 true true (10)] ] -80.0 MCshow 3775 720 M 0 63 V 0 3969 R 0 -63 V stroke 3775 480 M [ [(Helvetica) 240.0 0.0 true true (15)] ] -80.0 MCshow 4529 720 M 0 63 V 0 3969 R 0 -63 V stroke 4529 480 M [ [(Helvetica) 240.0 0.0 true true (20)] ] -80.0 MCshow 5283 720 M 0 63 V 0 3969 R 0 -63 V stroke 5283 480 M [ [(Helvetica) 240.0 0.0 true true (25)] ] -80.0 MCshow 6038 720 M 0 63 V 0 3969 R 0 -63 V stroke 6038 480 M [ [(Helvetica) 240.0 0.0 true true (30)] ] -80.0 MCshow 6792 720 M 0 63 V 0 3969 R 0 -63 V stroke 6792 480 M [ [(Helvetica) 240.0 0.0 true true (35)] ] -80.0 MCshow 1.000 UL LTb 1512 720 M 5280 0 V 0 4032 V -5280 0 V 0 -4032 V stroke 240 2736 M currentpoint gsave translate 90 rotate 0 0 moveto [ [(Helvetica) 240.0 0.0 true true (Desorption probability)] ] -80.0 MCshow grestore 4152 120 M [ [(Helvetica) 240.0 0.0 true true (Rotational quantum number)] ] -80.0 MCshow 4.000 UL LT0 6009 4569 M [ [(Helvetica) 240.0 0.0 true true (3D)] ] -80.0 MRshow 6153 4569 M 351 0 V 1512 2555 M 151 914 V 151 120 V 151 5 V 150 30 V 151 51 V 151 188 V 151 4 V 151 -88 V 151 -148 V 151 -364 V 150 -285 V 151 -225 V 151 -190 V 151 -145 V 151 -138 V 151 -144 V 151 -123 V 150 -220 V 151 -187 V 151 -114 V 151 -115 V 151 -90 V 151 -82 V 151 -94 V 150 -90 V 151 -67 V 151 -33 V 151 -10 V 151 18 V 151 -22 V 151 -54 V 150 -37 V 151 -35 V 151 -23 V 151 11 V 6.000 UL LT1 6009 4329 M [ [(Helvetica) 240.0 0.0 true true (2D total)] ] -80.0 MRshow 6153 4329 M 351 0 V 1512 1104 M 151 608 V 151 714 V 151 245 V 150 57 V 151 -30 V 151 -92 V 151 94 V 151 32 V 151 130 V 151 125 V 150 381 V 151 -89 V 151 -321 V 151 -152 V 151 71 V 151 -89 V 151 4 V 150 64 V 151 36 V 151 42 V 151 235 V 151 219 V 151 388 V 151 -59 V 150 -71 V 151 -257 V 151 -689 V 151 -584 V 151 -415 V 151 -461 V 151 -216 V 6339 852 L 151 -76 V 151 -29 V 151 -24 V 5.000 UL LT4 6009 4089 M [ [(Helvetica) 240.0 0.0 true true (2D late)] ] -80.0 MRshow 6153 4089 M 351 0 V 1512 971 M 151 441 V 151 692 V 151 206 V 150 15 V 151 -61 V 151 -101 V 151 29 V 151 -25 V 151 54 V 151 57 V 150 53 V 151 -55 V 151 -87 V 151 -125 V 151 -28 V 151 -145 V 151 -147 V 150 -29 V 151 -121 V 151 -89 V 151 -44 V 151 -72 V 151 41 V 151 -116 V 150 -144 V 151 -92 V 5585 911 L 151 -93 V 151 -54 V 151 -37 V 151 -3 V 150 -4 V 151 1 V 151 -1 V 151 0 V 5.000 UL LT3 6009 3849 M [ [(Helvetica) 240.0 0.0 true true (7D)] ] -80.0 MRshow 6153 3849 M 351 0 V 1512 1493 M 151 1394 V 151 580 V 151 454 V 150 -123 V 151 160 V 151 20 V 151 -15 V 151 -17 V 151 31 V 151 -330 V 150 -310 V 151 -295 V 151 -254 V 151 -213 V 151 -144 V 151 -75 V 151 -287 V 150 -185 V 151 -186 V 151 -176 V 151 -129 V 151 23 V 151 -149 V 151 -126 V 150 -41 V 151 -86 V 151 -74 V 151 3 V 151 -43 V 151 5 V 151 -40 V 150 -36 V 151 -44 V 151 -15 V 151 23 V stroke grestore end showpage %%Trailer %%DocumentFonts: Helvetica %%EndDocument @endspecial 2042 1327 a Fn(FIG.)37 b(4:)56 b(Rotational)38 b(distribution)e(of)h(desorbing)g(molecules)g(ac-)2042 1414 y(cording)26 b(to)g(2D,)g(3D)f(and)h(7D)f(calculations.)2042 1722 y Fr(tion)38 b(c)n(hannel)g(leads)g(to)g(m)n(uc)n(h)g(narro)n(w)n (er)e(v)n(elo)r(cit)n(y)h(distribu-)2042 1818 y(tions.)e(Unfortunately) -7 b(,)24 b(th)n(us)e(the)h(agreemen)n(t)f(with)h(the)g(exp)r(er-)2042 1913 y(imen)n(t)h([15)o(])g(is)g(reduced.)36 b(In)24 b(particular,)g(the)g(bimo)r(dal)g(v)n(elo)r(cit)n(y)2042 2009 y(distribution)18 b(found)h(in)g(the)g(exp)r(erimen)n(t)g(is)f (hardly)g(repro)r(duced)2042 2104 y(an)n(y)27 b(more.)2125 2213 y(Since)41 b(the)g(mass)g(of)g(the)g(substrate)g(atoms)f(and)h (the)g(NO)2042 2309 y(molecule)30 b(is)g(comparable,)g(recoil)g(pro)r (cesses)f(during)h(the)h(des-)2042 2404 y(orption)40 b(pro)r(cess)f(are)h(probable.)75 b(In)41 b(order)e(to)h(include)h(en-) 2042 2500 y(ergy)22 b(transfer)g(to)h(the)h(substrate)e(in)i(the)f(sim) n(ulations,)h(w)n(e)e(ha)n(v)n(e)2042 2595 y(coupled)28 b(the)h(2D)f(and)g(6D)g(p)r(oten)n(tials)g(to)h(a)e(surface)h (oscillator)2042 2691 y(with)39 b(realistic)e(parameters,)j(as)e (describ)r(ed)g(in)g(the)h(previous)2042 2786 y(section.)61 b(The)36 b(computational)f(costs)h(of)g(this)g(extension)f(are)2042 2882 y(rather)26 b(small.)2125 2991 y(In)33 b(T)-7 b(ab.)32 b(I)h(w)n(e)f(ha)n(v)n(e)g(collected)g(the)h(main)g(results)f(with)h (re-)2042 3087 y(sp)r(ect)41 b(to)f(the)i(desorption)d(probabilit)n(y)h (and)h(the)g(rotational)2042 3182 y(temp)r(erature)24 b(of)h(desorbing)e(molecules)h(according)f(to)i(the)g(2D,)2042 3278 y(3D,)k(6D)g(and)f(7D)h(calculations.)40 b(Going)28 b(from)g(2D)h(to)g(6D,)g(i.e.,)2042 3373 y(including)f(the)g(remaining) f(molecular)g(degrees)g(of)g(freedom)h(in)2042 3468 y(the)23 b(sim)n(ulations,)f(has)g(only)g(a)h(small)f(in\015uence)g(on)h(the)g (desorp-)2042 3564 y(tion)k(distributions.)2125 3673 y(W)-7 b(e)24 b(\014nd)h(that)f(the)g(most)g(dramatic)f(e\013ect)i (comes)e(from)h(tak-)2042 3769 y(ing)h(the)h(surface)f(oscillator)f(in) n(to)h(accoun)n(t.)36 b(The)25 b(total)h(desorp-)2042 3864 y(tion)21 b(probabilit)n(y)f(is)h(reduced)f(b)n(y)h(ab)r(out)g (1\045.)34 b(Muc)n(h)21 b(more)f(dra-)2042 3960 y(matic)k(is)g(the)g(c) n(hange)f(for)g(the)i(early)e(desorption)g(c)n(hannel,)h(it)g(is)2042 4055 y(reduced)g(b)n(y)g(a)g(factor)g(of)g(eigh)n(t.)36 b(This)24 b(can)g(also)g(b)r(e)h(seen)f(in)h(the)2042 4151 y(desorption)g(rate)g(In)h(Fig.)g(2\),)g(where)f(the)i(initial)f (\\early")d(p)r(eak)2042 4246 y(is)37 b(basically)f(absen)n(t)g(in)i (the)f(7D)g(results.)65 b(This)37 b(also)f(a\013ects)2042 4342 y(the)29 b(rotational)e(momen)n(tum)i(distribution.)39 b(While)29 b(in)g(the)g(2D)p 2522 4539 1082 4 v 2522 4626 4 88 v 2908 4626 V 2948 4600 a Fn(2D)p 3081 4626 V 76 w(3D)p 3254 4626 V 76 w(6D)p 3427 4626 V 76 w(7D)p 3600 4626 V 2522 4629 1082 4 v 2522 4716 4 88 v 2570 4690 a Fb(z)2606 4698 y Fa(C)s(O)2731 4690 y Fn(\(a)2799 4698 y Fp(0)2834 4690 y Fn(\))p 2908 4716 V 64 w(12.5)p 3081 4716 V 38 w(16.0)p 3254 4716 V 38 w(16.0)p 3427 4716 V 38 w(16.0)p 3600 4716 V 2522 4804 V 2570 4778 a Fb(P)2619 4787 y Fa(des)2740 4778 y Fn(\(\045\))p 2908 4804 V 64 w(4.84)p 3081 4804 V 38 w(3.63)p 3254 4804 V 38 w(4.74)p 3427 4804 V 38 w(4.02)p 3600 4804 V 2522 4891 V 2542 4865 a Fb(P)2591 4874 y Fa(ear)r(ly)2768 4865 y Fn(\(\045\))p 2908 4891 V 36 w(2.93)p 3081 4891 V 38 w(0.32)p 3254 4891 V 38 w(2.53)p 3427 4891 V 38 w(0.32)p 3600 4891 V 2522 4978 V 2572 4952 a Fb(E)2629 4960 y Fa(r)r(ot)2743 4952 y Fn(\(K\))p 2908 4978 V 76 w(770)p 3081 4978 V 59 w(366)p 3254 4978 V 59 w(883)p 3427 4978 V 59 w(395)p 3600 4978 V 2522 4981 1082 4 v 2042 5125 a(T)-6 b(ABLE)22 b(I:)g(Desorption)g(probabilities)h(and)f (mean)f(rotational)j(ener-)2042 5212 y(gies)j(according)g(to)g(the)f (2D,)g(3D,)h(6D)f(and)g(7D)g(calculations.)39 b(Early)2042 5299 y(means)25 b(desorption)h(within)g(the)f(\014rst)h(1.2)g (picoseconds.)p eop %%Page: 5 5 5 4 bop 4043 -299 a Fr(5)-74 1157 y @beginspecial 50 @llx 50 @lly 410 @urx 302 @ury 2267 @rwi @setspecial %%BeginDocument: graphs/COMP2_Vel.ps %!PS-Adobe-2.0 EPSF-2.0 %%Title: COMP2_Vel.ps %%Creator: gnuplot 3.7 patchlevel 1 %%CreationDate: Tue Apr 15 17:29:12 2003 %%DocumentFonts: (atend) %%BoundingBox: 50 50 410 302 %%Orientation: Portrait %%EndComments /gnudict 256 dict def gnudict begin /Color false def /Solid false def /gnulinewidth 5.000 def /userlinewidth gnulinewidth def /vshift -80 def /dl {10 mul} def /hpt_ 31.5 def /vpt_ 31.5 def /hpt hpt_ def /vpt vpt_ def /reencodeISO { dup dup findfont dup length dict begin { 1 index /FID ne { def }{ pop pop } ifelse } forall currentdict /CharStrings known { CharStrings /Idieresis known { /Encoding ISOLatin1Encoding def } if } if currentdict end definefont } def /ISOLatin1Encoding [ /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /space/exclam/quotedbl/numbersign/dollar/percent/ampersand/quoteright /parenleft/parenright/asterisk/plus/comma/minus/period/slash /zero/one/two/three/four/five/six/seven/eight/nine/colon/semicolon /less/equal/greater/question/at/A/B/C/D/E/F/G/H/I/J/K/L/M/N /O/P/Q/R/S/T/U/V/W/X/Y/Z/bracketleft/backslash/bracketright /asciicircum/underscore/quoteleft/a/b/c/d/e/f/g/h/i/j/k/l/m /n/o/p/q/r/s/t/u/v/w/x/y/z/braceleft/bar/braceright/asciitilde /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef/.notdef /.notdef/dotlessi/grave/acute/circumflex/tilde/macron/breve /dotaccent/dieresis/.notdef/ring/cedilla/.notdef/hungarumlaut /ogonek/caron/space/exclamdown/cent/sterling/currency/yen/brokenbar /section/dieresis/copyright/ordfeminine/guillemotleft/logicalnot /hyphen/registered/macron/degree/plusminus/twosuperior/threesuperior /acute/mu/paragraph/periodcentered/cedilla/onesuperior/ordmasculine /guillemotright/onequarter/onehalf/threequarters/questiondown /Agrave/Aacute/Acircumflex/Atilde/Adieresis/Aring/AE/Ccedilla /Egrave/Eacute/Ecircumflex/Edieresis/Igrave/Iacute/Icircumflex /Idieresis/Eth/Ntilde/Ograve/Oacute/Ocircumflex/Otilde/Odieresis /multiply/Oslash/Ugrave/Uacute/Ucircumflex/Udieresis/Yacute /Thorn/germandbls/agrave/aacute/acircumflex/atilde/adieresis /aring/ae/ccedilla/egrave/eacute/ecircumflex/edieresis/igrave /iacute/icircumflex/idieresis/eth/ntilde/ograve/oacute/ocircumflex /otilde/odieresis/divide/oslash/ugrave/uacute/ucircumflex/udieresis /yacute/thorn/ydieresis ] def /M {moveto} bind def /L {lineto} bind def /R {rmoveto} bind def /V {rlineto} bind def /vpt2 vpt 2 mul def /hpt2 hpt 2 mul def /Lshow { currentpoint stroke M 0 vshift R show } def /Rshow { currentpoint stroke M dup stringwidth pop neg vshift R show } def /Cshow { currentpoint stroke M dup stringwidth pop -2 div vshift R show } def /UP { dup vpt_ mul /vpt exch def hpt_ mul /hpt exch def /hpt2 hpt 2 mul def /vpt2 vpt 2 mul def } def /DL { Color {setrgbcolor Solid {pop []} if 0 setdash } {pop pop pop Solid {pop []} if 0 setdash} ifelse } def /BL { stroke userlinewidth 2 mul setlinewidth } def /AL { stroke userlinewidth 2 div setlinewidth } def /UL { dup gnulinewidth mul /userlinewidth exch def 10 mul /udl exch def } def /PL { stroke userlinewidth setlinewidth } def /LTb { BL [] 0 0 0 DL } def /LTa { AL [1 udl mul 2 udl mul] 0 setdash 0 0 0 setrgbcolor } def /LT0 { PL [] 1 0 0 DL } def /LT1 { PL [4 dl 2 dl] 0 1 0 DL } def /LT2 { PL [2 dl 3 dl] 0 0 1 DL } def /LT3 { PL [1 dl 1.5 dl] 1 0 1 DL } def /LT4 { PL [5 dl 2 dl 1 dl 2 dl] 0 1 1 DL } def /LT5 { PL [4 dl 3 dl 1 dl 3 dl] 1 1 0 DL } def /LT6 { PL [2 dl 2 dl 2 dl 4 dl] 0 0 0 DL } def /LT7 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 1 0.3 0 DL } def /LT8 { PL [2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 2 dl 4 dl] 0.5 0.5 0.5 DL } def /Pnt { stroke [] 0 setdash gsave 1 setlinecap M 0 0 V stroke grestore } def /Dia { stroke [] 0 setdash 2 copy vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke Pnt } def /Pls { stroke [] 0 setdash vpt sub M 0 vpt2 V currentpoint stroke M hpt neg vpt neg R hpt2 0 V stroke } def /Box { stroke [] 0 setdash 2 copy exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke Pnt } def /Crs { stroke [] 0 setdash exch hpt sub exch vpt add M hpt2 vpt2 neg V currentpoint stroke M hpt2 neg 0 R hpt2 vpt2 V stroke } def /TriU { stroke [] 0 setdash 2 copy vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke Pnt } def /Star { 2 copy Pls Crs } def /BoxF { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath fill } def /TriUF { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath fill } def /TriD { stroke [] 0 setdash 2 copy vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke Pnt } def /TriDF { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath fill} def /DiaF { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath fill } def /Pent { stroke [] 0 setdash 2 copy gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore Pnt } def /PentF { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath fill grestore } def /Circle { stroke [] 0 setdash 2 copy hpt 0 360 arc stroke Pnt } def /CircleF { stroke [] 0 setdash hpt 0 360 arc fill } def /C0 { BL [] 0 setdash 2 copy moveto vpt 90 450 arc } bind def /C1 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill vpt 0 360 arc closepath } bind def /C2 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C3 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill vpt 0 360 arc closepath } bind def /C4 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc closepath } bind def /C5 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc 2 copy moveto 2 copy vpt 180 270 arc closepath fill vpt 0 360 arc } bind def /C6 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 270 arc closepath fill vpt 0 360 arc closepath } bind def /C7 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 270 arc closepath fill vpt 0 360 arc closepath } bind def /C8 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C9 { BL [] 0 setdash 2 copy moveto 2 copy vpt 270 450 arc closepath fill vpt 0 360 arc closepath } bind def /C10 { BL [] 0 setdash 2 copy 2 copy moveto vpt 270 360 arc closepath fill 2 copy moveto 2 copy vpt 90 180 arc closepath fill vpt 0 360 arc closepath } bind def /C11 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 180 arc closepath fill 2 copy moveto 2 copy vpt 270 360 arc closepath fill vpt 0 360 arc closepath } bind def /C12 { BL [] 0 setdash 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C13 { BL [] 0 setdash 2 copy moveto 2 copy vpt 0 90 arc closepath fill 2 copy moveto 2 copy vpt 180 360 arc closepath fill vpt 0 360 arc closepath } bind def /C14 { BL [] 0 setdash 2 copy moveto 2 copy vpt 90 360 arc closepath fill vpt 0 360 arc } bind def /C15 { BL [] 0 setdash 2 copy vpt 0 360 arc closepath fill vpt 0 360 arc closepath } bind def /Rec { newpath 4 2 roll moveto 1 index 0 rlineto 0 exch rlineto neg 0 rlineto closepath } bind def /Square { dup Rec } bind def /Bsquare { vpt sub exch vpt sub exch vpt2 Square } bind def /S0 { BL [] 0 setdash 2 copy moveto 0 vpt rlineto BL Bsquare } bind def /S1 { BL [] 0 setdash 2 copy vpt Square fill Bsquare } bind def /S2 { BL [] 0 setdash 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S3 { BL [] 0 setdash 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S4 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S5 { BL [] 0 setdash 2 copy 2 copy vpt Square fill exch vpt sub exch vpt sub vpt Square fill Bsquare } bind def /S6 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill Bsquare } bind def /S7 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt vpt2 Rec fill 2 copy vpt Square fill Bsquare } bind def /S8 { BL [] 0 setdash 2 copy vpt sub vpt Square fill Bsquare } bind def /S9 { BL [] 0 setdash 2 copy vpt sub vpt vpt2 Rec fill Bsquare } bind def /S10 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S11 { BL [] 0 setdash 2 copy vpt sub vpt Square fill 2 copy exch vpt sub exch vpt2 vpt Rec fill Bsquare } bind def /S12 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill Bsquare } bind def /S13 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy vpt Square fill Bsquare } bind def /S14 { BL [] 0 setdash 2 copy exch vpt sub exch vpt sub vpt2 vpt Rec fill 2 copy exch vpt sub exch vpt Square fill Bsquare } bind def /S15 { BL [] 0 setdash 2 copy Bsquare fill Bsquare } bind def /D0 { gsave translate 45 rotate 0 0 S0 stroke grestore } bind def /D1 { gsave translate 45 rotate 0 0 S1 stroke grestore } bind def /D2 { gsave translate 45 rotate 0 0 S2 stroke grestore } bind def /D3 { gsave translate 45 rotate 0 0 S3 stroke grestore } bind def /D4 { gsave translate 45 rotate 0 0 S4 stroke grestore } bind def /D5 { gsave translate 45 rotate 0 0 S5 stroke grestore } bind def /D6 { gsave translate 45 rotate 0 0 S6 stroke grestore } bind def /D7 { gsave translate 45 rotate 0 0 S7 stroke grestore } bind def /D8 { gsave translate 45 rotate 0 0 S8 stroke grestore } bind def /D9 { gsave translate 45 rotate 0 0 S9 stroke grestore } bind def /D10 { gsave translate 45 rotate 0 0 S10 stroke grestore } bind def /D11 { gsave translate 45 rotate 0 0 S11 stroke grestore } bind def /D12 { gsave translate 45 rotate 0 0 S12 stroke grestore } bind def /D13 { gsave translate 45 rotate 0 0 S13 stroke grestore } bind def /D14 { gsave translate 45 rotate 0 0 S14 stroke grestore } bind def /D15 { gsave translate 45 rotate 0 0 S15 stroke grestore } bind def /DiaE { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V closepath stroke } def /BoxE { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V closepath stroke } def /TriUE { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V closepath stroke } def /TriDE { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V closepath stroke } def /PentE { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat closepath stroke grestore } def /CircE { stroke [] 0 setdash hpt 0 360 arc stroke } def /Opaque { gsave closepath 1 setgray fill grestore 0 setgray closepath } def /DiaW { stroke [] 0 setdash vpt add M hpt neg vpt neg V hpt vpt neg V hpt vpt V hpt neg vpt V Opaque stroke } def /BoxW { stroke [] 0 setdash exch hpt sub exch vpt add M 0 vpt2 neg V hpt2 0 V 0 vpt2 V hpt2 neg 0 V Opaque stroke } def /TriUW { stroke [] 0 setdash vpt 1.12 mul add M hpt neg vpt -1.62 mul V hpt 2 mul 0 V hpt neg vpt 1.62 mul V Opaque stroke } def /TriDW { stroke [] 0 setdash vpt 1.12 mul sub M hpt neg vpt 1.62 mul V hpt 2 mul 0 V hpt neg vpt -1.62 mul V Opaque stroke } def /PentW { stroke [] 0 setdash gsave translate 0 hpt M 4 {72 rotate 0 hpt L} repeat Opaque stroke grestore } def /CircW { stroke [] 0 setdash hpt 0 360 arc Opaque stroke } def /BoxFill { gsave Rec 1 setgray fill grestore } def /Symbol-Oblique /Symbol findfont [1 0 .167 1 0 0] makefont dup length dict begin {1 index /FID eq {pop pop} {def} ifelse} forall currentdict end definefont /Helvetica reencodeISO def /MFshow {{dup dup 0 get findfont exch 1 get scalefont setfont [ currentpoint ] exch dup 2 get 0 exch rmoveto dup dup 5 get exch 4 get {show} {stringwidth pop 0 rmoveto}ifelse dup 3 get {2 get neg 0 exch rmoveto pop} {pop aload pop moveto}ifelse} forall} bind def /MFwidth {0 exch {dup 3 get{dup dup 0 get findfont exch 1 get scalefont setfont 5 get stringwidth pop add} {pop} ifelse} forall} bind def /MLshow { currentpoint stroke M 0 exch R MFshow } bind def /MRshow { currentpoint stroke M exch dup MFwidth neg 3 -1 roll R MFshow } def /MCshow { currentpoint stroke M exch dup MFwidth -2 div 3 -1 roll R MFshow } def end %%EndProlog gnudict begin gsave 50 50 translate 0.050 0.050 scale 0 setgray newpath (Helvetica) findfont 240 scalefont setfont 1.000 UL LTb 1368 720 M 63 0 V 5361 0 R -63 0 V stroke 1224 720 M [ [(Helvetica) 240.0 0.0 true true (0)] ] -80.0 MRshow 1368 1296 M 63 0 V 5361 0 R -63 0 V stroke 1224 1296 M [ [(Helvetica) 240.0 0.0 true true (0.001)] ] -80.0 MRshow 1368 1872 M 63 0 V 5361 0 R -63 0 V stroke 1224 1872 M [ [(Helvetica) 240.0 0.0 true true (0.002)] ] -80.0 MRshow 1368 2448 M 63 0 V 5361 0 R -63 0 V stroke 1224 2448 M [ [(Helvetica) 240.0 0.0 true true (0.003)] ] -80.0 MRshow 1368 3024 M 63 0 V 5361 0 R -63 0 V stroke 1224 3024 M [ [(Helvetica) 240.0 0.0 true true (0.004)] ] -80.0 MRshow 1368 3600 M 63 0 V 5361 0 R -63 0 V stroke 1224 3600 M [ [(Helvetica) 240.0 0.0 true true (0.005)] ] -80.0 MRshow 1368 4176 M 63 0 V 5361 0 R -63 0 V stroke 1224 4176 M [ [(Helvetica) 240.0 0.0 true true (0.006)] ] -80.0 MRshow 1368 4752 M 63 0 V 5361 0 R -63 0 V stroke 1224 4752 M [ [(Helvetica) 240.0 0.0 true true (0.007)] ] -80.0 MRshow 1368 720 M 0 63 V 0 3969 R 0 -63 V stroke 1368 480 M [ [(Helvetica) 240.0 0.0 true true (0)] ] -80.0 MCshow 2724 720 M 0 63 V 0 3969 R 0 -63 V stroke 2724 480 M [ [(Helvetica) 240.0 0.0 true true (5)] ] -80.0 MCshow 4080 720 M 0 63 V 0 3969 R 0 -63 V stroke 4080 480 M [ [(Helvetica) 240.0 0.0 true true (10)] ] -80.0 MCshow 5436 720 M 0 63 V 0 3969 R 0 -63 V stroke 5436 480 M [ [(Helvetica) 240.0 0.0 true true (15)] ] -80.0 MCshow 6792 720 M 0 63 V 0 3969 R 0 -63 V stroke 6792 480 M [ [(Helvetica) 240.0 0.0 true true (20)] ] -80.0 MCshow 1.000 UL LTb 1368 720 M 5424 0 V 0 4032 V -5424 0 V 0 -4032 V stroke 240 2736 M currentpoint gsave translate 90 rotate 0 0 moveto [ [(Helvetica) 240.0 0.0 true true (Probability)] ] -80.0 MCshow grestore 4080 120 M [ [(Helvetica) 240.0 0.0 true true (Normal velocity \(100 m/s\))] ] -80.0 MCshow 4.000 UL LT0 6009 4569 M [ [(Helvetica) 240.0 0.0 true true (7D)] ] -80.0 MRshow 6153 4569 M 351 0 V 1639 1057 M 271 1382 V 272 1137 V 271 381 V 271 -15 V 271 -246 V 271 -588 V 272 -590 V 271 -498 V 271 -404 V 271 -299 V 271 -211 V 4894 934 L 271 -93 V 271 -45 V 271 -38 V 271 -14 V 272 -12 V 271 -1 V 271 -8 V 6.000 UL LT1 6009 4329 M [ [(Helvetica) 240.0 0.0 true true (6D)] ] -80.0 MRshow 6153 4329 M 351 0 V 1639 935 M 271 1226 V 272 1239 V 271 847 V 271 369 V 271 -254 V 271 -168 V 272 -687 V 271 -740 V 271 -638 V 271 -364 V 271 -472 V 272 -272 V 5165 858 L 271 -84 V 271 -29 V 271 -11 V 272 -6 V 271 -4 V 271 -2 V 2.000 UL LT4 6009 4089 M [ [(Helvetica) 240.0 0.0 true true (3D)] ] -80.0 MRshow 6153 4089 M 351 0 V 1639 1294 M 271 1170 V 272 842 V 271 432 V 271 -10 V 271 -289 V 271 -463 V 272 -532 V 271 -442 V 271 -390 V 271 -301 V 271 -215 V 4894 934 L 271 -82 V 271 -58 V 271 -38 V 271 -16 V 272 -5 V 271 -6 V 271 -1 V 2.000 UL LT3 6009 3849 M [ [(Helvetica) 240.0 0.0 true true (2D)] ] -80.0 MRshow 6153 3849 M 351 0 V 1639 720 M 271 1546 V 272 1589 V 271 644 V 271 184 V 271 -85 V 271 -625 V 272 -553 V 271 -776 V 271 -589 V 271 -492 V 271 -325 V 4894 980 L 5165 831 L 271 -58 V 271 -26 V 271 -16 V 272 -4 V 271 -4 V 271 -1 V stroke grestore end showpage %%Trailer %%DocumentFonts: Helvetica %%EndDocument @endspecial -150 1327 a Fn(FIG.)18 b(5:)31 b(V)-6 b(elo)r(cit)n(y)18 b(distribution)f(of)i(desorbing)f(molecules)g(according)-150 1414 y(to)26 b(2D,)g(3D,)g(6D)f(and)h(7D)f(calculations.)-150 1694 y Fr(calculations)i(w)n(e)h(obtain)h(a)f(double)g(p)r(eak)n(ed)g (structure)g(with)h(a)-150 1790 y(large)22 b(probabilit)n(y)h(for)g (high)h(rotational)e(quan)n(tum)h(n)n(um)n(b)r(ers)g Fj(j)5 b Fr(,)-150 1885 y(the)26 b(inclusion)f(of)g(the)h(surface)e (oscillator)f(causes)i(the)g(suppres-)-150 1981 y(sion)35 b(of)h(the)g(p)r(eak)g(at)f(high)h Fj(j)5 b Fr(.)62 b(The)36 b(distribution)g(is)f(similar)-150 2076 y(to)j(that)g(of)g(the)g(late)g (molecules)f(in)i(the)f(rigid)f(surface)g(case.)-150 2172 y(This)f(results)g(in)h(greatly)e(reduced)h(mean)g(rotational)f (energy)-150 2267 y(in)c(desorption,)g(366)e(K)h(and)h(395)e(K)h(for)h (3D)f(and)h(7D)g(calcula-)-150 2363 y(tions,)37 b(resp)r(ectiv)n(ely)-7 b(,)37 b(instead)f(of)f(770)f(K)i(and)f(883)f(K)h(for)g(2D)-150 2458 y(and)h(6D)g(calculations,)h(resp)r(ectiv)n(ely)-7 b(.)61 b(These)36 b(reduced)g(rota-)-150 2554 y(tional)23 b(temp)r(eratures)f(are)h(in)g(fact)h(in)f(m)n(uc)n(h)g(b)r(etter)h (agreemen)n(t)-150 2649 y(with)k(exp)r(erimen)n(t)g([15)o(].)-67 2745 y(As)c(far)f(as)g(the)h(comparison)e(b)r(et)n(w)n(een)i(exp)r (erimen)n(t)g(and)f(the-)-150 2840 y(ory)e(with)h(resp)r(ect)f(to)h (the)g(v)n(elo)r(cit)n(y)f(distribution)h(is)f(concerned,)-150 2936 y(ho)n(w)n(ev)n(er,)h(the)i(agreemen)n(t)e(is)h(greatly)f(reduced) h(if)h(the)g(late)f(des-)-150 3031 y(orption)34 b(c)n(hannel)h(and)g (the)g(surface)f(oscillator)f(is)i(tak)n(en)g(in)n(to)-150 3127 y(accoun)n(t.)g(In)25 b(Fig.)g(5,)g(w)n(e)g(ha)n(v)n(e)f(plotted)h (the)h(v)n(elo)r(cit)n(y)e(distribu-)-150 3222 y(tion)g(according)f(to) h(the)g(2D,)h(3D,)f(6D)g(and)g(7D)g(calculations.)35 b(It)-150 3317 y(is)20 b(fair)f(to)h(sa)n(y)f(that)h(there)f(is)h(no)g (indication)g(of)f(an)n(y)g(bimo)r(dal)h(v)n(e-)-150 3413 y(lo)r(cit)n(y)f(distribution)g(whic)n(h)g(w)n(as)f(found)h(in)g (the)g(exp)r(erimen)n(t)g([15)o(])-150 3508 y(and)24 b(whic)n(h)f(w)n(as)g(also)g(repro)r(duced)g(in)h(the)g(w)n(a)n(v)n (e-pac)n(k)n(et)d(calcu-)-150 3604 y(lations)27 b([17)o(].)-67 3699 y(These)j(\014ndings)h(do)f(not)h(necessarily)e(imply)i(that)g (the)g(con-)-150 3795 y(clusions)26 b(of)g(Ref.)h([17)o(])f(with)h (resp)r(ect)f(to)h(the)f(origins)f(of)i(the)f(bi-)-150 3890 y(mo)r(dalit)n(y)h(in)g(the)g(v)n(elo)r(cit)n(y)g(distribution)g (are)f(no)h(longer)e(v)-5 b(alid.)-150 3986 y(In)25 b(Ref.)g([17)o(])g (it)f(w)n(as)g(prop)r(osed)f(that)i(the)g(bimo)r(dalit)n(y)g(is)f(a)g (con-)-150 4081 y(sequence)31 b(of)h(a)f(bifurcation)h(of)g(the)g(w)n (a)n(v)n(e-pac)n(k)n(et)c(due)k(to)g(the)-150 4177 y(top)r(ology)24 b(of)i(the)g(excited)g(state)f(p)r(oten)n(tial)h(energy)f(surface.)35 b(It)-150 4272 y(migh)n(t)26 b(w)n(ell)g(b)r(e)h(that)f(this)g (explanation)g(is)g(still)g(correct.)35 b(Ho)n(w-)2042 -83 y(ev)n(er,)28 b(in)g(the)h(sim)n(ulations)f(only)g(one)h(excited)f (c)n(harge)f(transfer)2042 12 y(state)38 b(p)r(oten)n(tial)g(out)g(of)g (a)f(great)g(n)n(um)n(b)r(er)h(of)g(c)n(harge)e(trans-)2042 108 y(fer)30 b(states)h([28)o(])f(has)h(b)r(een)g(c)n(hosen.)45 b(P)n(ossibly)29 b(more)h(than)h(one)2042 203 y(excited)38 b(state)g(migh)n(t)g(b)r(e)h(in)n(v)n(olv)n(ed)e(in)h(the)h(desorption) e(pro-)2042 299 y(cess.)h(F)-7 b(urthermore,)27 b(the)i(extension)e(of) h(the)h(t)n(w)n(o-dimensional)2042 394 y Fk(ab)42 b(initio)47 b Fr(p)r(oten)n(tial)41 b(to)f(sev)n(en)g(dimensions)g(using)h(a)f(ph)n (ysi-)2042 490 y(cally)e(reasonable)f(mo)r(del)i(p)r(oten)n(tial)f (could)h(not)g(b)r(e)g(realistic)2042 585 y(enough.)67 b(This)37 b(will)h(b)r(e)h(c)n(hec)n(k)n(ed)d(b)n(y)i(mapping)f(out)h (higher-)2042 681 y(dimensional)31 b(p)r(oten)n(tial)g(energy)g (surfaces)f(through)h(quan)n(tum)2042 776 y(c)n(hemical)20 b(calculations.)33 b(Finally)-7 b(,)22 b(the)f(consideration)e(of)i(a)f (spa-)2042 872 y(tially)g(v)-5 b(arying)19 b(transition)h(probabilit)n (y)f(could)i(lead)f(to)g(a)g(b)r(etter)2042 967 y(agreemen)n(t)28 b(b)r(et)n(w)n(een)i(theory)f(and)g(exp)r(erimen)n(t.)43 b(If)31 b(the)f(deex-)2042 1063 y(citation)37 b(mainly)h(o)r(ccurs)f (at)g(sp)r(eci\014c)h(con\014gurations)e(of)i(the)2042 1158 y(adsorbate,)d(this)h(can)f(ha)n(v)n(e)f(a)g(strong)g(e\013ect)i (on)f(the)h(desorp-)2042 1254 y(tion)27 b(dynamics.)36 b(F)-7 b(rom)26 b(a)h(computational)f(p)r(oin)n(t)h(of)g(view,)g(the) 2042 1349 y(sim)n(ulation)f(of)h(suc)n(h)f(pro)r(cesses)f(within)j(our) e(mixed)h(quan)n(tum-)2042 1445 y(classical)h(sc)n(heme)h(is)h(indeed)g (feasible)f(and)h(will)f(b)r(e)h(addressed)2042 1540 y(in)e(the)g(future.)2655 1850 y Fl(IV.)88 b(CONCLUSION)2125 2070 y Fr(W)-7 b(e)29 b(ha)n(v)n(e)f(implemen)n(ted)i(a)f(mixed)g(quan) n(tum-classical)e(sur-)2042 2165 y(face)k(hopping)g(sc)n(heme)g(for)g (the)h(sim)n(ulation)f(of)g(laser-induced)2042 2261 y(desorption)k(pro) r(cesses.)63 b(In)37 b(this)g(metho)r(d,)i(the)e(n)n(uclear)f(mo-)2042 2356 y(tion)19 b(is)g(describ)r(ed)g(classically)e(while)i(the)h (electrons)e(are)g(treated)2042 2452 y(quan)n(tum)25 b(mec)n(hanically)-7 b(.)35 b(Still)25 b(the)g(feedbac)n(k)f(b)r(et)n (w)n(een)h(n)n(uclei)2042 2547 y(and)30 b(electrons)f(is)h(fully)h(tak) n(en)f(in)n(to)g(accoun)n(t.)44 b(In)30 b(con)n(trast)f(to)2042 2643 y(a)23 b(quan)n(tum)h(treatmen)n(t)f(the)i(computational)e (e\016ciency)g(of)h(our)2042 2738 y(metho)r(d)31 b(allo)n(ws)e(a)h(m)n (ulti-dimensional)g(treatmen)n(t.)45 b(W)-7 b(e)31 b(ha)n(v)n(e)2042 2834 y(applied)37 b(this)g(metho)r(d)h(to)f(the)g(laser-induced)f (desorption)g(of)2042 2929 y(NO)23 b(from)h(NiO\(100\))f(using)g(a)h (previously)e(determined)i Fk(ab)j(ini-)2042 3025 y(tio)36 b Fr(p)r(oten)n(tial)31 b(energy)e(surface.)45 b(By)31 b(comparing)e(our)h(metho)r(d)2042 3120 y(to)24 b(jumping)g(w)n(a)n(v)n (e-pac)n(k)n(et)d(calculations)i(on)h(exactly)f(the)i(same)2042 3216 y(p)r(oten)n(tial)h(energy)g(surface)g(w)n(e)g(v)n(eri\014ed)g (that)h(it)h(is)e(indeed)h(jus-)2042 3311 y(ti\014ed)h(to)f(neglect)h (quan)n(tum)f(e\013ects)h(in)g(the)g(n)n(uclear)e(motion.)2125 3413 y(Our)h(mixed-quan)n(tum)h(classical)e(metho)r(d)j(is)f (computation-)2042 3508 y(ally)39 b(v)n(ery)g(e\016cien)n(t.)74 b(This)40 b(has)f(allo)n(w)n(ed)g(us)h(to)g(extend)g(the)2042 3604 y(sim)n(ulations)32 b(of)i(the)f(laser-induced)g(desorption)f(of)h (NO)h(from)2042 3699 y(NiO\(100\))28 b(to)g(longer)g(time)h(scales)f (and)h(higher)f(dimensionali-)2042 3795 y(ties.)35 b(W)-7 b(e)22 b(\014nd)g(that)g(the)h(bimo)r(dalit)n(y)e(in)h(the)g(v)n(elo)r (cit)n(y)f(distribu-)2042 3890 y(tion)29 b(of)h(desorbing)e(molecules)h (obtained)g(in)h(lo)n(w-dimensional)2042 3986 y(sim)n(ulations)37 b(v)-5 b(anishes)38 b(if)g(in)h(particular)e(surface)g(recoil)g(pro-) 2042 4081 y(cesses)30 b(are)h(tak)n(en)f(in)n(to)h(accoun)n(t.)48 b(This)31 b(indicates)g(that)h(more)2042 4177 y(than)f(one)f(excited)h (state)g(migh)n(t)g(b)r(e)g(in)n(v)n(olv)n(ed)f(in)h(the)h(desorp-)2042 4272 y(tion)27 b(pro)r(cess.)p 948 4474 2039 5 v 1203 4475 1529 7 v 1458 4476 1020 9 v 1712 4477 510 11 v -112 4722 a Fn([1])35 b(F.)20 b(M.)g(Zimmermann)d(and)i(W.)h(Ho,)25 b(Surf.)20 b(Sci.)g(Rep.)f Fl(22)h Fn(\(1995\))3 4809 y(127.)-112 4896 y([2])35 b(H.)28 b(Guo,)j(P)-6 b(.)28 b(Saalfrank,)j(and)e(T.)g(Seidman,)44 b(Prog.)30 b(Surf.)f(Sci.)3 4984 y Fl(62)d Fn(\(1999\).)-112 5071 y([3])35 b(A.)20 b(Gro\031,)j(B.)e(Hammer,)f(M.)h(Sc)n(he\017er,)h(and)e(W.)g(Brenig,)28 b(Ph)n(ys.)3 5158 y(Rev.)d(Lett.)h Fl(73)g Fn(\(1994\))h(3121.)-112 5245 y([4])35 b(A.)22 b(Gro\031,)j(S.)e(Wilk)n(e,)h(and)f(M.)g(Sc)n (he\017er,)31 b(Ph)n(ys.)22 b(Rev.)h(Lett.)g Fl(75)3 5332 y Fn(\(1995\))k(2718.)2080 4722 y([5])34 b(A.)26 b(Gro\031,)35 b(Surf.)26 b(Sci.)g(Rep.)g Fl(32)g Fn(\(1998\))g(291.) 2080 4809 y([6])34 b(G.-J.)27 b(Kro)r(es,)35 b(Prog.)27 b(Surf.)f(Sci.)g Fl(60)g Fn(\(1999\))h(1.)2080 4896 y([7])34 b(A.)26 b(Gro\031,)35 b(J.)27 b(Chem.)e(Ph)n(ys.)h Fl(110)g Fn(\(1999\))h(8696.)2080 4984 y([8])34 b(Z.)d(S.)f(W)-6 b(ang,)32 b(G.)f(R.)g(Darling,)h(and)e(S.)h(Hollo)n(w)n(a)n(y)-6 b(,)50 b(Surf.)31 b(Sci.)2194 5071 y Fl(458)c Fn(\(2000\))g(63.)2080 5158 y([9])34 b(J.)27 b(C.)f(T)-6 b(ully)g(,)34 b(J.)27 b(Chem.)e(Ph)n(ys.)g Fl(93)h Fn(\(1990\))h(1061.)2042 5245 y([10])34 b(C.)27 b(Bac)n(h)f(and)f(A.)h(Gro\031,)35 b(F)-6 b(arada)n(y)26 b(Diss.)g Fl(117)h Fn(\(2000\))f(99.)2042 5332 y([11])34 b(C.)27 b(Bac)n(h)f(and)f(A.)h(Gro\031,)35 b(J.)27 b(Chem.)e(Ph)n(ys.)g Fl(114)i Fn(\(2001\))f(6396.)p eop %%Page: 6 6 6 5 bop 4043 -299 a Fr(6)-150 -83 y Fn([12])35 b(D.)25 b(S.)h(Sholl)g(and)f(J.)i(C.)f(T)-6 b(ully)g(,)34 b(J.)26 b(Chem.)f(Ph)n(ys.)h Fl(109)g Fn(\(1998\).)-150 4 y([13])35 b(W.)26 b(Brenig,)35 b(Z.)26 b(Ph)n(ys.)f(B)h Fl(23)g Fn(\(1976\))h(361.)-150 91 y([14])35 b(P)-6 b(.)25 b(Saalfrank,)36 b(Chem.)25 b(Ph)n(ys.)g Fl(193)i Fn(\(1995\))g(119.)-150 178 y([15])35 b(T.)51 b(Mull,)58 b(B.)52 b(Baumeister,)57 b(M.)52 b(Menges,)58 b(H.-J.)51 b(F)-6 b(reund,)3 266 y(D.W)g(eide,)30 b(C.)h(Fisc)n(her,)g(and)e(P)-6 b(.)30 b(Andersen,)46 b(J.)30 b(Chem.)f(Ph)n(ys.)3 353 y Fl(96)d Fn(\(1992\))h(7108.)-150 440 y([16])35 b(G.)79 b(Eic)n(hhorn,)92 b(M.)79 b(Ric)n(h)n(ter,)91 b(K.)79 b(Al-Shamery)-6 b(,)90 b(and)3 527 y(H.)25 b(Zac)n(harias,)36 b(Surf.)26 b(Sci.)g Fl(368)g Fn(\(1996\))h(67.)-150 614 y([17])35 b(T.)28 b(Kl)r(\177)-41 b(uner,)29 b(H.-J.)g(F)-6 b(reund,)27 b(V.)h(Staemmler,)f(and)g(R.)h(Koslo\013,)3 702 y(Ph)n(ys.)d(Rev.)g (Lett.)h Fl(80)g Fn(\(1998\))h(5208.)-150 789 y([18])35 b(T.)30 b(Kl)r(\177)-41 b(uner,)31 b(H.-J.)f(F)-6 b(reund,)29 b(J.)h(F)-6 b(reitag,)32 b(and)d(V.)g(Staemmler,)3 876 y(J.)d(Mol.)h(Catal.)g(A)f Fl(119)g Fn(\(1997\))h(155.)-150 963 y([19])35 b(H.)40 b(Zac)n(harias,)45 b(G.)c(Eic)n(hhorn,)i(R.)d(Sc) n(hliesing,)45 b(and)40 b(K.)g(Al-)3 1050 y(Shamery)-6 b(,)32 b(Applied)25 b(Ph)n(ysics)h(B)g Fl(68)g Fn(\(1999\).)-150 1137 y([20])35 b(G.)79 b(Eic)n(hhorn,)92 b(M.)79 b(Ric)n(h)n(ter,)91 b(K.)79 b(Al-Shamery)-6 b(,)90 b(and)3 1225 y(H.)25 b(Zac)n(harias,)36 b(JCPh)n(ys)26 b Fl(111)g Fn(\(1999\).)2042 -83 y([21])34 b(R.)19 b(G.)g(Newton,)24 b Fo(Sc)l(attering)f(The)l(ory)f(of)f(Waves)g (and)h(Particles)p Fn(,)2194 4 y(McGra)n(w-Hill,)28 b(1966.)2042 91 y([22])34 b(R.)25 b(Brak)n(o)g(and)f(D.)h(M.)g(Newns,)33 b(Rep.)24 b(Prog.)i(Ph)n(ys.)f Fl(52)g Fn(\(1989\))2194 178 y(655.)2042 266 y([23])34 b(J.)27 b(W.)f(Gadzuk,)34 b(Surf.)25 b(Sci.)i Fl(342)f Fn(\(1995\))h(345.)2042 353 y([24])34 b(A.)26 b(Gro\031)h(and)e(W.)h(Brenig,)35 b(Surf.)26 b(Sci.)g Fl(302)g Fn(\(1994\))h(403.)2042 440 y([25])34 b(K.)28 b(S.)f(Upadh)n(y)n(a)n(y)n(a,)g(G.)h(K.)f(Upadh)n (y)n(a)n(y)n(a,)g(and)g(A.)g(N.)h(P)n(andey)-6 b(,)2194 527 y(J.)27 b(Ph)n(ys.)e(Chem.)h(Solids)g Fl(63)g Fn(\(2002\))h(127.) 2042 614 y([26])34 b(A.)h(Gro\031)h(and)e(M.)h(Sc)n(he\017er,)63 b(J.)36 b(V)-6 b(ac.)34 b(Sci.)h(T)-6 b(ec)n(hnol.)36 b(A)e Fl(15)2194 702 y Fn(\(1997\))27 b(1624.)2042 789 y([27])34 b(C.)28 b(Cresp)r(os,)h(H.)e(F.)h(Busnengo,)g(W.)f(Dong,)h (and)e(A.)h(Salin,)39 b(J.)2194 876 y(Chem.)26 b(Ph)n(ys.)f Fl(114)h Fn(\(2001\))h(10954.)2042 963 y([28])34 b(T.)d(Kl)r(\177)-41 b(uner,)31 b(H.-J.)f(F)-6 b(reund,)29 b(J.)h(F)-6 b(reitag,)32 b(and)d(V.)g(Staemmler,)2194 1050 y(J.)e(Chem.)e(Ph)n(ys.)h Fl(104)g Fn(\(1996\))h(10030.)p eop %%Trailer end userdict /end-hook known{end-hook}if %%EOF